Toyota Jidosha Kabushiki Kaisha

Kabushiki Kaisha Toyota Chuo Kenkyusho

Aisin Seiki Kabushiki Kaisha

Yu Morimoto

Masaya Kawasumi

Naoki Hasegawa

Takumi Taniguchi

Manabu Kato

Kazutaka Kimura

Fusayoshi Miura

Kyoko Tsusaka

Toshiyuki Suzuki

Yoshiaki Fukushima

Shinji Inagaki

Hiroo Yoshikawa

Seiji Mizuno

Tatsuya Kawahara

Mitsuru Nakano

Takahiko Asaoka

Makoto Yoshida

Atsushi Kamiya

Daisuke Kanno

Tsutomu Ochi

Kazuo Kawahara

Tomoo Yoshizumi

Kensaku Kodama

Michio Asukabe

Tomoyuki Nagai

Toshihiro Ikai

Hajime Murata

Michiaki Kato

Eishiro Toyoda

Tomohiro Takeshita

Takahisa Suzuki

Disclosed is a fuel cell stack which is able to prevent corrosion from occurring in a separator. The fuel cell stack formed by arranging a terminal on both ends of a cell stacked body in which a plurality of cells including a membrane electrode assembly and separators interposing the membrane electrode assembly therebetween is stacked, includes a rust preventive plate which is arranged between a metal separator and a positive electrode terminal on a high potential side of the cell stacked body, and includes a material more noble than that of the separator in the surface.

Fuel cell stack

A method of producing a displacement plating precursor, including a deposition step of depositing a Cu layer on a surface of a core particle formed of Pt or a Pt alloy by contacting a Cu ion-containing acidic aqueous solution with at least a portion of a Cu electrode, and contacting the Cu electrode with the core particle or with a composite, in which the core particle is supported on an electroconductive support, within the acidic aqueous solution or outside the acidic aqueous solution, and moreover contacting the core particle with the acidic aqueous solution under an inert gas atmosphere.

Method of producing displacement plating precursor

A membrane electrode assembly according to the invention includes a solid polymer electrolyte membrane and an electrode joined to each of two sides of the solid polymer electrolyte membrane. The solid polymer electrolyte membrane is such that some or all of the protons included in the entire solid polymer electrolyte membrane, a band region, or a non-power generating region are ion exchanged with one or more cations selected from among complex cations, class four alkylammonium cations, and high valence cations. In addition or alternatively, the solid polymer electrolyte membrane includes an organo-metalloxane polymer obtained by impregnating the entire solid polymer electrolyte membrane, the non-power generating region, or the band region with an organo-metalloxane monomer that includes an ammonium cation or a class four ammonium cation at its terminus and then hydrolyzing and polycondensing the organo-metalloxane monomer.

Membrane electrode assembly and polymer electrolyte membrane fuel cell

The membrane electrode assemblyhas an anode, a cathode, and an electrolyte membranedisposed between the anode and cathode; the anode and cathode are gas diffusion electrodes; the electrolyte membrane contains a solid electrolyte in which a plurality of pores with mean pore diameters of 1 to 30 nm are formed; and the solid electrolyte has a backbone comprising organic groups having one or more metal atoms, oxygen atoms bonded to the metal atoms, and carbon atoms bonded to the metal atoms or oxygen atoms, and also has functional groups with ion-exchange capabilities that are bonded to the organic groups in the pores.

Polymer electrolyte membrane with an inorganic backbone

Disclosed herein is a solid polymer electrolyte wherein protons of cation exchange groups contained in a perfluorinated electrolyte are partially replaced by metal ions. The metal ion is at least one metal ion selected from vanadium (V), manganese (Mn), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), iron (Fe), ruthenium (Ru), nickel (Ni), palladium (Pd), platinum (Pt), silver (Ag), cerium (Ce), neodymium (Nd), praseodymium (Pr), samarium (Sm), cobalt (Co), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), and erbium (Er) ions. Further disclosed is a solid polymer fuel cell using the solid polymer electrolyte.

Solid polymer electrolyte, solid polymer fuel cell and method for manufacturing the fuel cell

A Polymer Electrolyte Membrane is formed by hot air drying of a membrane formed with an acidic main-polymer having proton conductivity and capability of forming an electrolyte membrane (S), and then immersing it into a basic polymer solution to impregnate the membrane with the basic polymer (S). The basic polymer is introduced in a large quantity into a site acting as a proton conduction pass of the main-polymer to take charge of the proton conduction. Since in the Polymer Electrolyte Membrane, a base polymer takes charge of proton conduction as compared with the case where proton takes charge of the proton conduction as a hydrate, the base polymer shows favorable proton conductivity even in a low humidity state at an elevated temperature exceeding boiling point of water.

Polymer electrolyte membrane and method of production thereof

A fuel-cell electrode and a method of manufacturing the fuel-cell electrode achieves a high catalyst utilization ratio and makes it possible to obtain higher output characteristics with a smaller amount of catalyst. The fuel-cell electrode includes a catalytic layer composed of an ion conductive substance, an electron conductive substance and catalytic activation substances. The catalytic activation substances are electrolytically deposited on the electron conductive substance.

Fuel-cell electrode and method of manufacturing the fuel-cell electrode

The present invention is a grafted polymer electrolyte membrane prepared by first preparing a precursor membrane comprising a polymer which is capable of being graft polymerized, exposing the surface of the precursor membrane to a plasma in an oxidative atmosphere, then graft-polymerizing a side chain polymer to the plasma treated precursor membrane and introducing a proton conductive functional group to the side chain. The resulting grafted polymer electrolyte membrane has excellent stability and performance when used in a proton-exchange membrane fuel cell or for electrolysis of water.

Grafted polymer electrolyte membrane, method of producing a grafted polymer electrolyte membrane, and fuel cell comprising the same

Disclosed is a membrane electrode assembly obtained by bonding electrodes to both surfaces of a solid polymer electrolyte membrane suitably for use in a solid polymer fuel cell. In order to maintain not only the solid polymer electrolyte but also the electrode in appropriate wet states, the catalyst layer of the assembly contains a metalloxane polymer in the intra-catalyst-layer electrolyte including an electrode catalyst preferably in an amount of 0.5 to 50 wt % of the total weight of the intra-catalyst-layer electrolyte and the metalloxane polymer contained therein exclusive of the electrode catalyst.

Membrane electrode assembly, and solid polymer fuel cell using the assembly

In solid polymer electrolyte having high-durability, comprising a polymer electrolyte material having a hydrocarbon part, a chelate group and an electrolyte group are introduced into the polymer electrolyte material. The chelate group contains a phosphonic acid group, nitrogen, both of nitrogen and a phosphonic acid group (one or more selected from the group consisting of alkylamino monophosphonic acid groups, alkylamino diphosphonic acid groups, dialkylamino monophosphonic acid groups, alkylalkylene diamine triphosphonic acid groups, and alkylimino phosphonic acid groups) or, both of nitrogen and a carboxylic acid group (one or more selected from the group consisting of alkylamino monocarboxylic acid groups, alkylamino dicarboxylic acid groups, dialkylamino monocarboxylic acid groups, alkylalkylene diamine tricarboxylic acid groups, and alkylimino carboxylic acid groups).

Solid polymer electrolyte having high-durability

Growing community of inventors

Nagoya, Japan

Yu Morimoto