Air Products and Chemicals, Inc.

The Boc Group, Inc.

Yue-Sheng Lin

Donald L MacLean

Yongxian Zeng

Antonij J Burggraaf

Oxygen is removed from gas streams by subjecting the gas stream to a pressure swing adsorption process carried out at temperature in the range of 300 to 1400.degree. C. using as adsorbent a perovskite material having the structural formula A.sub.1-x M.sub.x BO.sub.3-.delta., where A is a rare earth ion, M is Na, Ca, Sr, Ba or mixtures of these, B is Co, Mn, Cr or Fe, x varies from 0.1 to 1 and .delta. is the deviation from stoichiometric composition resulting from the substitution of Sr, Ca and Ba for rare earth ions.

High temperature adsorption process

The present invention is a method for manufacturing ultrathin inorganic membranes comprising yttria-stabilized zirconia (YSZ) in a thickness of .ltoreq.0.5 .mu.m which has been deposited onto a lanthanum-doped alumina surface layer of a porous alumina substrate having an average pore diameter of less than about 50 nm. The inorganic membranes formed by the method provide oxygen flux rates superior to those known in the art and are suitable for numerous uses including processes for separating oxygen from oxygen-containing gaseous mixtures and in processes for partially oxidizing hydrocarbons to their corresponding oxidized products.

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Cincinnati, OH, United States of America

Yue-Sheng Lin