Samsung Electronics Co., Ltd.

Yu-gyun Shin

Moon-han Park

Tai-su Park

Han-sin Lee

Dong-ho Ahn

Sun-ghil Lee

Sug-hun Hong

Han-Sin Lee

Hee-Sook Park

Jin-bum Kim

Tai-Su Park

Kwan-heum Lee

Sung-eui Kim

Soo-Jin Hong

Wook-Je Kim

Yun-gi Kim

Kyung-won Park

Moon-Han Park

Sang-jin Hyun

Su-Kyoung Kim

Hyun-cheol Choe

Taek-jung Kim

Seong-joon Ahn

Jong-min Back

Provided is a simplified method of manufacturing a semiconductor device having a stress creating layer. A first conductive first impurity region is formed on a semiconductor substrate on both sides of a first gate of a first area of the semiconductor substrate, and a second conductive second impurity region is formed on the semiconductor substrate on both sides of a second gate of a second area. First and second spacers are formed on sidewalls of the first and second gates, respectively. First and second semiconductor layers are formed in portions of the semiconductor substrate so as to contact the first and second impurity regions, respectively. The second semiconductor layer is removed. First and second barrier layers are formed in the first and second contact holes of the insulation layer, respectively.

Method of manufacturing semiconductor device having stress creating layer

A sputtering target includes a tungsten (W)-nickel (Ni) alloy, wherein the nickel (Ni) is present in an amount of between about 0.01 weight % and about 1 weight %.

Sputtering target and semiconductor device manufactured using the same

Oxide layers, including gate oxide layers having different thicknesses, are formed, plasma nitridized, and oxidized in an oxygen atmosphere containing hydrogen at a high temperature. Electron trap sites and stress occurring during plasma nitridation may be removed during oxidation.

Methods of fabricating oxide layers by plasma nitridation and oxidation

A method of forming an isolation film forms a spacer for connecting the edge of an active region to the isolation film. The spacer is on the upper sidewall of a trench and smoothes the transition or step between the level of the isolation film and the level of the active region. Accordingly, a gate oxide film of a uniform thickness can be formed on the entire active region in a subsequent process, thus preventing degradation of the characteristics of the gate oxide film. The spacer can be formed using a sidewall spacer on the hard mask used for forming the trench. The sidewall spacer protects part of the isolation formed in the trench, and etching after removal of the sidewall spacer can round the protected portion to create the spacer. Furthermore, to dispel stresses and defects in the isolation film, annealing for densification of the isolation film can be performed at a high temperature such as about 1150&deg; C. because the spacer mitigates the effects of shrinking or sagging of the isolation film.

Method of forming isolation film for semiconductor devices

A trench isolation method is provided. In the trench isolation method, a pad oxide film, an oxidative film and an etching mask film are formed on a semiconductor substrate in sequence, and then a trench is formed in a field region of the semiconductor substrate. A oxide film is formed at the inner wall of the trench and the side walls of the oxidative film by oxidizing the semiconductor substrate. After filling the trench with a dielectric material, the pad oxide film, oxidative film and etching mask film formed in the active region are removed.

Trench isolation method for semiconductor device

A method is provided for forming a trench isolation structure in an integrated circuit that has a better reliability and an acceptable time-dependent dielectric breakdown over a greater range of production. The manufacturing method involves etching a trench in a semiconductor substrate, forming a sidewall-insulating layer along the sidewall and bottom of the trench, and depositing a trench-insulating layer in the trench and over the semiconductor substrate. The sidewall-insulating layer is formed to have a lower etch rate than the trench-insulating layer. As a result of this difference in etch rates, the sidewall-insulating layer is not damaged too much during wet etching processes that take place during the later part of manufacture. This makes the interface between the substrate, sidewall-insulating layer, and gate oxide more reliable. The difference in etching rate can be obtained by keeping an annealing process used in later processing below a threshold temperature so that the etch rate of the trench-isolating layer does fall too low. The difference in etching rate can also be obtained by using different materials for the sidewall-isolating layer and the trench-isolating layer, or by using multiple annealing processes.

