Lg Chem, Ltd

Yong Hee An

Chun Ho Park

Tae Hoon Kim

Yong Yeon Hwang

Jeongmin Jang

Ho Hoon Kim

Da Eun Sung

Jang Won Park

Min Soo Kim

Jin Woo Lee

Min Jung Kim

Daeun Sung

Wangrae Joe

Bong Keun Ahn

Jeong Min Jang

Hyun Taek Oh

Eun Soo Kang

Seung Young Park

Jun Wye Lee

Wangrae Cho

Yun Ki Cho

Hyun Ju Cho

Wang Rae Joe

Jung Min Sohn

Yoon Jung Kim

Taek Jun Jung

Hyun Min Kim

Bo Hyun Seong

Sung-Kyoung Kim

Dong Kwon Lee

Jong-Ku Lee

Woo Sung Hwang

Ji Yoon Jeon

Kwang Hyon Kim

Daewoong Lee

The present disclosure relates to a thermoplastic resin composition and an exterior material including the same. The thermoplastic resin composition included 90 to 99.5% by weight of styrene-based resins each including 5 to 30% by weight of acrylate rubber having a DLS average particle diameter of 0.25 to 0.32 μm or a TEM average particle diameter of 0.2 to 0.27 μm based on a total weight of the styrene-based resins; and 0.5 to 10% by weight of a polyamide resin, and an exterior material including the thermoplastic resin composition. According to the present disclosure, a low-gloss thermoplastic resin composition having excellent aesthetics, such as softness, luxuriousness, and naturalness, due to uniformity, low gloss, and improvement in surface texture while having mechanical properties and processability equal or superior to those of conventional ASA resins; and an exterior material including the low-gloss thermoplastic resin composition may be provided.

Thermoplastic resin composition and exterior material including the same

Disclosed is an ASA resin composition, a molded article including the ASA resin composition, and a method of manufacturing the molded article. Also disclosed is an ASA resin composition including 20 to 47% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer containing acrylate rubber having an average particle diameter of 50 to 150 nm as a core; 23 to 55% by weight of an alkyl methacrylate-aromatic vinyl compound-vinyl cyanide compound copolymer; and 25 to 45% by weight of a poly(alkyl methacrylate) resin, a molded article including the ASA resin composition, and a method of manufacturing the molded article. Also disclosed is an ASA resin composition having excellent colorability and transparency even at a processing thickness of a predetermined value while having excellent mechanical properties and processability, a molded article including the ASA resin composition, and a method of manufacturing the molded article are provided.

ASA-based resin composition, molded article including ASA-based resin composition, and method of manufacturing molded article

The present disclosure relates to a thermoplastic resin composition and an exterior material including the same. The thermoplastic resin composition has low gloss and has mechanical properties and processability equal or superior to those of conventional ASA resins. The thermoplastic resin composition also has improved viscoelastic properties that can lead to excellent processability during the manufacture of a co-extruded product and excellent adhesion within the co-extruded product. The thermoplastic resin composition is also capable of reducing surface defects.

The present disclosure relates to a thermoplastic resin composition and a molded article including the same. The thermoplastic resin composition includes 10 to 70% by weight of a graft copolymer (A) including an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) containing acrylate rubber having an average particle diameter of 50 to 150 nm and an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) containing acrylate rubber having an average particle diameter of 300 to 600 nm; and 30 to 90% by weight of a non-grafted copolymer (B) including a high molecular weight aromatic vinyl compound-vinyl cyanide compound copolymer (B-1) having a weight average molecular weight of 160,000 to 200,000 g/mol and a low molecular weight aromatic vinyl compound-vinyl cyanide compound copolymer (B-2) having a weight average molecular weight of 80,000 g/mol or more and less than 160,000 g/mol.

Thermoplastic resin composition and molded article including the same

Provided is a thermoplastic resin composition which includes: a first graft copolymer including a first acrylic rubber polymer; a second graft copolymer including a second acrylic rubber polymer; and a first styrene-based copolymer including an alkyl-substituted styrene-based monomer unit and an acrylonitrile-based monomer unit, wherein the first acrylic rubber polymer has an average particle diameter larger than that of the second acrylic rubber polymer, the first graft copolymer is included in a larger amount than the second graft copolymer, and the sum of the first graft copolymer and the second graft copolymer is 22 parts by weight or less with respect to 100 parts by weight of the sum of the first graft copolymer, the second graft copolymer, and the first styrene-based copolymer.

Thermoplastic resin composition

A thermoplastic resin composition including 100 parts by weight of a base resin including 0.5 to 45% by weight of a graft copolymer (A-1) including acrylate rubber having an average particle diameter of 50 to 150 nm, an aromatic vinyl compound, and a vinyl cyanide compound, 20 to 80% by weight of a graft copolymer (A-2) including acrylate rubber having an average particle diameter of 151 to 600 nm, an aromatic vinyl compound, and a vinyl cyanide compound, and 10 to 45% by weight of an α-methylstyrene-based copolymer (B) having a weight average molecular weight of 60,000 to 180,000 g/mol; and 0.5 to 10 parts by weight of an ultra-high molecular weight copolymer (C) having a weight average molecular weight of 1,000,000 to 12,000,000 g/mol. A method of preparing the thermoplastic resin composition and a molded article including the thermoplastic resin composition are also disclosed.

