Mazda Motor Corporation

Dainippon Ink and Chemicals, Incorporated

Nof Corporation

Madza Motor Corporation

Yoshiaki Marutani

Kazuhi Koga

Mika Ohsawa

Hiroyuki Uemura

Goro Iwamura

Tadamitsu Nakahama

Shigeki Matsui

Hiroshi Kubota

Takashi Tomita

Shinji Sasaki

Ichiro Azuma

Norio Kosaka

Toshio Yamamoto

Hiroki Kagawa

Yasuyuki Takeuchi

A one-pack coating composition is disclosed. The composition comprises (A) an oligomer or polymer containing an acid anhydride group, a blocked hydroxyl group and an epoxy group as indispensable functional groups in the same or different molecules, (B) a heat-potential curing catalyst which comprises a complex of an organometallic compound and an electron-donating compound or an onium salt and which exhibits its activity upon heating, (C) an ultraviolet absorber comprising a triazine or oxalic anilide, and (D) a hindered amine light stabilizer having a piperidine ring of the following structure:

One-pack coating composition and coating method using the same

Thermosetting compositions, coating compositions method of coating, and

The present invention is to provide a low solvent content type-coating composition by which the resultant coatings with good scuff resistance or water resistance as well as good chipping resistance are produced, while the content of an organic solvent to be used can be much reduced. The low solvent content type-coating composition comprises a polyester oligomer having a hydroxyl group in an amount of 2.0 to 10.0 moles/Kg-resin, a number average molecular weight (Mn) of 300 to 1500, a weight average molecular weight (Mw) of 300 to 3000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1 to 2.0, an amount of a modifying lactone being 31 to 85%, and an aliphatic hydrocarbon group of C4-22 which is not derived from lactones. The present invention is also to provide a process for coating a low solvent content type-coating composition on, for example, a base coating composition by a wet-on-wet coating. The base coating composition comprises a vinyl oligomer having a hydroxyl group and/or a blocked hydroxyl group, a melamine resin containing 50 to 100% of an imino type or methylol type mononucleus melamine and a weak acidic curing catalyst.

Low solvent content type-resin composition, coating composition

A coating method is disclosed, which comprises coating a base coating paint on a substrate, coating thereon a clear coating paint of a curing system different from that of the base coating paint in a wet-on-wet state, and then baking the resultant coatings, wherein a curing catalyst for curing the clear coating paint is incorporated into the base coating paint and wherein the curing catalyst has a boiling point of 150.degree. C. or higher under 760 mmHg. The base coating paint comprising such a curing catalyst is also disclosed.

Method for forming coating and base coating paint used therefor

The present invention provides a curable resin composition incorporating an oligomer containing blocked hydroxyl group, an epoxy-group containing compound, hydrolytic silyl-group containing compound, and a dissociation catalyst and/or curing catalyst, each possessing a specific molecular weight; a paint which uses this resin composition as a binder; and a coat-finishing method which coat-finishes any desired material using the aforementioned resin composition and paint. According to the present invention, it is possible to reduce viscosity, and consequently increase the coat non-volatile content and hence improve acid resistance, abrasion resistance, and the like. In addition, according to the present invention, it is possible to obtain a curable resin composition, paint using this curable resin composition, and coat-finishing method for this paint in which the aforementioned resin and paint have an extremely high utility and possess a high solid content wherein air bubbles and drip-runs are not generated.

Curable resin composition, paint using the same, and coat-finishing

A coating for polyolefin molding compositions comprises (1) (a) from 40-90% by weight of a chlorinated polyolefin grafted with a vinyl-polymerizable monomer having a hydroxyl group at a position 15 to 40 atoms distant from the main chain of vinyl polymer grafted onto the chlorinated polyolefin, or (b) from 50 to 90% by weight of a vinyl polymer obtained by polymerizing from 5 to 40% by weight of a hydroxyl group-containing (meth)acrylate monomer having a carbon chain derived from an alcohol residue with from 6 to 18 carbon atoms, and a vinyl-polymerizable monomer having a hydroxyl group at a position 15 to 40 atoms distant from the vinyl group, wherein the vinyl polymerizable monomer is derived from the reaction product of a vinyl-polymerizable monomer having a hydroxyl group at a position 2 to 12 atoms distant from the vinyl group and a lactone, and (2) from 10 to 60 or 50% by weight of a melamine resin containing methylol, alkoxy or imino groups.

