University System of Maryland

The Johns Hopkins University

Yonggang Yao

Liangbing Hu

Chao Wang

Tian Li

Pengfei Xie

Yanan Chen

Disclosed are single atom dispersions and multi-atom dispersions, and systems and methods for synthesizing the atomic dispersions. An exemplary method of synthesizing atomic dispersions includes: positioning a loaded substrate which includes a substrate which is loaded with at least one of: a precursor of an element or a cluster of an element, applying one or more temperature pulses to the loaded substrate where a pulse of the temperature pulse(s) applies a target temperature for a duration, maintaining a cooling period after the pulse, and providing single atoms of the element dispersed on the substrate after the one or more temperature pulses. The target temperature applied by the pulse is between 500 K and 4000 K, inclusive, and the duration is between 1 millisecond and 1 minute, inclusive.

Systems and methods for high temperature synthesis of single atom dispersions and multi-atom dispersions

A catalytic structure has a plurality of high-entropy alloy (HEA) nanoparticles. Each HEA nanoparticle is composed of a homogeneous mixture of elements of cobalt (Co), molybdenum (Mo), and at least two transition metal elements. For example, in some embodiments, each HEA nanoparticle is a quinary mixture of Co, Mo, iron (Fe), nickel (Ni), and copper (Cu). The homogeneous mixture in each HEA nanoparticle forms a single solid-solution phase. The catalytic structure is used to catalyze a chemical reaction, for example, ammonia decomposition or ammonia synthesis. Methods for forming the catalytic structure are also disclosed.

High-entropy alloy (HEA) catalysts, methods of forming HEA catalysts, and methods of using HEA catalysts

A formation of multielement nanoparticles is disclosed that includes at least three elements. Each of the at least three elements is uniformly distributed within the multielement nanoparticles forming nanoparticles having a homogeneous mixing structure. At least five elements may form a high-entropy nanoparticle structure. A method for manufacturing a formation of multielement nanoparticles includes providing a precursor material composed of the at least three component elements in multielement nanoparticles; heating the precursor material to a temperature and a time; and quenching the precursor to a temperature at a cooling rate to result in a formation of multielement nanoparticles containing at least three elements and the heating and the quenching representing a multielement nanoparticle thermal shock formation process. A corresponding system for manufacturing the formation of multielement nanoparticles and a method of using the multielement nanoparticles are also disclosed.

Thermal shock synthesis of multielement nanoparticles

Systems and methods of synthesizing nanoparticles on substrates using rapid, high temperature thermal shock. A method involves depositing micro-sized particles or salt precursors on a substrate, and applying a rapid, high temperature thermal shock to the micro-sized particles or the salt precursors to become nanoparticles on the substrate. A system may include a rotatable member that receives a roll of a substrate sheet having micro-sized particles or salt precursors; a motor that rotates the rotatable member so as to unroll the substrate; and a thermal energy source that applies a short, high temperature thermal shock to the substrate. The nanoparticles may be metallic, ceramic, inorganic, semiconductor, or compound nanoparticles. The substrate may be a carbon-based substrate, a conducting substrate, or a non-conducting substrate. The high temperature thermal shock process may be enabled by electrical Joule heating, microwave heating, thermal radiative heating, plasma heating, or laser heating.

Nanoparticles and systems and methods for synthesizing nanoparticles through thermal shock

A porous base substrate is infiltrated with a polymer material to form a hybrid substrate that combines the optical advantages of both. Prior to infiltration, the base substrate may exhibit relatively low optical transmittance. For example, the base substrate may be paper, textiles, aerogels, natural wood, or any other porous material. By infiltrating the base substrate with a polymer having a similar refractive index to that of the material of the base substrate, the transmittance can thus be improved, resulting in, for example, a transparent hybrid substrate that exhibits both relatively high optical haze and relatively high optical transmittance within the visible light spectrum. The hybrid substrate can thus serve as a base for fabricating electronic devices or can be coupled to electronic devices, especially optical devices that can take utilize the unique optical properties of the hybrid substrate.

Growing community of inventors

College Park, MD, United States of America

Yonggang Yao