Oji Holdings Corporation

Bridgestone Corporation

Yuichi Noguchi

Ikue Homma

Yasutomo Noishiki

Mitsuru Tsunoda

Yusuke Todoroki

Takayuki Shimaoka

Mengchen Zhao

Go Banzashi

Koh Sakai

Yusuke Matsubara

Ikue Sugiyama

Hayato Fushimi

Hideko Akai

Rie Shirahama

Shino Iwai

Moe Mizukami

Saaya Takaoka

Takuri Ozaki

Yoshiyuki Tsutsumi

Tomoki Watanabe

Takayuki Kishida

Objects of the present invention are to provide a phosphoric acid-esterified fine cellulose fiber of which slurry shows superior transparency, and to provide a method for producing a phosphorylated fine cellulose fiber showing superior transparency with good efficiency and high yield. According to the present invention, there is provided a phosphoric acid-esterified fine cellulose fiber, of which 0.2 mass % aqueous dispersion shows a solution haze of 15% or lower.

Phosphoric acid-esterified fine cellulose fiber and method for producing the same

It is an object of the present invention to provide a resin composite comprising ultrafine cellulose fibers, in which deterioration of a resin component is suppressed. The present invention relates to a cellulose fiber-containing resin composition comprising cellulose fibers with a fiber width of 1000 nm or less having phosphoric acid groups or phosphoric acid group-derived substituents, and a resin, wherein the counterions of the phosphoric acid groups or phosphoric acid group-derived substituents are organic onium ions, and the conjugate bases of the organic onium ions have a pKb value of 1.0 or more.

Cellulose fiber-containing resin composition, sheet, and molded body

It is an object of the present invention to provide ultrafine cellulose fibers capable of exhibiting favorable dispersibility even in an organic solvent. The present invention relates to cellulose fibers having a fiber width of 1000 nm or less and having phosphoric acid groups or phosphoric acid group-derived substituents, wherein the content of the phosphoric acid groups or phosphoric acid group-derived substituents is 0.5 mmol/g or more, and the supernatant yield measured by an measurement method (a) is 70% or less.

Cellulose fibers, cellulose fiber-containing composition, cellulose fiber dispersion, and method for producing cellulose fibers

It is an object of the present invention to optimize a bleaching process in a step of producing phosphorylated cellulose fibers. The present invention relates to a pulp comprising cellulose fibers having 0.5 mmol/g or more of phosphoric acid groups or phosphoric acid group-derived substituents, wherein when the pulp is processed into a sheet and four sheets are laminated on one another, the ISO whiteness of the laminate is 82% or more. Moreover, when the pulp of the present invention is processed into a sheet and four sheets are then laminated on one another, the b* value of the obtained laminate according to the L*a*b* color system is 5.5 or less.

Pulp, slurry, sheet, laminate, and method for producing pulp

An object of the present invention is to provide a salt water thickener that uniformly (favorably) disperses ultrafine cellulose fibers even in a liquid containing a salt (electrolyte). The salt water thickener comprises ultrafine cellulose fibers and a water-soluble polymer and can thereby uniformly disperse the ultrafine cellulose fibers even in a liquid containing a salt. The salt water thickener of the present invention is uniformly dispersed even in a liquid containing a salt and therefore exerts a high viscosity. The salt water thickener of the present invention can also be used as an additive for a fluid. The salt water thickener of the present invention can be used for purposes, for example, subterranean formation processing.

Composition comprising ultrafine cellulose fibers

It is an object of the present invention to provide a method for producing ultrafine fibrous cellulose, which is capable of efficiently obtaining ultrafine fibrous cellulose having phosphoric acid groups with a high yield. The present invention relates to a method for producing fibrous cellulose having a fiber width of 1000 nm or less, comprising: a (A) of introducing phosphoric acid groups into cellulose fibers to form crosslinked structures via the phosphoric acid groups, thereby obtaining crosslinked phosphorylated cellulose fibers, a (B) of breaking some or all of the crosslinked structures to obtain crosslink-broken phosphorylated cellulose fibers, and a (C) of performing a mechanical treatment on the crosslink-broken phosphorylated cellulose fibers to obtain fibrous cellulose having a fiber width of 1000 nm or less, wherein, in the (A), crosslinked structures in an amount of 0.05 mmol/g or more and 2.0 mmol/g or less are formed, and the (B) is a step of performing the hydrolysis of the crosslinked structures in an aqueous solvent with pH 3 or more.

