Nippon Shokubai Co., Ltd.

Nippon Shokubai Kagaku Kogyo Co., Ltd.

Nippon Shokubai Kagaku Kogyo Kabushiki Kaisha

Yoshikuni Mori

Mitsuo Kushino

Nobuaki Urashima

Hayato Ikeda

Yoshinori Sano

Kenji Minami

Masuji Izubayashi

Yoshihiro Arita

Kiyoshi Kawamura

Shigeru Tanimori

Hironobu Toribuchi

Keiichi Uehara

Yoshinobu Asako

Masatoshi Yoshida

Tadahiro Yoneda

Tatsuhito Matsuda

Hideki Oishi

Tetsuya Yamamoto

Masao Baba

Akio Naka

Masahiro Yoshida

Satoru Ono

Saburo Nakahara

Nobuyuki Ando

Kazuhiro Anan

Iwao Fujikawa

Ryoichi Oshiumi

Yohji Akazawa

Manabu Nishida

Iwao Fukikawa

Hayato Ideda

Shiro Sugiura

An electrorheological fluid composition comprises dielectric particles as a disperse-phase and an electrically insulating oil as a dispersion medium, wherein the dielectric particle has a polymer portion and an electrically conductive carbon black portion and the polymer portion is grafted on the carbon black portion. The electrorheological fluid composition shows a large change in viscosity and the small current properties under an applied electric field, and excellent fluidity and dispersion stability in an absence of an applied electric field.

Electrorheological fluid composition comprising an electrically

A carrier particle which includes a core and a coating layer formed on the surface of the core. The coating layer is made of a coating material including: an organic compound (A) having a functional group other than an Si(OR.sup.1) group, where R.sup.1 is a hydrogen atom, a lower alkyl group or an acyl group; a compound (B) and/or a hydrolytic condensation product thereof, having a functional group having reactivity with the functional group of the organic compound (A), and an Si(OR.sup.1) group; an organometallic compound (C) and/or a hydrolytic condensation product thereof; and a solvent (D). The carrier particles of the present invention, enable toner particles to be sufficiently charged even at high temperature and high humidity, so that an image with no fog can be formed. In addition, the carrier particle has high durability. There is no unnecessary attachment of the toner particles onto the carrier particles, so that the problems of carrier particle contamination and spent toner never arise.

Carrier particles for use in electrostatic image development and

Carbon black graft polymer, method for production thereof, and use

A method for the recovery of microfine suspended particles from a suspension medium, characterized by subjecting a polymeric monomer suspended in a suspension medium to suspension polymerization thereby forming microfine globular particles in the suspension solution, adding microfine water-insoluble particles to said suspension solution of microfine globular particles thereby inducing cohesion of said microfine globular particles, and separating said microfine globular particles in the form of an aggregate from said suspension solution filtration.

Method for production of microfine colored particles and

A polymeric monomer (A) having as a main component thereof a (meth)acryl type monomer which is subjected to aqueous suspension polymerization in the presence of a compound (B) which is substantially insoluble in water and sparingly soluble in the polymeric monomer (A). The compound (B) has at least one, preferably two or more, structural units, selected from the group consisting of --SH, --S--S--, --COOH, --NO.sub.2, and --OH. The use of compound (B), in the suspension polymerization of the (meth)acryl type monomer, represses of the production of by-produced minute particles due to sympathetic emulsion polymerization. The suspension polymerization permits production of (meth)acryl type polymer particles having high heat stability and a small range of particle diameters.

Resinous particles, method for production thereof, and uses therefor

A suspension polymerization of a polymerizable monomer in the presence of an emulsion polymerization inhibitor is disclosed. The inhibitor is an aromatic series compound having a NO.sub.2 group, a SO.sub.3 Na group, and a secondary amino group, representatively, the following compound. In this suspension polymerization, the production of by-produced microfine particles caused by the emulsion polymerization as the secondary polymerization scheme is repressed. ##STR1##

Emulsion polymerization inhibitor and suspension polymerization method

A method for the production of microfine colored particles, characterized by subjecting a polymeric monomer suspended in a suspension medium to suspension polymerization in the presence of a coloring agent and/or a magnetic powder thereby forming microfine globular colored particles possessing an average particle diameter in the range of from 3 to 50 .mu.m, heat treating said microfine globular colored particles with water as a heating medium at a temperature in the range of from 50.degree. C. to 130.degree. C. thereby inducing fusion of said particles and giving rise to blocks of fused particles, and then disintegrating said blocks of particles to an average particle diameter substantially equal to the average particle diameter of said microfine globular colored particles existent prior to said fusion.

