Korea Institute of Science and Technology

Samsung Electronics Co., Ltd.

Yong Soo Kang

Hoon Sik Kim

Jongok Won

Bum Suk Jung

Un Young Kim

Hyun Chae Park

Jong Ok Won

Hyun Joo Lee

Byung Gwon Lee

Sang Cheol Park

Jae Hee Ryu

Jong Hak Kim

Jee Won Choun

Jung Hak Nam

SAng Hyeon Kang

Young Jin Kim

Young Jun Park

Won Cheol Jung

Heung Yong Ha

Byung Hee Sohn

Byung-hee Sohn

Jae Jin Kim

In-Hwan Oh

Kookheon Char

Chul J Lee

Kook Heon Char

Moon Sung Kang

Hyun Chul Park

Jae Min Hong

Kyu Hong Ahn

Young Gun Lee

Hye Hun Park

Seong Geun Oh

Seong Hyun Yoo

Sung W Song

Bumsuk Jung

Seong Ryong Ha

Jae Sik Na

Yong Gun Lee

Sang Wook Kang

Sangwook Choi

Yeo Sang Yoon

Bum-Suk Jung

Disclosed herein is a method for modifying the surface of a counter electrode. According to the method, the surface modification is achieved by treating the surface of a counter electrode with a polyethylene glycol derivative having a pendant group at one end. Also disclosed is a counter electrode whose surface is modified by the method. The electron transfer rate at the interface between the counter electrode and an electrolyte layer of a photovoltaic device is increased and the affinity of the counter electrode for the electrolyte layer is improved, resulting in an improvement in the power conversion efficiency of the photovoltaic device.

Method for modifying surface of counter electrode and surface-modified counter electrode

A dye-sensitized solar cell using an ion-bound oligomer complex is provided. The dye-sensitized solar cell comprises an electrolyte, comprising a first oligomer having a Cheteroaryl group containing a nitrogen heteroatom as a basic functional group at both ends of the molecule, mixed with a second oligomer having an acidic functional group selected from among carboxylic acid, phosphoric acid, and sulfonic acid, at both ends of the molecule, to thus form a salt, which then leads to an ion-bound oligomer complex that constitutes the electrolyte. The solar cell exhibits excellent mechanical properties, can be manufactured conveniently, and can have a high energy conversion efficiency.

Dye-sensitized solar cell using ion-bound oligomer complex and method of manufacturing the same

Disclosed is a solid state dye-sensitized solar cell employing a composite polymer electrolyte, which includes a photoelectrode, a counter electrode, and an electrolyte interposed between the photoelectrode and counter electrode. The electrolyte includes at least one of a middle molecular substance, a polymer mixture, and inorganic nanoparticles, and a redox derivative. The dye-sensitized solar cell reduces crystallinity of the polymer electrolyte to significantly increase ionic conductivity, and enables the polymer electrolyte to smoothly permeate into a titanium oxide layer to improve mechanical properties, thereby significantly increasing energy conversion efficiency. Accordingly, the dye-sensitized solar cell assures high energy conversion efficiency without an electrolyte leak, and thus, it can be stably and practically used for a long time.

Solid state dye-sensitized solar cell employing composite polymer electrolyte

There is provided a nanocomposite membrane comprising an Ag-nanoparticle/polymer nanocomposite, in which the Ag-particles are uniformly dispersed in the polymer matrix, and a support membrane for supporting the nanocomposite, as well as a process of preparing said membrane. The nanocomposite membrane of the present invention comprising a neutral Ag-nanoparticle as an olefin carrier, which is chemically stable, has excellent long-term operation performance characteristics as well as high selectivity and permeability. Thus, it can be advantageously used for the separation of olefin from an olefin/paraffin mixture.

Silver nanoparticle/polymer nanocomposite membranes for olefin/paraffin separation and method of preparing the same

The present invention relates to a facilitated transport membrane for separation of alkene hydrocarbons from hydrocarbon mixtures, comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure, in which the electrolyte is in solid state at its operating temperature. The facilitated transport membrane is prepared by forming a solid polymer electrolyte consisting of a transition metal salt and a polymer on a porous support. The transition metal salt can selectively and reversibly form a complex with alkene hydrocarbons and the polymer can dissociate the transition metal salt. In particular, the polymer matrix allows the transition metal salt to be well dissociated because it has a phthalic structure capable of being coordinated to a transition metal ion.

Facilitated transport membranes comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure

An ion exchange composition membrane is made up of dispersed natural clay and/or organized clay in ion conducting polymeric film as a methanol barrier material. The membrane exhibits low methanol crossover, high proton conductivity and is thus suitable for use in direct methanol fuel cells with low costal advantage.

Proton exchange composite membranes, composite solutions, and method for manufacturing and fuel cell using the same

The present invention relates to polymer membranes for separating olefins from paraffins which have the similar molecular size and close boiling point. More particularly, it relates to a silver salt-containing facilitated transport membrane for olefin separation, and also a method for producing the same. An object of the present invention is to provide a silver salt-containing facilitated transport membrane for olefin separation having improved stability, and also a method for preparing the same, which exhibits no deterioration in membrane performance even when operated for an extended period of time. The facilitated transport membrane for olefin/paraffin separation of the present invention comprises a polymer, a silver salt, and a phthalate compound represented by the following formula (1)wherein R denotes an alkyl group of 2 to 8 carbon atoms or a phenyl group.

