Kureha Corporation

Toyota Jidosha Kabushiki Kaisha

Yoshiyuki Nagasawa

Yasuhiro Suzuki

Takuya Ikeda

Tamito Igarashi

Mitsuyasu Sakuma

Aya Shike

Keisuke Watanabe

Naoki Osada

Shingo Komura

Shota Kobayashi

Yusaku Inaba

Yuichi Hashimoto

Shohei Kawashima

Aya Takeuchi

Kayoko Okada

Yumeno Suzuki

Aya Oikawa

Ryosuke Furuya

Naoko Tohmiya

Masataka Katono

A method for producing an electrode member that configures an electrode body of an all-solid-state battery, including: a slurry preparation step for preparing a mixed material slurry that contains at least a binder, solid electrolyte particles, and a nonaqueous solvent with low polarity; a molding step for molding the mixed material slurry into a desired shape; and a drying step for obtaining a molded body by removing the nonaqueous solvent with low polarity from the mixed material slurry after the molding. Then, the temperature of the mixed material slurry is controlled so as not to cause re-crystallization of the binder, which has been dissolved in the nonaqueous solvent with low polarity, at least until the initiation of the molding step. Consequently, it is possible to stably provide an all-solid-state battery that has low battery resistance, while improving electrode member production efficiency by preventing gelation of a mixed material slurry.

Production method for electrode member

The vinylidene-fluoride-based polymer composition according to the present invention comprises a vinylidene-fluoride-based polymer and a specific surfactant and contains no fluorinated surfactant, wherein the specific surfactant is contained in an amount of 10 ppm or larger but less than 100 ppm in terms of mass ppm of the solid components of the composition and has an HLB value of 10 or greater. The method for producing a vinylidene-fluoride-based polymer according to the present invention comprises emulsion-polymerizing specific monomers in an aqueous medium in the presence of a specific emulsifier and an initiator without using any fluorinated surfactant, the use amount of the emulsifier being 8.5 ppm or larger but less than 100 ppm in terms of mass ppm of the monomers.

Vinylidene fluoride-based polymer composition obtained using non-fluorinated surfactant and production method therefor

Provided is a vinylidene fluoride copolymer particle which is capable of efficiently exhibiting high adhesion between an electrode and a separator. The vinylidene fluoride copolymer particle of the present invention comprises vinylidene fluoride; and

Vinylidene fluoride copolymer particles and use thereof

A binder composition includes a dispersion medium and a group of binder particles. The group of binder particles is dispersed in the dispersion medium. The group of binder particles include a polymer material. The polymer material includes a constitutional unit originated from vinylidene difluoride. The group of binder particles has a number-based particle size distribution. The particle size distribution satisfies the following conditions: '0.19≤X≤0.26', “0.69≤Y≤0.76”, and “0≤Z≤0.05”. Here, “X” represents a frequency of particles each having a particle size of less than or equal to 40 μm. “Y” indicates a frequency of particles each having a particle size of more than 40 μm and less than or equal to 110 μm. “Z” indicates a frequency of particles each having a particle size of more than 110 μm and less than or equal to 250 μm.

Binder composition, method of producing binder composition, and method of producing all-solid-state battery

A resin composition for a non-aqueous electrolyte secondary battery that includes a vinylidene fluoride copolymer having a constituent unit derived from vinylidene fluoride and a constituent unit derived from a fluorine-containing alkyl vinyl compound. A melting point, measured in accordance with ASTM D3418, of the vinylidene fluoride copolymer is from 105&#xb0; C. to 125&#xb0; C., and a mass fraction Wof the constituent unit derived from the fluorine-containing alkyl vinyl compound in the vinylidene fluoride copolymer, a degree of crystallinity Dof the vinylidene fluoride copolymer, and a degree of amorphicity Dof the vinylidene fluoride copolymer satisfy Equation (1) below:4.7&#x2264;&#xd7;()&#x2264;14&#x2003;&#x2003;(1).

Resin composition for nonaqueous electrolyte secondary battery, separator for nonaqueous electrolyte secondary battery using same, resin composition for electrode mixture layer, electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery

The present invention provides a binder composition which suppresses a swelling ratio in an electrolyte solution while having sufficient peel strength. The binder composition according to the present invention contains a copolymer including monomer units derived from vinylidene fluoride, a fluorine-containing alkyl vinyl compound, and a crosslinkable monomer; the content of the monomer unit derived from the fluorine-containing alkyl vinyl compound in the copolymer being not less than 2 mass % and less than 10 mass %; and the content of the monomer unit derived from the crosslinkable monomer being less than 5 mass %.

Binder composition, binder dispersion liquid, electrode mixture, electrode, non-aqueous electrolyte secondary battery, and method for producing binder composition

An object of the present invention is to provide a structure for a non-aqueous electrolyte secondary battery that can be manufactured without going through a complicated process such as passing through a poor solvent. The structure for a non-aqueous electrolyte secondary battery of the present invention comprises a positive electrode, a separator, and a negative electrode, the structure comprising an intermediate layer formed between the positive electrode and the separator and/or between the negative electrode and the separator and including vinylidene fluoride polymer particles constituting 60 to 100 parts by mass per 100 parts by mass of raw materials that constitute the intermediate layer.

Structure for non-aqueous electrolyte secondary battery, non-aqueous electrolyte secondary battery, and method for manufacturing same structure

Provided is a method of manufacturing a negative electrode for a solid-state battery, the method including: a step of mixing a negative electrode active material, a sulfide solid electrolyte, a binder, and a solvent with each other to prepare a negative electrode slurry; a step of applying the prepared negative electrode slurry to a surface of a solid electrolyte layer of the solid-state battery or a substrate of the negative electrode; and a step of drying the applied negative electrode slurry. In this method, the solvent is butyl butyrate, and the binder is a copolymer containing a vinylidene fluoride (VDF) monomer unit and a hexafluoropropylene (HFP) monomer unit, in which a molar ratio of the HFP monomer unit to a total amount of the VDF monomer unit and the HFP monomer unit is 10% to 25%.

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Tokyo, Japan

Yoshiyuki Nagasawa