Canon Kabushiki Kaisha

Yuka Ishiduka

Nobuhiro Nakamura

Kunihiko Sekido

Koji Takahashi

Masato Tanaka

Atsushi Okuda

Kenichi Kaku

Hiroyuki Watanabe

Tsutomu Nishida

Hideharu Shimozawa

Yota Ito

Kazunori Noguchi

Takeshi Murakami

Michiyo Sekiya

Atsushi Fujii

Yuki Yamamoto

Wataru Kitamura

Akihiro Maruyama

Mai Murakami

Ryoichi Tokimitsu

Kazuko Sakuma

Harunobu Ogaki

Takakazu Tanaka

Tatsuya Yamaai

Daisuke Miura

Tomohito Ishida

Itaru Takaya

Akira Yoshida

Koichi Nakata

Kazuhiro Yamauchi

Daisuke Tanaka

Hiroyuki Tomono

Masaki Nonaka

Haruki Mori

Shuhei Iwasaki

Yuichi Kikuchi

Kazumichi Sugiyama

Tatsuya Ikezue

Hideaki Nagasaka

Kan Tanabe

Masataka Kawahara

Koji Nishikawa

Shuhei Moribe

Kentaro Yamawaki

Kazuhisa Shida

Tatsuya Ohsawa

Masashi Nishi

Hidetoshi Hirano

Kazuko Araki

Satoshi Otsuji

Takahisa Taniguchi

Takehiko Endo

There is provided an electrophotographic photosensitive member having drum shape, the electrophotographic photosensitive member including a support and a photosensitive layer, wherein an outer surface of the electrophotographic photosensitive member has wrinkles, and when an observation region having square form with one side of 100 μm is placed at an arbitrary position on the outer surface, a line that passes through a central point of the observation region and is parallel to a circumferential direction of the electrophotographic photosensitive member is defined as a first reference line L1, and 3,599 reference lines obtained by rotating the first reference line L1 at every 0.1° around the central point are defined as L2 to L3,600, respectively, each of L1 to L3,600 intersects with convex portions of the wrinkles at a plurality of locations and has at least two different intersection angles selected from the plurality of locations.

Electrophotographic photosensitive member

A method for producing an electrophotographic photosensitive member including: forming a photosensitive layer; and forming a protective layer, wherein the step of forming the photosensitive layer forms a photosensitive layer having an amount of residual solvent of a first solvent in the photosensitive layer of 0.05% to 2.50% and an amount of residual solvent of a second solvent in the photosensitive layer of 0.50% to 2.50%, and the step of forming the protective layer includes step (A) of forming a cured film and step (B) of forming the protective layer having wrinkle shapes, wherein, in step (A), the irradiated coating film is heated at a heating temperature lower than a boiling point of the first solvent and in step (B), the cured film is heated at a heating temperature higher than a boiling point of the first solvent.

Method for producing electrophotographic photosensitive member

An electrophotographic photosensitive member that is excellent in image smearing resistance and low torque while maintaining its electrophotographic characteristic. The electrophotographic photosensitive member is an electrophotographic photosensitive member including, in this order: a support; a photosensitive layer; and a protection layer as a surface layer, wherein the protection layer has a surface having a developed area ratio Sdr of 1.0% to 40.0%, and wherein an A value represented by the following formula (1) is 0.10 to 0.27: A=S1/S2 . . . formula (1), where, in the formula (1), S1 represents a peak area based on C&#x2550;C stretching vibration of an aromatic ring by attenuated total reflection Fourier transform infrared spectroscopy, and S2 represents a peak area based on C&#x2550;O stretching vibration of an ester group by the same method.

Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus

An electrophotographic image forming apparatus in which streak-like banding to be formed in an electrophotographic photosensitive member is suppressed. The electrophotographic image forming apparatus includes an electrophotographic photosensitive member, which has a protective layer, and a developer carrying member for supplying a developer. The protective layer contains a cured product containing an aromatic ring and an ester group, by attenuated total reflection Fourier transform infrared spectroscopy, when a peak area based on C&#x2550;C stretching vibration of the aromatic ring is represented by S1, and a peak area based on C&#x2550;O stretching vibration of the ester group is represented by S2, an area ratio S1/S2 is 0.10 to 0.27, and a rotation speed ratio D1/D2 of a rotation speed D1 of the developer carrying member to a rotation speed D2 of the electrophotographic photosensitive member is 0.80 to 1.20.

Electrophotographic image forming apparatus and process cartridge

Provided is an electrophotographic photosensitive drum that achieves both of a reduction in torque of the electrophotographic photosensitive drum at the time of its cleaning and an improvement in image transferability. The electrophotographic photosensitive drum includes: a support; and a photosensitive layer arranged on the support, the electrophotographic photosensitive drum having arranged on an outer surface thereof at least two structure groups having different appearance periods, wherein when, out of the two structure groups, a group including structures having a smaller appearance period is defined as a first structure group, and a group including structures having a larger appearance period is defined as a second structure group, a height of the first structure group is lower than a height of the second structure group.

Electrophotographic photosensitive member having outer surface with first and second structure groups, the first structure group having a smaller appearance period and a lower height than the second structure group

A process cartridge which allows any spot and stripe as image defects to be suppressed is provided. A process cartridge, in which an electroconductive layer of a charging member has a matrix including a first rubber, and domains dispersed in the matrix, the domains include a second rubber and an electron electroconductive agent, at least some of the domains are exposed on a surface of the charging member, when a volume resistivity of the matrix is 10times or more a volume resistivity of the domains, a protective layer of an electrophotographic photosensitive member includes a metal oxide particle, and when a number average primary particle size of the metal oxide particle is defined as Sm and an average value of equivalent circle diameters of the domains is defined as Sd, the Sd/Sm satisfies the following expression (1): 0.5&#x3c;Sd/Sm&#x3c;100 . . . expression (1).