Method for producing silver salt-containing facilitated transport membrane for olefin separation having improved stability

The present invention relates to composite polymers containing nanometer-sized metal particles and manufacturing method thereof, which can be uniformly dispersed nanometer-sized metal particles into polymers, thereby allowing the use thereof as optically, electrically and magnetically functional materials. The method for manufacturing composite polymers containing nanometer-sized metal particles includes the steps of: dispersing at least one metal precursor into a matrix made of polymers in a molecule level; and irradiating rays of light on the matrix containing the metal precursors dispersed in the molecule level and reducing the metal precursors into metals and fixing nanometer sized metal particles inside of matrix.

Composite polymers containing nanometer-sized metal particles and manufacturing method thereof

Silver salt-containing facilitated transport membrane for olefin separation having improved stability and method for producing the same

A facilitated transport membrane with improved permeance and selectivity to alkene-based unsaturated hydrocarbons is provided. The facilitated transport membrane includes a solid state polymer electrolyte and additionally a non-volatile surfactant that enhances long-term operation stability. In preparing the facilitated transport membrane for separation of alkenes, a porous supporting membrane is coated with a solid polymer electrolyte layer having a non-volatile polymer, a non-volatile surfactant, and a salt of a transition metal capable of complexing selectively and reversibly with alkenes.

Solid state polymer electrolyte facilitated transport membranes containing surfactants

Disclosed is an inorganic-organic hybrid polymer composed of nano-particles on the surface using a dendrimer and a manufacturing method thereof, in which nanometer-sized inorganic (metal) particles are uniformly dispersed across the surface of the polymer and available as optically, electrically and magnetically functional materials. The method includes the steps of: forming a functional anhydride group on a polymer-based matrix; selectively adding metal or inorganic salts to the dendrimer to prepare either of dendrimer-metal precursor solution or dendrimer-inorganic particle solution; inducing the reaction between the functional anhydride group of the surface of polymer matrix with the solution to form a chemical bond between the matrix and the dendrimer; and reducing the metal ions or inorganic particle by irradiation of light.

Inorganic-organic hybrid polymers composed of nano-particles on the surface using dendrimers and manufacturing method thereof

An asymmetric support membrane can be prepared by using a phase separation method. The method includes immersing a polymer solvent solution into water. The polymer solution is made by dissolving 15 to 35% by weight of the polymer into a solvent that lets the polymer solution become a gel at a temperature of 0 to 50&deg; C. The solution is then allowed to gel and brought into a final membrane form in water for phase separation and formation of the asymmetric support membrane. The polymer may be poly(vinyl chloride), polyethersulfone, polyetherimide and polyamic(methylester). The solvent is &ggr;-butyrolactone alone as a major solvent or is a mixed solvent with N-methyl-2-pyrrolidone as a cosolvent. The asymmetric support membrane is a porous support membrane of a sponge form having open pores that are connected to one another with a narrow pore size distribution. Thus, the asymmetric support membrane has an improved permeance and mechanical strength. Further, because it has a narrow pore size distribution, a coating process can be optimized with a material having high selectivity. Therefore, the composite membranes having improved selectivity can be easily produced by the present invention.

Method for producing an asymmetric support membrane by physical gelation and the membranes obtained thereby

This invention provides a polyamide separation membrane, prepared from high molecular weight polyamide having a repeating unit represented by the formula (I) and a process for separating gaseous mixtures using them. ##STR1## wherein, R is an aliphatic or aromatic organic group derived from dicarboxylic acid or halide. The polyamide separation membrane according to the present invention has a large free volume and good permeation properties such as permeability and permeation selectivity.

Separation membranes prepared from polyamide polymers having 2,2'-bis

A polymeric dope solution comprising a polymeric material and a mixed solvent as a solvent system for use in the preparation of an integrally skinned asymmetric membrane having a surface layer (selective surface layer) and a porous support layer, which is useful as a gas separation membrane, is disclosed. Also disclosed are a process for the preparation of the asymmetric membrane using the polymeric dope solution, and an integrally skinned dope solution prepared thereby. The asymmetric membranes according to the present invention show good gas permeability and high permselectivity.

Polymeric dope solution for use in the preparation of an integrally

The present invention describes a method for preparing an asymmetric porous membrane by a dry-wet phase inversion method, which comprises contacting a cast or spun polymer solution with water or organic vapor prior to immersing into the non-solvent precipitation medium, whereby said water or organic vapor is adsorbed onto the cast or spun polymer solution. Higher permeability and excellent rejection ability can be obtained, due to the high porosity and uniform pore size of said membranes according to the present invention.

Method for preparing porous membranes utilizing water or organic vapor

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Seoul, South Korea

Yong Soo Kang