Air Liquide Advanced Technologies U.S. LLC

Praxair Technology, Inc.

Porogen Corporation

L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

Gas Technology Institute

Liquide Advanced Technologies U.S. LLC

Decarbontek LLC

Yong Ding

Benjamin Bikson

Paul Terrien

Joyce K Nelson

Pascal Marty

Michael John Mitariten

Sandeep K Karode

Youxin Yuan

Alex Augustine

Kevin Weatherford

Shiguang Li

Howard S Meyer

Shaojun Zhou

James Timothy Macheras

Dennis Rocha

Johann Katz Leroux

Porous solid amine adsorbents are prepared by bringing into contact a first (e.g., dope) solution, including a water insoluble polymer and a water-soluble amine polymer, with an aqueous solution containing a multifunctional chemical agent. The first solution can be obtained by dissolving the water insoluble polymer and the water-soluble amine polymer in a polar solvent. The adsorbents can be in the form of beads, sheets, fibers, hollow fibers, etc. and can be used in the removal of acid gases, CO, for instance, from fluid streams.

Porous solid amine adsorbents and applications

An energy efficient process for NGL recovery and production of compressed natural gas (CNG) in which natural gas is fed to a first gas separation membrane-based separation stage where it is separated into a permeate and a retentate. The high Cconcentration first stage permeate is chilled and separated to provide liquid phase NGL and a gaseous phase. The first stage retentate is separated at a second gas membrane-based separation stage to produce a retentate meeting pipeline specifications for CNG (including hydrocarbon dewpoint) and a permeate that is recycled to the first stage. The gaseous phase, constituting a low BTU fuel, may be used in on-site power generation equipment and/or in internal combustion engines. The second stage permeate (and optionally the third stage retentate) is (are) recycled back to the first stage to enhance the production of NGL and CNG. The gaseous phase may instead be fed to a third stage to produce a third permeate and a third residue, in which case the third permeate is recycled to the first stage and the third retentate is a low BTU fuel which may be used in on-site power generation equipment and/or in internal combustion engines.

Membrane process for natural gas liquids recovery and hydrocarbon dew point control

A process for purifying a gaseous feed stream of natural gas including methane, COand heavy hydrocarbons including step a): cooling the gaseous feed stream in a heat exchanger; step b): introducing the cooled stream into a phase-separating chamber to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gaseous stream; step c): separating the gaseous stream obtained from step b) in a first membrane producing at least one CO-enriched permeate stream and a residual stream enriched in methane; step d): introducing the residual stream obtained from step c) into a phase-separator to produce a liquid stream and a gaseous stream; step e): heating the gaseous stream obtained from step d) by introducing it into the heat exchanger used in step a) counter-currentwise with the feed stream thereby producing a gaseous stream depleted in COand enriched in methane.

Method for purifying natural gas using an economizer

A feed containing methane and nitrogen gas is processed in a three-stage membrane system, each stage of which is selective for methane over nitrogen. The methane enriched permeate from the first stage is removed as product gas. The methane-depleted residue from the second stage is purified in second and third cascaded stages to provide second and third permeates and second and third residues. The third stage permeate is recycled to the feed.

Membrane nitrogen rejection process and system

An approach for separating a gaseous mixture includes a multi-stage membrane system in which a rubbery membrane is operated at a low temperature. Various streams are cooled and heated in a multi-fluid heat exchanger. In specific configurations, the multi-fluid heat exchanger is cooled by using no fluids other than fluids derived from the permeate and/or residue generated in the first membrane stage.

Cold membrane nitrogen rejection process and system

A process for purifying a feed gas including methane and heavy hydrocarbons, including: step a): cooling the feed gas in a heat exchanger; step b): introducing the resulting into a first phase separator to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gas stream; step c): separating the gas stream in a membrane from which a methane-enriched permeate stream and a partially condensed residue stream exit; step d): introducing the residue stream from step c) into a second phase separator vessel in order to produce a liquid stream and a gas stream; step e): introducing at least one portion of the gas stream resulting from step d) into a JT expansion means; and step f): heating at least one portion of the expanded stream in the heat exchanger used in step a) counter-current to the feed stream in order to cool the latter.