Thermoplastic resin composition, method of preparing the same, and molded article including the same

The present disclosure relates to a thermoplastic resin composition and an exterior material including the same. The thermoplastic resin composition includes 100 parts by weight of styrene-based resins; 0.5 to 5 parts by weight of a first polyamide resin having a melting temperature (Tm) of 230° C. or less; and 0.5 to 10 parts by weight of a second polyamide resin having a melting temperature (Tm) of 250° C. or more. Both the first and second polyamide resins have a relative viscosity of 2.5 or less. The present disclosure advantageously provides a low-gloss thermoplastic resin composition having excellent aesthetics, such as softness, luxuriousness, and naturalness, due to uniform and low gloss, and improvement in surface texture while having mechanical properties and processability equal or superior to those of conventional ASA resins; and an exterior material including the low-gloss thermoplastic resin composition.

The present invention relates to a thermoplastic resin composition, a method of preparing the same, and a molded article manufactured using the same. More specifically, the thermoplastic resin composition of the present invention includes 100 parts by weight of a base resin consisting of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) containing acrylate rubber having an average particle diameter of 0.05 to 0.15 μm as a core, an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) containing acrylate rubber having an average particle diameter of 0.3 to 0.6 μm as a core, an aromatic vinyl polymer (B-1), and a heat-resistant aromatic vinyl polymer (B-2); and 0.5 to 10 parts by weight of a polyolefin elastomer (C). Within this range, the thermoplastic resin composition may have a heat deflection temperature (HDT) of 89° C. or more.

Thermoplastic resin composition, method of preparing the same, and molded article manufactured using the same

A thermoplastic resin composition and a molded article including the same can include 100 parts by weight of a base resin including 10 to 50% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) containing acrylate rubber having an average particle diameter of 0.3 to 0.5 μm, 5 to 40% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) containing acrylate rubber having an average particle diameter of 0.05 μm or more and less than 0.3 μm, and 20 to 65% by weight of an aromatic vinyl polymer (B), and 0.5 to 12 parts by weight of a polyamide (C). The thermoplastic resin composition can have a solvent resistance of 15 days or more.

Thermoplastic resin composition and molded article thereby

A thermoplastic resin composition and a molded article including the same are disclosed in which the thermoplastic resin composition includes 100 parts by weight of a base resin including an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer; and 0.5 to 10 parts by weight of a matting agent having a refractive index of 1.46 to 1.53, and a molded article including the thermoplastic resin composition, wherein the thermoplastic resin composition satisfies Equations 1 and 2 below:≤20,  [Equation 1]

Thermoplastic resin composition and molded article thereof

The present invention relates to a thermoplastic resin composition and a molded article including the same. More specifically, the thermoplastic resin composition of the present invention includes 100 parts by weight of a base resin consisting of 10 to 30% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-1) including an acrylate rubber having an average particle diameter of 0.05 to 0.15 μm, 20 to 40% by weight of an acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A-2) including an acrylate rubber having an average particle diameter of 0.3 to 0.5 μm, 0 to 35% by weight of an aromatic vinyl polymer (B), and 10 to 60% by weight of a polymethacrylate (C); and 0.5 to 10 parts by weight of a polyamide (D).

Provided is a thermoplastic resin composition which includes: a graft copolymer including a Cto Calkyl (meth)acrylate-based monomer unit, a styrene-based monomer unit, and a vinyl cyan-based monomer unit; a first styrene-based copolymer including a Cto Calkyl-substituted styrene-based monomer unit and a vinyl cyan-based monomer unit; and a second styrene-based copolymer including an unsubstituted styrene-based monomer unit and a vinyl cyan-based monomer unit. The thermoplastic resin composition is remarkably excellent in heat resistance, chemical resistance, and appearance characteristics while maintaining basic properties.

Provided is a thermoplastic resin composition which includes: a graft copolymer prepared by graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyan-based monomer onto an acrylic rubber polymer having an average particle diameter of 50.0 to 90.0 nm; a matrix copolymer including a C-Calkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit and a vinyl cyan-based monomer unit; and an additive including a polymer including a C-Calkyl (meth)acrylate-based monomer unit, specifically, a thermoplastic resin composition which has improved properties in terms of elongation, processability, weather resistance, colorability, hardness, chemical resistance, scratch resistance, a whitening phenomenon, surface gloss and appearance quality while having excellent basic properties.

The present invention relates to a method of preparing an ASA graft copolymer, a method of preparing a thermoplastic resin composition including the ASA graft copolymer, and a method of manufacturing a molded article using the thermoplastic resin composition. More particularly, the present invention provides an ASA graft copolymer having improved thermal stability through addition of an emulsifier in a specific amount range in a seed preparation step and introduction of a multifunctional carboxylic acid having 20 or more carbon atoms or a salt thereof, as an emulsifier, in a shell preparation step and a high-quality thermoplastic resin composition exhibiting excellent impact resistance, such as impact strength and tensile strength, and excellent appearance, such as surface gloss, whiteness, and retention-associated heat discoloration, and causing considerable reduction in the amount of gas generated on a surface of a resin during a high-temperature thermoforming process due to inclusion of the ASA graft copolymer.

Method of preparing ASA graft copolymer, method of preparing thermoplastic resin composition including ASA graft copolymer, and method of manufacturing molded article using thermoplastic resin composition

The present invention relates to a thermoplastic resin composition, including a first graft copolymer including an alkyl (meth)acrylate-based polymer-derived unit, an aromatic vinyl-based monomer-derived unit, and a vinyl cyanide-based monomer-derived unit; a copolymer including an aromatic vinyl-based monomer-derived unit and a vinyl cyanide-based monomer-derived unit; a polyester-based elastomer; and a phthalate-based plasticizer.

Growing community of inventors

Daejeon, South Korea

Yong Hee An