Petrochina Company Limited

Sophonix Co., Ltd.

Yongcheng Sun

Ning Zhang

Jingyuan Zhang

Qian Chen

Haiyang Zhang

Sihan Wang

Yongjun Zhang

Hongxia Chen

Guizhi Wang

Baojun Zhang

Shiliang Zhou

Deshun Zhang

Shukun Sun

Jianzhong Li

Huimin Yuan

Yulong Li

Yunguang Han

Kuiliang Han

Xiqiang Zhang

Lihua Xing

Yingnan Ning

Dongting Kuang

The present application relates to a photon measuring and reading device, which belongs to the field of detection equipment, including a mounting seat and a photon counter. The photon counter can move up and down on the mounting seat. The mounting seat is provided with a vertically arranged sliding trough, and the photon counter is provided with a sliding rod slidably connected with the sliding trough. A double head motor is arranged on the mounting base, and a linkage mechanism is arranged between the output shaft at the tail end of the double head motor and the sliding rod. The bottom end of the photon counter is fixed with a box body.

Photon measuring and reading device

The present invention relates to a catalyst composition for ethylene oligomerization and the use thereof. Such catalyst composition includes chromium compound, ligand containing P and N, activator and accelerator; wherein the chromium compound is selected from the group consisting of acetyl acetone chromium, THF-chromium chloride and Cr(2-ethylhecanoate); general formula of the ligand containing P and N is shown as: in which R, R, Rand Rare phenyl, benzyl, or naphthyl. Ris isopropyl, butyl, cyclopropyl, cyclopentyl, cyclohexyl or fluorenyl; the activatior is methyl aluminoxane, ethyl aluminoxane, propyl aluminoxane and/or butyl aluminoxane; the accelerator is selected from the group consisting of 1,1,2,2,-tetrachloroethane, 1,1,2,2-tetrabromoethane, 1,1,2,2-tetrafluoroethane, and compounds having a formula of XRX, in which Xand Xare F, Cl, Br, I or alkoxyl, Ris alkylene or arylene group; the molar ratio of chromium compound, ligand containing P and N, activator and accelerator is 1:0.5&#x2dc;10:50&#x2dc;3000:0.5&#x2dc;10. After mixing the four components mentioned previously under nitrogen atmosphere for 10 minutes, they are incorporated to the reactor, or these four components are incorporated directly into the reactor. Then ethylene is introduced for oligomerization. Such catalyst can be used in producing 1-octene through ethylene oligomerization. It is advantageous in high catalysing activity, high 1-octene selectivity, etc. The catalytic activity is more than 1.0&#xd7;10g product&#xb7;maCr&#xb7;h, the fraction of Clinear &#x3b1;-olefin is more than 70% by mass.

Catalyst composition for ethylene oligomerization and the use thereof

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Beijing, China

Yongcheng Sun