A polymeric monomer (A) having as a main component thereof a (meth)acryl type monomer which is subjected to aqueous suspension polymerization in the presence of a compound (B) which is substantially insoluble in water and sparingly soluble in the polymeric monomer (A). The compound (B) has at least one, preferably two or more, structural units, selected from the group consisting of --SH, --S--S--, --COOH, --NO.sub.2, and --OH. The use of compound (B), in the suspension polymerization of the (meth)acryl type monomer, represses of the production of by-produced minute particles due to sympathetic emulsion polymerization. The suspension polymerization permits production of meth)acryl type polymer particles having high heat stability and a small range of particle diameters.

A thermosensitive recording material comprising a recording layer formed on a substrate and a coating film layer formed thereon, wherein the recording layer is of a bilayer structure composed of a first thermosensitive layer on the side of the lower layer and a second thermosensitive layer on the side of the upper layer and particles are dispersed in at least one of the first and second thermosensitive layers. An original plate for lithographic printing can be produced from a combination of an ink-philic resin and an ink-repelling resin as the compositional materials of such thermosensitive layers. Besides, thermosensitive, recording materials for magnetic recording, thermosensitive materials for electrostatic recording, thermosensitive recording materials for colored image recording and the like, can be generated through a variety of modifications of the compositional materials. Then, the use of such thermosensitive recording materials attains thermosensitive recording at a higher precision through simple processes and procedures.

Thermosensitive recording material and thermosensitive recording method

This invention discloses a toner characterized by the toner particles thereof severally possessing a sea-island-lake structure wherein a crystalline (meth)acrylic ester type polymer is present in the form of a plurality of domains in a matrix of a binder resin and a portion of the binder resin is present in the form of a plurality of domains in each of the domains of the polymer. The melt viscosity of the crystalline (meth)acrylic ester type polymer is not less than 50 cPs at 140.degree. C. The toner combines an ability to resist the phenomenon of offset with ideal particle flowability, stability of storage, and charging characteristics.

Toner and method for production thereof

Spherical fine particles of colored resin are provided. The fine particles are of a spherical shape and are superior in heat resistance, solvent resistance, and chemical resistance, and sufficiently satisfactory in durability and coloring, and industrially advantageous. The spherical fine particles of colored resin are made by incorporating an amino resin cured matter and an inorganic pigment into one body, and a ratio of the inorganic pigment against a total amount of the amino resin cured matter and inorganic pigment is in a range of from about 1 to 30% by weight.

Method for producing spherical fine particles of colored resin

Coloring fine particles produced by heating spheroidal coloring fine particles with an average fine particle diameter of 1-100 .mu.m obtained by suspension polymerization to a temperature of 30.degree. to 200.degree. C., thereby causing the particles to fuse together in a block without completely destroying the particle interfaces, and then crushing the block to substantially the same average particle diameter of the spheroidal coloring particles before melting, and a toner for developing electrostatic images using the same.

Coloring fine particles and toner for developing electrostatic images

Coloring fine particles produced by heating spheroidal coloring fine particles with an average fine particle diameter of 1-100 .mu.m obtained by suspension polymerization to a temperature of 30.degree. to 200.degree. C., thereby causing the particles to fuse together in a block without completely destroying the particle interfaces, and then crushing the block to substantially the same average particle diameter of the spheroidal coloring particle before melting, and a toner for developing electrostatic images using the same.

Coloring fine particle and toner for developing electrostatic images

A carbon black-graft polymer, produced by causing a polymer possessing within the molecular unit thereof at least one reactive group selected from the class consisting of aziridine group, oxazoline group. N-hydroxyalkylamide group, epoxy group, and thioepoxy group to react with carbon black. The polymer can be used as a toner for electrostatically charged image, resin composition, coating composition, ink for thermographic transfer, coating agent for magnetic recording medium, rubber composition, and carbon black dispersion and the like.

Carbon black-graft polymer, method for production thereof, and use

Colored microfine globular particles are produced by causing carbon black to react with a polymer capable of reacting with the carbon black thereby forming a carbon black-graft polymer, dispersing this carbon black-graft polymer in a polymerizable monomer component, and then polymerizing the polymerizable monomer component. These particles, in the unmodified form, are usable as a toner for the development of images of static charge and, in a form incorporated in a varying component, are usable such as in resin composition, coating composition, thermosensitive transfer ink ribbon coating agent, thermosensitive transfer ink, or back-coating agent for magnetic recording medium.

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Takatsuki, Japan

Yoshikuni Mori