Method for producing fibrous cellulose, and fibrous cellulose

It is an object of the present invention to provide a resin composite that is excellent in water resistance and is capable of exerting sufficient strength even under wet conditions. The present invention relates to a resin composite comprising a resin, fibers having an ionic functional group, and a polyvalent ion. The fibers having an ionic functional group are preferably cellulose fibers having a fiber width of 1000 nm or less.

Resin composite and method for producing resin composite

An object of the present invention is to improve the strength of a sheet containing substituent-introduced ultrafine fiber under high-humidity conditions while maintaining its high transparency. The sheet of the present invention comprises ultrafine fiber having an ionic substituent, and a divalent or higher metal, and has a haze of 10.0% or less.

Sheet, method for producing sheet, and laminate

The object is to provide a subterranean formation processing composition which has a highly stable viscosity against change in temperature and a high water stopping property. A subterranean formation processing composition comprising cellulose fibers wherein the composition contains ultrafine cellulose fibers having 0.14 to 2.5 mmol/g of a substituent is used. The substituent is preferably an anion group, particularly a phosphoric acid group. The present invention relates to various fluids which are used in well processing. The present invention relates to a method for processing a subterranean formation, for example, drilling of an exploratory well or a wildcat, an appraisal well, an exploratory well or an exploration well, a delineation well, a development well, a production well, an injection well, an observation well, and a service well; cementing; fracturing; and a method for producing petroleum resources. The present invention provides also a cellulose fiber-containing composition which is not limited to the subterranean formation processing use.

An object is to provide a dispersion of ultrafine cellulose fibers having a high thickening effect and a gelling function. There is provided a subterranean formation processing composition comprising ultrafine cellulose fibers, which has a haze value of 1.0% to 50%, when the composition is suspended in water such that the solid concentration of cellulose fibers is 0.2% by mass. The composition of the present invention can be used as an additive to the fluid at the time of the processing of subterranean formation, especially the processing of the well. The present invention provides also various fluids which are used in well processing. The present invention provides a method for processing a subterranean formation, for example, drilling of an exploratory well or a wildcat, an appraisal well, an exploratory well or an exploration well, a delineation well, a development well, a production well, an injection well, an observation well, and a service well; cementing; fracturing; and a method for producing petroleum resources.

Subterranean formation processing composition comprising ultrafine cellulose fibers

An object of the present invention is to provide a method for producing an ultrafine fiber-containing sheet with suppressed yellowing. The present invention provides a method for producing an ultrafine fiber-containing sheet, comprising (a) introducing a substituent having electrostatic and/or steric functionality to a fiber raw material to obtain substituent-introduced fiber; (b) machine-processing the substituent-introduced fiber obtained in the step (a) to obtain substituent-introduced ultrafine fiber; (c) preparing a sheet from the substituent-introduced ultrafine fiber obtained in the step (b); and (d) eliminating at least a portion of introduced substituents from the sheet obtained in the step (c). In a preferred aspect, the substituent having electrostatic and/or steric functionality is a phosphoric acid-derived group, and the method may further comprise, after the step (a) and before the step (c), the step of (e) changing the degree of neutralization of the substituent-introduced fiber or the substituent-introduced ultrafine fiber.

Methods for producing ultrafine fiber and ultrafine fiber-containing sheet, sheet obtained thereby, and resin composite comprising laminated resins

The object of the present invention is to provide a method for producing fine fibers and a sheet containing fine fibers, whereby fiber refinement (fibrillating) of a fiber material is facilitated, freeness and dehydration performance of slurry containing fine fibers obtained after fiber refinement (fibrillating) is favorable and resistance to yellowing of the fine fibers is improved. The present invention provides a method for producing fine fibers, comprising at least the steps of: (a) introducing electrostatic and/or steric functional substituents into a fiber material to obtain substituent-introduced fibers; (b) subjecting the substituent-introduced fibers to mechanical treatment; and (c) eliminating some or all of introduced substituents from the substituent-introduced fine fibers obtained in step (b) to obtain fine fibers from which substituents have been eliminated.

Method for producing fine fibers and sheet containing fine fibers

Provided are a rubber composition provided with excellent reinforcement properties by improving the dispersibility of fibers in a rubber component when the fibers are added to the rubber, a method for manufacturing the same, a vulcanized rubber, and a tire. A rubber composition comprising a rubber component and short fibers, wherein the short fibers are cationized. A method for manufacturing the rubber composition, comprising a mixing step for mixing cationized short fibers and rubber latex to prepare a rubber-short fiber mixed solution, and a drying step for drying the rubber-short fiber mixed solution to give a rubber composition.

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Tokyo, Japan

Yuichi Noguchi