Method for separating a natural gas stream into a methane-enriched fraction and a fraction enriched in Cand higher hydrocarbons

A process for purifying a natural gas feed gas stream including methane and hydrocarbons, including step a): cooling the feed gas stream; step b): introducing the cooled stream into a first phase separator vessel in order to produce a liquid stream and a gas stream; step c): separating the gas stream resulting from step b) in a membrane unit from which a methane-enriched permeate stream and one partially condensed residue stream enriched in hydrocarbons exit; step d): introducing the residue stream resulting from step c) into a second phase separator vessel to produce a liquid stream and a gas stream; step e): introducing at least one portion of the liquid stream resulting from step d) into a JT expansion means; step f): heating at least one portion of the expanded by introduction into the heat exchanger used in step a) counter-current to the feed stream.

Method for purifying a natural gas stream

A feed fluid mixture including at least one condensable component and at least one non-condensable component is separated into a gaseous permeate and an at least partially liquid retentate with a gas separation membrane through simultaneous condensation of at least one of said at least one condensable component on a retentate side of the membrane and permeation of at least one of said at least one non-condensable component through the membrane.

Dead end membrane gas separation process

Natural gas may be purified by removing Chydrocarbons and COin respective one or more separation units to yield conditioned gas lower in Chydrocarbons and COin comparison to the un-conditioned natural gas. Notably, the feed gas need not be subjected to joule-thomson expansion and molecular sieve dehydration performed by conventional processes. Rather, any water-rich reject stream from the separation unit(s) is dried downstream with a smaller compressor and smaller molecular sieve or gas separation membrane dehydration unit before it may be re-injected deep underground or deep under the sea bed.

Method and system for purification of natural gas using membranes

Nitrogen is removed from biogas using a three-stage separation system based on gas separation membranes. The first stage separates a biomethane feed stream into a first permeate gas stream and a first retentate gas stream. The second stage separates the first permeate stream into a biomethane product gas and a first low quality biomethane gas stream. The third stage separates the first retentate into a second low quality biomethane gas stream and a waste gas. A biogas feed stream is pretreated to remove amounts of water, VOCs, and COto yield a methane-enriched biogas stream. The methane-enriched biogas stream is compressed together with the first and second low quality biomethane gas streams to form the biomethane feed stream.

Multi-stage membrane for N2 rejection

The invention relates to a process for recovering methane from digester biogas or landfill gas. More specifically, the invention pertains to a method for producing biomethane that removes impurities from a compressed digester biogas with staged membrane modules of at least two different types, to produce a biomethane having at least 94% CH, below 3% of CO, and below 4 ppm of HS.

Production of biomethane using multiple types of membrane

Composite porous hydrophobic membranes are prepared by forming a perfluorohydrocarbon layer on the surface of a preformed porous polymeric substrate. The substrate can be formed from poly(aryl ether ketone) and a perfluorohydrocarbon layer can be chemically grafted to the surface of the substrate. The membranes can be utilized for a broad range of fluid separations, such as microfiltration, nanofiltration, ultrafiltration as membrane contactors for membrane distillation and for degassing and dewatering of fluids. The membranes can further contain a dense ultra-thin perfluorohydrocarbon layer superimposed on the porous poly(aryl ether ketone) substrate and can be utilized as membrane contactors or as gas separation membranes for natural gas treatment and gas dehydration.

Composite perfluorohydrocarbon membranes, their preparation and use

Natural gas may be purified by removing Chydrocarbons and COin respective first and second gas separation membrane stages to yield conditioned gas lower in Chydrocarbons and COin comparison to the un-conditioned natural gas.

Composite porous hydrophobic membranes are prepared by forming a perfluorohydrocarbon layer on the surface of a preformed porous polymeric substrate. The substrate can be formed from poly (aryl ether ketone) and a perfluorohydrocarbon layer can be chemically grafted to the surface of the substrate. The membranes can be utilized for a broad range of fluid separations, such as microfiltration, nanofiltration, ultrafiltration as membrane contactors for membrane distillation and for degassing and dewatering of fluids. The membranes can further contain a dense ultra-thin perfluorohydrocarbon layer superimposed on the porous poly (aryl ether ketone) substrate and can be utilized as membrane contactors or as gas separation. membranes for natural gas treatment and gas dehydration.

A method for desorption of one or more gases from a liquid stream in which a liquid stream containing at least one gas is provided to the feed side of a porous membrane and a trans-membrane pressure drop from the feed side to the opposite gas side of the membrane is created, resulting in a portion of the liquid stream filling at least a portion of the pores of the porous membrane and desorption of at least a portion of the at least one gas from the liquid stream to the gas side of the porous membrane.

Growing community of inventors

Waban, MA, United States of America

Yong Ding