Lg Chem, Ltd

Young Hyun Choi

Byung Yul Choi

Hyun Jong Shin

Duk Ki Kim

Yeon Shick Yoo

Young Jin Cho

Joo Yeon Park

Kwang Ho Park

Gyu Il Lee

Eung Seob Yeom

Byeong Joon Jeong

Woo Seon Choi

Ju Yeon Park

Won Ho Lee

Jung Hwa Kang

Hyun Sub Lim

Min Ho Kil

The present invention relates to a graft copolymer and a method for preparing the same, wherein the graft copolymer has merits of a superior storage convenience compared to existing dry powder and a high whiteness index, and thus may be widely applied to various fields.

Graft copolymer and method for preparing same

An extruder configured to extrude a solid raw material containing moisture includes a barrel, a hopper coupled to one side of the barrel, a discharge port, a screw, vent disposed between the hopper and the discharge port to discharge vapor generated within the barrel; and a heater mounted on the barrel to heat the raw material. Raw material introduced into the barrel through the hopper is heated by the heater while being transferred within the barrel through the screw. A kneading zone, in which raw materials transferred by the screw threads are compressed, is formed on the screw. Since the raw material is melted within the barrel, a heating temperature of the heater and an axial rotation speed of the screw are controlled so that a sealing membrane that shields an inner transverse section of the barrel is formed from the liquid raw material in the kneading zone.

Extruder

An extruder configured to extrude a solid raw material containing moisture includes a barrel, a hopper, a discharge port, and a slot portion, through which the inside and outside of the barrel communicate each other, is provided between the discharge port and the hopper; a screw, and a heater mounted on the barrel to heat the raw material. Raw material introduced into the barrel through the hopper is heated by the heater while being transferred within the barrel through the screw. A kneading zone, in which raw materials transferred by the screw threads are compressed, is formed on the screw. Since the raw material is melted within the barrel, a heating temperature of the heater and an axial rotation speed of the screw are controlled so that a sealing membrane that shields an inner transverse section of the barrel is formed from the liquid raw material in the kneading zone.

Disclosed are a high-performance polyoxometalate catalyst and a method of preparing the same. More particularly, disclosed are a high-performance polyoxometalate catalyst which may enhance activity and selectivity by controlling the content of vanadium, etc. exhibits superior reproducibility, and may produce unsaturated carboxylic acid with high yield and long lifespan from unsaturated aldehyde, and a method of preparing the same.

High performance polyoxometal catalyst and method for producing the same

Disclosed is a shell-and-tube reactor that may be used for fixed-bed catalytic partial oxidation, the reactor being characterized by including at least one reaction zone of a first-step reaction zone for mainly producing unsaturated aldehydes and a second-step reaction zone for mainly producing unsaturated acids, wherein at least one reaction zone of the above reaction zones comprises two or more catalytic layers; each of the catalytic layers is packed with a formed product of catalyst that is different in pore density and/or pore size in a catalytically active component; and the pore density and/or pore size is controlled in such a manner that specific surface area of the catalytically active component increases from the inlet of the reactor to the outlet of the reactor. A method for producing unsaturated aldehydes and/or unsaturated fatty acids from olefins using the same reactor is also disclosed. According to the present invention, it is possible to control the temperature efficiently at a hot spot, thereby permitting stable use of a catalyst, and to produce unsaturated aldehydes and/or unsaturated fatty acids with high yield.

Method of producing unsaturated aldehyde and/or unsaturated acid

The present invention provides a method for producing a catalyst comprising an inert carrier an a mixed metal oxide as a catalytically active component supported on the inert carrier, the method comprising the steps of: a) adding organic acid(s) into solvent(s) and salt of each metal component which will form a mixed metal oxide, to prepare a catalyst precursor solution for the mixed metal oxide; b) adjusting pH of the catalyst precursor solution using a basic solution; c) containing the catalyst precursor solution for the mixed metal oxide, of which the pH is adjusted, on the inert carrier, d) removing the solvent(s); and e) calcining the resultant from step d. The catalyst produced by the present method has improved reproducibility, activity and yield, while maintaining a high selectivity.

Method for preparing a catalyst for partial oxidation of acrolein

Disclosed is a method for producing unsaturated fatty acids from unsaturated aldehydes by means of fixed-bed catalytic partial oxidation in a shell-and-tube reactor, characterized in that the reactor includes a reaction zone for producing unsaturated fatty acids, the reaction zone having an inactive material layer inserted into a position where a hot spot is to be generated in a reaction tube. A fixed-bed shell-and-tube reactor for use in the above method is also disclosed. According to the present invention, at least one layer of inactive material is packed at the point of a hot spot to control the hot spot temperature efficiently, thereby increasing the lifetime of a catalyst and producing unsaturated fatty acids with high yield.

Method for producing unsaturated fatty acids

Disclosed is a shell-and-tube reactor that may be used in a method for producing unsaturated aldehydes and/or unsaturated acids from olefins by means of fixed-bed catalytic partial oxidation. The reactor includes at least one reaction zone of a first-step reaction zone for producing unsaturated aldehydes as a main product and a second-step reaction zone for producing unsaturated acids as a main product, and at least one reaction zone of the reaction zones comprises two or more catalytic layers, each of the catalytic layers being packed with a formed product of catalyst as secondary particles, wherein the secondary particles in each catalytic layer are formed of primary particles of a catalytically active component having a different particle size, and the particle size of primary particles of the catalytically active component is controlled so that it decreases from an inlet of the reactor to an outlet of the reactor. A method for producing unsaturated aldehydes and/or unsaturated fatty acids from olefins using the same reactor is also disclosed. According to the present invention, it is possible to control the temperature efficiently at a hot spot, thereby permitting a catalyst to be used stably, and to produce unsaturated aldehydes and/or unsaturated fatty acids with high yield.

Disclosed is a method for producing unsaturated aldehydes or unsaturated fatty acids from at least one compound selected from the group consisting of propylene, propane, (meth)acrolein, isobutylene, t-butyl alcohol, methyl-t-butyl ether and o-xylene by means of fixed-bed catalytic partial oxidation in a shell-and-tube reactor, characterized in that the reactor includes a reaction zone for producing unsaturated aldehydes as a main product, the reaction zone having an inactive material layer inserted into a position where a hot spot is to be generated in a reaction tube. A fixed-bed shell-and-tube reactor for use in the above method is also disclosed. According to the present invention, at least one layer of inactive material is packed at the point of a hot spot to control the hot spot temperature efficiently, thereby increasing the lifetime of a catalyst and producing unsaturated aldehydes and unsaturated fatty acids with high yield.

Growing community of inventors

Jeollanam-do, South Korea

Young Hyun Choi