Method for forming a trench isolation structure in an integrated circuit

An isolation method in the fabrication process of a semiconductor device is provided. The method forms an oxide layer as a buffer layer for reducing stress through chemical vapor deposition (CVD). By the method, a first pad oxide layer and a silicon nitride layer are formed on a semiconductor substrate, and then an silicon nitride layer pattern is formed by patterning, and undercuts are formed in the first pad oxide layer pattern. Subsequently, a second pad oxide layer is formed on the entire surface of the semiconductor substrate through CVD, and then spacers are formed on the sidewalls of both the patterned first pad oxide layer and silicon nitride layer and a field oxide layer is formed through thermal oxidation. Alternatively, a silicon layer is deposited without the spacers to form the field oxide layer. The second pad oxide layer is a buffer layer for buffering stress during formation of the field oxide layer.

Isolation method of semiconductor device using second pad oxide layer

A method for forming a trench isolation in a semiconductor device is provided in which a first heat treatment process is conducted on a thermal oxide layer previously formed in a trench at temperature range from about 1000.degree. C. to 1200.degree. C. for about 1 to 8 hours so as to remove defects in a semiconductor substrate and oxygen impurities within the semiconductor substrate resulting from a step of forming the trench in the semiconductor substrate. As a result, a subsequent second heat treatment process for densifying a trench filling material such as a CVD oxide layer can be performed at lower temperature of about 1000.degree. C. to 1050.degree. C., as compared with the temperature of the first annealing of the thermal oxide layer, thereby reducing distortions of the semiconductor substrate and reducing current leakages.

Method for forming a trench isolation in a semiconductor device

A multilayer oxide film, including at least two oxide layers having differing stress characteristics, is used in a trench isolation method. Preferably, at least a first one of the oxide layers has tensile stress characteristics and at least a second one of the oxide layers has compressive stress characteristics. Thus, during densification, the overall stress can be reduced. The multilayer film is preferably formed by sequentially stacking first and second oxide films which have opposite stress characteristics. In one example, the first oxide film is a tetra-ethyl-orthosilicate (TEOS)-O.sub.3 based chemical vapor deposition (CVD) oxide film and the second oxide film is selected from the group consisting of TEOS-based plasma-enhanced CVD (PECVD) oxide film, an SiH.sub.4 based PECVD oxide film and a high density plasma (HDP) oxide film. In another embodiment, the first oxide film is an HDP oxide film and the second film is a TEOS-O.sub.3 based CVD oxide film. Accordingly, integrated circuits with reduced stress may be fabricated, thereby allowing increased performance of the integrated circuits.

Trench isolation methods utilizing composite oxide films

Methods of forming trench-based isolation regions with reduced susceptibility to edge defects include the steps of forming trenches at a face of a semiconductor substrate and then filling the trenches with electrically insulating regions. However, to prevent exposure of those portions of the substrate extending adjacent the trenches, supplemental oxide regions are formed at the interfaces between the upper portions of the trench sidewalls and the electrically insulating regions in the trenches, by exposing the electrically insulating regions to an oxidation atmosphere at a temperature in a range between about 950.degree. C. and 1100.degree. C. In particular, the supplemental oxide regions are formed as thermal oxides of higher density than the electrically insulating regions in the trenches. Thus, the supplemental oxide regions are more resistant to chemical etchants. Accordingly, when the electrically insulating regions are planarized and etched during back end processing steps, the supplemental oxide regions will not be entirely etched and, therefore, those portions of the substrate (i.e., active regions) extending adjacent the trenches will not be exposed.

Methods of forming trench-based isolation regions with reduced

A method for forming a microelectronic structure includes the steps of forming a mask layer on a substrate, forming a trench in the exposed portion of the substrate, forming a layer of an insulating material which fills the trench and covers the mask layer, and annealing the insulating material at a temperature of at least about 1,150.degree. C. The annealing step can be performed for a period of time of about .5 hours to about 8 hours, and the annealing step can be performed in an inert atmosphere.

Annealing methods for forming isolation trenches

In a device isolation method for a semiconductor device, after a pad oxide layer and a nitride layer are formed on a semiconductor substrate, the nitride layer located above the device isolation region is removed. An undercut is formed under the nitride by partially etching the pad oxide layer. After a first oxide layer is formed on the exposed substrate and a polysilicon spacer is formed on the sidewalls of the nitride layer, a void is formed in the oxide layer under the nitride layer which is formed on the active region by oxidizing the resultant structure in which the polysilicon spacer is formed at a temperature above 950.degree. C. Thus, good cell definition and stable device isolation can be realized, while solving the typical problem of conventional LOCOS methods by forming the void intentionally in the pad oxide layer thickened by bird's beak punch through.

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Seoul, South Korea

Yu-gyun Shin