Hitachi Chemical Company, Ltd.

Yuichi Osada

Yasunori Okada

Shozo Kasai

Hiroshi Nishizawa

Yoshiyuki Mukoyama

Nobuyuki Hayashi

Isao Uchigasaki

Shigeo Tachiki

Mineo Nakano

Masahiro Abo

Toyoji Oshima

Toshiaki Ishimaru

Touichi Sakata

A heat resistant resin composition comprising (A) a polyamideimide resin soluble in a cresol type solvent obtained by using a lactam as a reactant, and (B) at least one member selected from the group consisting of a polyester resin, a polyesteramide resin, a polyesterimide resin and a polyesteramideimide resin, preferably heated for conducting a reaction, gives coatings excellent in heat resistance, thermal shock resistance, wear resistance, resistance to hydrolysis, crazing resistance, etc., suitable for enamelled wire.

Heat resistant resin composition

A polyamide-imide resin composition comprising (A) a polyamide-imide resin modified with a polyisocyanate containing one or more isocyanurate rings and a lactam and (B) at least one member selected from the group consisting of (i) an alkoxy modified amino resin, (ii) a polyisocyanate containing one or more isocyanurate rings, (iii) a phenol-formaldehyde resin, (iv) an epoxy resin, (v) a polyester resin having one or more hydroxyl groups obtained by using terephthalic acid and/or isophthalic acid as an acid component, and (vi) a metal salt of Sn, Mn, Co or Zn, can give fast curing properties to the resin composition without lowering heat resistance, flexibility, abrasion resistance and also giving good surface appearance to the coating.

Polyamide-imide resin composition

A heat resistant resin produced by reacting (A) a polyamideimide resin with (B) an alcohol component and (C) an acid component with heating is soluble in a cresol type solvent and gives coatings excellent in heat resistance, thermal shock resistance, wear resistance, resistance to hydrolysis, etc., suitable for enamelled wire.

Heat resistant resin and process for producing the same

Heat resistant resin composition comprising reaction product of

Polyesteramides produced by reacting in the first step an aromatic monoalkyl dicarboxylate with an aromatic diisocyanate in the presence or absence of one or more monoalkyl dicarboxylates and/or diisocyanates to produce an aromatic dialkyl diamidedicarboxylate of the formula: ##STR1## wherein R.sub.1 is alkyl; and R.sub.2 is a divalent aromatic residue, or a mixture of dialkyl diamidedicarboxylates containing the compound of the formula (II), and reacting in the second step the compound of the formula (II) or the mixture containing the compound of the formula (II) with one member selected from the group consisting of

Polyesteramides and process for producing the same

A polyester resin, polyester-imide resin or polyester-amide-imide resin dissolved in a solvent containing 60% by weight or more of at least one polyhydric alcohol derivative selected from the group consisting of R.sub.1 COO(CHR.sub.2 CH.sub.2 O).sub.n H, R.sub.1 COO(CHR.sub.2 CH.sub.2 O).sub.n COR.sub.3, R.sub.1 O(CHR.sub.2 CH.sub.2 O).sub.n COR.sub.3 and R.sub.1 O(CHR.sub.2 CH.sub.2 O).sub.n R.sub.4, wherein R.sub.1, R.sub.3 and R.sub.4 are independently lower alkyl, aryl or aralkyl; R.sub.2 is hydrogen or methyl; and n is an integer of 1 to 3, gives an electrical insulating coating having excellent storage stability and high resin concentration without causing defects of phenols when used as a solvent.

Electrical insulating coatings

An electrical insulating resin composition comprising a resin obtained by reacting (a) one or more tri- or higher polyhydric alcohols and/or tri- or higher polybasic acids, (b) one or more dihydric alcohols, (c) one or more dibasic acids, (d) one or more monobasic acids containing one or more aromatic rings in the molecule, and/or (e) one or more monohydric alcohols containing one or more aromatic rings in the molecule, and if desired (f) one or more compounds containing or being able to form one or more 5-membered imide rings, can give high solids varnishes without lowering the molecular weight of the resin produced. Said varnishes can give coating films excellent in heat resistance, flexibility and mechanical strengths.

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Hitachi, Japan

Yuichi Osada