Process cartridge and electrophotographic apparatus

There is provided a process cartridge detachably attachable to a main body of an electrophotographic apparatus, the process cartridge including an electrophotographic photosensitive member and a charging member, wherein an outer surface of the charging member is composed of at least a matrix and at least a part of domains, a volume resistivity of the matrix is 1.0&#xd7;10times or more of a volume resistivity of the domain, an average value Sd of circle equivalent diameters of the domains observed on the outer surface of the charging member is in a predetermined range, the electrophotographic photosensitive member contains a support, a photosensitive layer, and a protective layer in this order and when a surface roughness of the protective layer is measured, each of a protruding valley portion Rvk, a load length ratio Mr2, and Sd/Rvk is in a predetermined range.

Process cartridge and electrophotographic apparatus using the same

The present disclosure provides an electrophotographic photosensitive member that suppresses electric potential fluctuations in repeated use. The electrophotographic photosensitive member includes a support, a photosensitive layer and a protective layer, in this order, wherein the photosensitive layer includes a compound having a structure represented by formula (1), and the protective layer includes a resin having a structure represented by formula (2) and a structure represented by formula (3).

Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus

Provided are an electrophotographic apparatus and a process cartridge each capable of suppressing the occurrence of a black spot (white background contamination) in an output image under a low-temperature and low-humidity environment. The electrophotographic apparatus includes: an electrophotographic photosensitive member including a support, a photosensitive layer, and a protective layer in the stated order; an exposing device; a developing device; and a cleaning device, wherein the protective layer has a triarylamine structure and a specific structure at a ratio in a specific range, and a toner contains toner particles each containing at least a resin, and an external additive. The toner has a volume-average particle diameter of 7 &#x3bc;m or more. The external additive contains a compound containing a titanium atom. The ratio of the mass of the compound containing a titanium atom to the total mass of the toner is 0.6 mass % or more.

An electrophotographic photosensitive member having a protective layer wherein the density unevenness among output images is reduced with abrasion resistance maintained is provided. The present invention is an electrophotographic photosensitive member having a support, a photosensitive layer and a protective layer in this order, wherein the protective layer has a triarylamine structure and a cyclic structure represented by the formula (1) or (2): and an A value expressed by expression (4), A=S1/S2, wherein, in expression (4), S1 is a peak area based on in-plane deformation vibration of terminal olefin (CH&#x2550;), and S2 is a peak area based on stretching vibration of C&#x2550;O among peak areas of a spectrum obtained by measuring a surface of the protective layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and using a measurement condition of 45&#xb0; as an incidence angle is from 0.065 to 0.100.

A method for producing an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order includes: forming a coating film for a protective layer by coating a coating liquid for the protective layer for forming the protective layer on the photosensitive layer and curing the coating film for the protective layer, in which the coating liquid for the protective layer contains a solvent, a compound represented by a general formula (1), a compound represented by a general formula (2), and a compound represented by a general formula (3) at a specific ratio. In addition, in an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order, the protective layer is obtained by curing a coating liquid for the protective layer.

Electrophotographic photosensitive member and method for producing electrophotographic photosensitive member

To provide an electrophotographic photosensitive member which does not cause film exfoliation in long-term use. An electrophotographic photosensitive member, having: a support; a layered photosensitive layer; and a protective layer in this order, wherein the protective layer is a single layer, the protective layer includes: at least two specific structures, the two specific structures are included in the protective layer at a mass ratio of 20% or more and 240% or less, and a peak area based on in-plane deformation vibration of terminal olefin (CH&#x2550;) of the protective layer and a peak area based on stretching vibration of C&#x2550;O of acryloyloxy groups, the peak areas being determined by total reflection Fourier transform infrared spectroscopy under conditions where an internal reflection element is Ge, and an incidence angle is 45&#xb0;, have a fixed relationship.

Electrophotographic photosensitive member and method for manufacturing the same as well as process cartridge and electrophotographic image-forming apparatus

Provided is a process cartridge including: an electrophotographic photoreceptor; a charging unit configured to charge the electrophotographic photoreceptor through abutment against the electrophotographic photoreceptor; a developing unit configured to develop an electrostatic latent image formed on the electrophotographic photoreceptor with a toner to form a toner image; and a cleaning unit configured to remove the toner on the electrophotographic photoreceptor by bringing a blade into abutment against the electrophotographic photoreceptor, wherein the toner includes a toner base containing a coloring agent and a binder resin, and has a surface layer containing an organosilicon polymer having a specific sticking ratio to a toner base, and wherein the electrophotographic photoreceptor includes a supporting member and a surface layer, and the surface layer has a specific universal hardness value and a specific elastic deformation ratio (We).

The present invention provides an electrophotographic photosensitive member sequentially including: a support; a photosensitive layer; and a protection layer formed on the support, wherein the protection layer has a triarylamine structure and a specific cyclic structure, and a specific A-value obtained by measurement using total reflection Fourier transform infrared spectroscopy is 0.010 or more and 0.050 or less.

An electrophotographic photosensitive member includes an undercoat layer, a charge generation layer, and a charge transport layer in this order. The undercoat layer contains a cured product of a composition containing an electron transport material, a particle having an average primary particle size of 10 nm or more, and a silicone oil. A content of the particle in the undercoat layer is 3% by mass or more and 20% by mass or less. A content of the silicone oil in the undercoat layer is 0.01% by mass or more and 10% by mass or less relative to the content of the particle.

Electrophotographic photosensitive member, process cartridge, electrophotographic apparatus, and method for producing electrophotographic photosensitive member

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Suntou-gun, Japan

Yuka Ishiduka