Grirem Advanced Materials Co., Ltd.

Grirem Hi-tech Co., Ltd.

Rare Earth Functional Materials (xiong'an) Innovation Center Co., Ltd.

Yongke Hou

Xiaowei Huang

Meisheng Cui

Hongwei Li

Dali Cui

Zhiqi Long

Qiang Zhong

Lei Wang

Hao Wang

Qi Wang

He Fang Zhang

Liangshi Wang

Ying Yu

Zongyu Feng

Xinlin Peng

Guilin Yang

Chunmei Wang

Yongqi Zhang

Shunli Zhang

Zhizhe Zhai

Mei Yue

The present invention discloses a rare-earth-manganese/cerium-zirconium-based composite compound, a method for preparing the same, and a use thereof. The composite compound is of a core-shell structure with a general formula expressed as: A REBO-(1-A)CeZrMO, wherein 0.1≤A≤0.3, preferably 0.1≤A≤0.2; a shell layer has a main component of rare-earth manganese oxide with a general formula of REMnO, wherein RE is a rare-earth element or a combination of more than one rare-earth elements, and B is Mn or a combination of Mn and a transition metal element, 1≤a≤8, 2≤b≤18, and 0.25≤c≤4; and a core has a main component of cerium-zirconium composite oxide with a general formula of CeZrMO, wherein M is one or more non-cerium rare-earth elements, 0.1≤x≤0.9, 0≤y≤0.3, and 0.01≤z≤0.3. The composite compound enhances an oxygen storage capacity of a cerium-zirconium material through an interface effect, thereby increasing a conversion rate of a nitrogen oxide.

Rare-earth-manganese/cerium-zirconium-based composite compound, method for preparing same and use thereof

Provided are a cerium-zirconium composite oxide, a preparation method therefor and application of a catalyst. The cerium-zirconium composite oxide has a composite phase structure, and comprises a cerium oxide phase and a cerium-zirconium solid solution phase, or consists of two or more cerium-zirconium solid solution phases with different crystal structures and different chemical compositions, wherein the chemical formula of the cerium-zirconium solid solution phase is CeZrMO, where M is at least one selected from the group consisting of a rare earth element other than cerium, a transition metal element and an alkaline earth metal element, x is 15-85 mol %, and y is 0-20 mol %.

Cerium-zirconium composite oxide, preparation method therefor, and application of catalyst

The present invention provides a cerium oxide based composite polishing powder and a preparation method thereof. The polishing powder contains the element magnesium in an amount of 0.005 wt %-5 wt % to magnesium oxide meter. The preparation method includes: (1) uniformly mixing a salt solution containing cerium serving as the main component of the polishing powder; (2) uniformly mixing a precipitating agent of an aqueous magnesium bicarbonate solution with the mixed solution prepared in step (1) to obtain a slurry; (3) aging the slurry prepared in step (2) for 0-48 h while the temperature of the slurry is kept at 30-90 degrees centigrade, and filtering the aged slurry to obtain the precursor powder of the polishing powder; (4) calcinating the precursor powder at 600-1000 degrees centigrade, then dispersing and separating the calcinated precursor powder to obtain the polishing powder. The present invention improves the polishing performance and the suspension performance of polishing powder.

Cerium oxide based composite polishing powder and preparation method thereof

The present invention relates to a method of precipitation of metal ions. Mineral(s), oxide(s), hydroxide(s) of magnesium and/or calcium are adopted as raw materials, and the raw material(s) is processed through at least one step of calcination, slaking, or carbonization to produce aqueous solution(s) of magnesium bicarbonate and/or calcium bicarbonate, and then the solution(s) is used as precipitant(s) to deposit rare earth, such as nickel, cobalt, iron, aluminum, gallium, indium, manganese, cadmium, zirconium, hafnium, strontium, barium, copper and zinc ions. And at least one of metal carbonates, hydroxides or basic carbonates is obtained, or furthermore the obtained products are calcined to produce metal oxides. The invention takes the cheap calcium and/or magnesium minerals or their oxides, hydroxides with low purity as raw materials to instead common precipitants such as ammonium bicarbonate and sodium carbonate etc. The calcium, magnesium, carbon dioxide etc are efficiently and circularly used, and the environment pollution by ammonium-nitrogen wastewater, high concentration salts wastewater is avoided, and both of the discharge of greenhouse gas carbon dioxide and the production cost of metal are decreased.

Method of precipitation of metal ions

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Beijing, China

Yongke Hou