Daicel Corporation

Tokyo Ohka Kogyo Co., Ltd.

Yoshiya Narasaki

Ichiro Takase

Yasutaka Ishii

Takamasa Suzuki

Dai Shiota

Kunihiro Noda

Hiroki Chisaka

Yasuyuki Akai

Kyuhei Kitao

Daisuke Tanida

A novel vinyl-group-containing fluorene compound and a method for producing the same, a polymerizable monomer and cross-linking agent including this compound, a leaving-group-containing fluorene compound, a monovinyl-group-containing fluorene compound, and methods for producing the same. This vinyl-group-containing fluorene compound is represented by formula (1). In the formula, Wand Wrepresent a group represented by formula (2), a group represented by formula (4), a hydroxyl group, or a (meth)acryloyloxy group, Rand Rrepresent a cyano group, a halogen atom, or a monovalent hydrocarbon, and n1 and n2 are integers of 0-4. In formulas (2) and (4), a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or a group represented by &#x2014;S&#x2014;, Ris a single bond or a C1-4 alkylene group, Ris a specific substituent group such as a monovalent hydrocarbon, and m is an integer of 0 or greater. 

Vinyl-group-containing fluorene compound

Provided is a method of oxidizing a substrate with excellent oxidizing power to yield a corresponding oxide. The method can employ a commercially available imide compound as intact as a catalyst and can produce the oxide in a high yield under mild conditions. A method for producing an oxide according to the present invention includes performing oxidation of a substrate in the presence of oxygen and ozone under catalysis of an imide compound to yield a corresponding oxide. The imide compound has a cyclic imide skeleton represented by Formula (I). In the formula, n is selected from 0 and 1; and X is selected from an oxygen atom and an &#x2014;OR group, where R is selected from hydrogen and a hydroxy-protecting group. 

Method for producing oxide

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Himeji, Japan

Yoshiya Narasaki