University of Maine System

Stora Enso Oyj

Nova Chemicals Inc.

Bvpv Styrenics LLC

Yousoo Han

Douglas J Gardner

Christopher H West

Yucheng Peng

Janne Pynnönen

Duncan Mayes

Stephen Michalik

The present invention relates to a method of making a foamed cellulosic fiber-thermoplastic composite article. The method includes the steps of providing a copolymer composition, combining the copolymer composition and cellulosic fibers, applying heat, mixing energy and pressure to form a foamable mixture, and forming the foamable article in a molding or extruding operation. The method is characterized in that at least 10% of the cellulosic fibers have been thermally modified prior to being combined with the copolymer composition.

Composite product and a process for producing said product

The present invention is directed to a composite material comprising a cellulosic material, high impact polystyrene (HIPS) and styrene maleic anhydride (SMA). The cellulosic material may be thermally modified prior to being incorporated into the composite material. The present invention is also directed to a composite product that comprises the composite material according to the invention.

Composite material and composite product

The present invention provides, among other things, compositions comprising nanofibrils, at least one maleic-anhydride (MA) copolymer and at least one matrix polymer, and methods of making such compositions. The provided methods and compositions allow for the production of composites with unexpectedly superior properties including improved impact resistance, tensile modulus of elasticity, tensile strength, and flexural modulus of elasticity as compared to previously known composites. In some embodiments, the present invention provides methods including the steps of providing cellulose nanofibrils, associating the cellulose nanofibrils with a maleic-anhydride (MA) copolymer to form a nanofibril-MA copolymer blend, preparing the nanofibril-MA copolymer blend for addition to a matrix polymer, and forming a composite by associating the nanofibril-MA copolymer blend with the matrix polymer, wherein the amount of cellulose nanofibrils in the composite is between 3% and 50% by weight of the composite.

Nanofibril-polymer composites

A method of producing dried cellulose nanofibrils includes atomizing an aqueous suspension of cellulose nanofibrils and introducing the atomized aqueous suspension into a drying chamber of a drying apparatus. The aqueous suspension is then dried, thereby forming substantially non-agglomerated dried cellulose nanofibrils.

Method for drying cellulose nanofibrils

A method of making foamed articles that includes providing a copolymer composition, combining the copolymer composition and cellulosic fibers, applying heat, mixing energy and pressure to the copolymer composition and cellulosic fibers mixture to form a foamable mixture, and forming the foamed article by placing the foamable mixture in a molding or extruding operation. The copolymer composition includes a copolymer of 51% to 99.9% of primary monomers, 0.1% to 49% of anhydride containing monomers, and 0% to 25% of other monomers and 0% to 30% of elastomeric polymers. This is combined at 30% to 99.99% copolymer composition with 0.01% to 70% by cellulosic fibers such that the copolymer anhydride groups react with the cellulosic fiber hydroxyl groups to produce a blowing agent byproduct to form a foamable mixture. The foamed article has a density of not more than 1.3 g/cm.

Method of making cellulosic filled thermoplastic composites of an anhydride containing copolymer

A composite includes raw lignocellulosic materials dispersed in a thermoplastic polymeric matrix which includes a blend of different polymers. A composite includes raw lignocellulosic materials and a thermal stabilization agent dispersed in a thermoplastic polymeric matrix. A composite includes lignocellulosic nanoparticles dispersed in a thermoplastic polymeric matrix.

Growing community of inventors

Bangor, ME, United States of America

Yousoo Han