Coating for polyolefin containing copolymer of monomer with distant OH

There are disclosed a high solids content resin composition excellent in solubility in an organic solvent, comprising an acrylic oligomer having a blocked hydroxyl group, a curing agent having a reactivity with a hydroxyl group and a dissociation or curing catalyst, and a high solids content type paint using the resin composition. There are also disclosed a coating process and a baking process comprising coating and baking the resin composition or the paint while rotating a material to be coated at an appropriate speed. The resin composition and the paint of the present invention have substantially no sagging and solvent popping. Further, the thus obtained paint film have improved smoothness, solvent resistance, weather resistance and resistance to scratching.

High solids content resin composition, high solids content type paint,

The present invention relates to a low solvent content-type resin composition, a low solvent content-type coating composition containing such a resin composition as a binder, and a method for coating such a coating composition. The resin composition comprises an oligomer containing an alicyclic epoxy group in a molecule and having a number average molecular weight (Mn) of 300 to 2000, a weight average molecular weight (Mw) of 300 to 4000 and an Mw/Mn ratio of 1 to 2.5. The coating composition comprises such a resin composition and a cationic polymerization catalyst, wherein the content of an organic solvent content is 0 to 40 wt. %. Since the present composition contains a low molecular weight oligomer, the viscosity of the composition is low even though the solid content is high. Accordingly, the content of the organic solvent can be much reduced.

Low solvent composition of alicyclic epoxy oligomer

The present invention relates to a coating composition which is excellent in handling and safety, enables the curing of the resultant coating composition at low temperature, and provides an excellent adhesion to polyolefin resin moldings. The coating composition comprises (1) 40-90 wt. % of a grafted and chlorinated polyolefin oligomer obtained by graft polymerizing a vinyl polymerizable monomer to a chlorinated polyolefin, the grafted and chlorinated polyolefin oligomer having a primary or blocked primary hydroxyl group at a position of 15 to 40 atoms away from the vinyl graft polymer chain grafted to the chlorinated polyolefin, a number average molecular weight of 5,000 to 50,000, 0.4 to 2.5 mole/kg-resin of a primary or blocked primary hydroxyl group, 50 to 95 wt. % of said vinyl graft polymer chain, and 5 to 50 wt. % of the chlorinated polyolefin used as a starting material, and (2) 60 to 10 wt. % of an imino-type, methylol-type or complete alkoxy-type melamine resin. The present coating composition can be cured by baking the coating composition at 90.degree. to 120.degree. C.

Resin composition used in coating composition for coating polyolefin

A coating method is disclosed, which comprises coating a base coating paint on a substrate, coating thereon a clear coating paint of a curing system different from that of the base coating paint in a wet-on-wet state, and then baking the resultant coatings, wherein a curing catalyst for curing the clear coating paint is incorporated into the base coating paint and wherein the curing catalyst has a boiling point of 150.degree. C. or higher, under 760 mmHg. The base coating paint comprising such a curing catalyst is also disclosed.

The present invention relates to a low solvent content type-coating composition which provides the resultant coating with improved surface appearance, acid resistance, alkali resistance, weathering resistance, scuff resistance and solvent resistance, while the content of an organic solvent of the coating composition can be much reduced to 0 to 30% at 25.degree. C. The low solvent content type-coating composition comprises a vinyl oligomer having a blocked carboxyl group and an additional group selected from an epoxy group, a silanol group, a hydrolyzable silyl group and an acid anhydride group. The vinyl oligomer has a number average molecular weight (Mn) of 600 to 2000, a weight average molecular weight (Mw) of 600 to 5000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1.0 to 2.5. The blocked carboxyl group and an additional group may be present in the same or different vinyl oligomers.

Growing community of inventors

Hiroshima, Japan

Yoshiaki Marutani