Cosmo Oil Co., Ltd.

Cosmo Research Institute

Maruzen Oil Co. Ltd.

Yoshihiro Kojima

Sanae Ueda

Takashi Hori

Hitoshi Kumagai

Masato Goto

Makoto Nishishita

Shinji Yamaoka

Disclosed is a process for producing a mixture of sulfurized alkaline earth metal salts of a salicylic acid compound and a phenol which comprises reacting either a mixture of reactants comprising a phenol, a dihydric alcohol, and an alkaline earth metal oxide and/or hydroxide or a mixture of these reactants and water, subsequently distilling off water and the dihydric alcohol, reacting the resulting bottom with carbon dioxide, and then adding a dihydric alcohol and elemental sulfur to the resulting reaction product to conduct sulfurization reaction.

Process for producing mixture of sulfurized alkaline earth metal salts

A process for the production of an over based alkaline earth metal phenate (sulfurized, unsulfurized or a mixture thereof), in which the process comprises the steps of: effecting reactions among phenols, dihydric alcohols and an alkaline earth metal reagent (alkaline earth metal oxide or hydroxide or a mixture thereof), or among these compounds further mixed with sulfur and/or water; removing an excess of the dihydric alcohols and at least an excess of water by distillation; and subsequently treating resulting distillation residue with carbon dioxide, wherein the improvement resides in that the carbon dioxide treatment is carried out in the presence of water in an amount of from 0.01 to 1.0 mol per 1 mol of the alkaline earth metal reagent. Preferably, the carbon dioxide treatment is carried out in the presence of 0.1 to 0.7 mol sulfur and 0.1 to 1.0 mol water per 1 mol of the alkaline earth metal reagent. The process of this invention is industrially advantageous because the alkaline earth metal phenate obtained by the process has a high basicity and an easily handleable low viscosity and is useful as a high quality detergent for a lubricating or fuel oil.

Process for producing over-based alkaline earth metal phenate

A process for producing an over-based sulfurized alkaline earth metal phenate type detergent, which comprises reacting a phenol and a dihydric alcohol with an alkaline earth metal reagent to carry out a metal addition reaction, and reacting sulfur therewith to carry out a sulfurization reaction, and then reacting carbon dioxide therewith to carry out a carbon dioxide treatment, characterized in that the metal addition reaction and the sulfurization reaction are carried out under pressure and closed conditions. The sulfurization reaction may be carried out simultaneously with the metal addition reaction, or, alternatively, with the carbon dioxide treatment after the metal addition reaction. Furthermore, the sulfurization reaction may be carried out between the metal addition reaction and the carbon dioxide treatment.

Process for producing over-based sulfurized alkaline earth metal phenate

A process for producing a mixture of sulfides of alkaline earth metal salts of an alkylhydroxybenzoic acid and an alkylphenol comprising the steps of: reacting a mixture of a phenol, a dihydric alcohol and an alkaline earth metal oxide and/or hydroxide (hereinafter referred to as an alkaline earth metal reagent) in an amount of no more than 0.99 gram equivalents per gram equivalent of said phenol; distilling off water and the dihydric alcohol until the amount of the dihydric alcohol becomes no more than 0.6 moles per mole of the alkaline earth metal reagent; reacting the resulting distillation residue with carbon dioxide; and reacting the resulting product with elemental sulfur in an amount of 0.1-4.0 moles per mole of the alkaline earth metal reagent.

Process for producing a mixture of sulfides of alkaline earth metal

A process for the production of a basic alkaline earth metal phenate is disclosed. The process comprises reacting a phenol, a dihydric alcohol, and an alkaline earth metal agent selected from alkaline earth metal oxides and hydroxides to achieve the addition of the alkaline earth metal to the phenol, wherein water is added to the reaction system in an amount of from 0.01 to 10 mols per mol of the alkaline earth metal agent. This basic alkaline earth metal phenate is useful as an additive for lubricating oils and fuel oils.

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Ibaraki, Japan

Yoshihiro Kojima