Guangdong Kaijin New Energy Technology Co., Ltd.

Zhuhai Essex Bio-Pharmaceutical Co., Ltd.

Yongjun Yang

Anhua Zheng

Dexin Yu

Bo Yang

Haizhou Fang

Xinzhi Wang

Luo Yan

Malcolm Ngiam

Peimin Dai

Qi Xue

Chuanchang Ge

La Ma

A carbon-based anode material having a surface formed with slightly oxidized pores, includes by weight: 10-30 parts of clay minerals, 5-8 parts of chitosan, 0.1-1 part of a cationic polymer, 0.1-1 part of tris-1-(2-methylaziridinyl) phosphine oxide, 3-8 parts of a conductive agent, 3-8 parts of absolute ethyl alcohol, 1-3 parts of potassium oxalate, and 10-15 parts of a binder. According to the invention, the cationic polymer and the tris-1-(2-methylaziridinyl) phosphine oxide are added on the basis of the chitosan and the clay minerals, the cationic polymer contains polynuclear olation complex ions with a high positive electrovalence, thus being able to closely adhering to the surface of clay to form a three-dimensional net structure, so multiple slightly oxidized pores are formed in the surface of the obtained carbon-based material in a carbonization process, and the finally obtained carbon-based anode material has good charge-discharge performance and cycle performance.

Carbon-based anode material having surface formed with slightly oxidized pores, and method for preparing same

The present invention relates to the field of anode materials of lithium batteries, and in particular, relates to a silicon/carbon composite material with a highly compact structure. The silicon/carbon composite material with the highly compact structure includes silicon particles and a carbon coating layer, and further includes a highly compact carbon matrix, wherein the silicon particles are distributed inside the highly compact carbon matrix evenly and dispersively and forms an inner core; and the silicon/carbon composite with the highly compact structure is compact inside without voids or has few closed voids inside. The present invention provides the silicon/carbon composite material with the highly compact structure with a reduced volumetric expansion effect and an improved cycle performance, a method for preparing the same, and a use thereof.

Silicon/carbon composite material with highly compact structure, method for preparing same, and use thereof

A three-dimensional porous silicon/carbon composite material includes a three-dimensional porous skeleton, a filler layer, and a coating layer. The three-dimensional porous skeleton is a three-dimensional porous carbon skeleton; the filler layer includes silicon particles and conductive carbon; the filler layer is formed by scattering the silicon particles evenly and dispersively in the conductive carbon; and the coating layer is a carbon coating layer. The present invention provides the three-dimensional porous silicon/carbon composite material with long cycle and low expansion, a method for preparing the same, and a use thereof.

Three-dimensional porous silicon/carbon composite material, method for preparing same, and use thereof

A silicon-carbon composite material includes a matrix core, a silicon-carbon composite shell formed by uniformly dispersing nano silicon particles in conductive carbon, and a coating layer. The nano silicon particles are formed by high-temperature pyrolysis of a silicon source, and the conductive carbon is formed by high-temperature pyrolysis of an organic carbon source. The coating layer is a carbon coating layer including at least one layer, and the thickness of its single layer is 0.2-3 μm. A silicon-carbon composite material precursor is formed by simultaneous vapor deposition and is then subjected to carbon coating to form the pitaya-like silicon-carbon composite material which has advantages of high first-cycle efficiency, low expansion and long cycle. The grain growth of the silicon material is slowed down during the heat treatment process, the pulverization of the material is effectively avoided, and the cycle performance, conductivity and rate performance of the material are enhanced.

Silicon-carbon composite material and preparation method thereof

Provided are a method for producing a soluble recombinant human-basic fibroblast growth factor (rh-bFGF), a recombinant human-basic fibroblast growth factor (rh-bFGF) obtained by the method, and a mutated nucleic acid molecule encoding the recombinant human-basic fibroblast growth factor (rh-bFGF).

Growing community of inventors

Guangdong, China

Yongjun Yang