Mitsui Petrochemical Industries, Ltd.

Ricoh Company, Ltd.

Mitsui Chemicals, Inc.

Other

Hoechst Aktiengesellschaft

Nec Environment Engineering, Ltd.

Yohzoh Yamamoto

Hideo Nakamura

Toshiyuki Hirose

Shigetoshi Nishijima

Masaru Wakizaka

Hideshi Kawachi

Takasi Nakagawa

Kenji Yokoyama

Toshio Kimura

Satoru Moriya

Syuji Minami

Akira Matsuda

Hideki Sakai

Hidekuni Oda

Hiroshi Inoue

Shiro Honma

Kiyomi Yasuda

Michio Hashimoto

Goro Suzuki

Yasushi Amada

Shuichi Ishiwata

Shinji Osato

Kimio Hasegawa

Masashi Yatoumaru

Michio Tsugawa

Shinji Ohsato

Masaru Kokuryou

Kenji Miharu

A resin composition is a transparent, low-water-absorption polyolefin-based resin composition containing a sorbitol-based derivative of a particular structure, whose polyolefin-based resin having crystallinity of 0% to 20% shows haze of not more than 10%, total light transmittance of not less than 80%, when measured in accordance with ASTM D1003 using an article 3 mm thick molded therefrom as the test specimen, and shows water absorption of not more than 0.1% after 100-hour immersion in water at 23&deg; C., or whose polyolefin-based resin comprises a cyclic olefin-based polymer comprising a cyclic olefin of a particular structure. Preferable examples of the polyolefin-based resin include the aforesaid cyclic olefin-based polymer and a polycyclohexane-based resin. This resin composition is used for transparent resin moldings that are useful as optical products and moldings for medical and pharmaceutical use because it has excellent transparency, heat resistance, rigidity and water vapor resistance and the decline in its transparency in a high-temperature/high-humidity atmosphere will be little.

Polyolefin-based resin compositions and fabricated products produced therefrom

Cycloolefin resin pellets of the present invention comprises a cycloolefin resin pellet and a powdery coating material and/or a liquid coating material, the melting point or the glass transition point of the coating material being C. or lower, and the coating material being adhered onto the surface of the cycloolefin resin pellets, so that the molded product thereof is excellent in transparency.

Cycloolefin resin pellets and a process for producing a molded product thereof

Multi-layer laminates and uses thereof

A laminated film superior in the heat resistance, shock resistance, moisture-barriering property and easy hand-tearability, which comprises one or more layers of a thermoplastic polyester resin (A), one or more layers of a resin based on cycloolefin (C) and one or more interposed layers of an adhesive (B) between layer (A) and layer (C), wherein the layer(s) of the thermoplastic polyester resin (A) and optionally the layer(s) of the resin based on cycloolefin (C) have been biaxially stretched and wherein the total thickness of the layer(s) of the thermoplastic polyester resin (A), the total thickness of the layer(s) of the adhesive (B) and the total thickness of the layer(s) based on cycloolefin (C) are 0.5-50 .mu.m, 0.5-20 .mu.m and 5-150 .mu.m, respectively.

Laminated film and packaging material

A press-through packaging or blister package having excellent moisture-proofness, transparency, and superior processibility by vacuum or pneumatic forming, comprising of a formed product having blisters thereon prepared by forming a sheet or film of a non-stretched layer made from one or more non-crystalline polyolefin resins selected from the group consisting of

PTP or blister packaging articles and packaging material therefor

The resin composition of the present invention comprises (A) a cycloolefin resin selected from the group consisting of a random copolymer of a cycloolefin prepared from a specified cycloolefin such as norbornene or tetracyclododecene, a (co)polymer obtained by a ring-opening polymerization of such a cycloolefin and a product of hydrogenation of the above ring-opening (co)polymer; and (B) an oligomer having an allcyclic structure and/or an aromatic ring structure, e.g., a terpene resin oligomer. Therefore, the resin composition of the present invention is especially excellent in coating and bonding suitabilities.

Resin composition

A polyolefin multilayer laminate in which a first layer (A) made of a cycloolefin-based resin, such as an ethylene/cycloolefin random copolymer resulting from copolymerization of ethylene and a cycloolefin represented by the formula (1) given below, or a cycloolefin-based resin blend and a second layer (B) made of an olefin (co)polymer or a composition containing it are laminated. This laminate can be used as a packaging material which is superior in the interlayer adhesion, shapability, moistureproof property, transparency, flexibility, easiness of hand-cutting, heat-sealability and dead-hold property. Formula (1) comprises ##STR1## in which n and q are 0 or 1, m is 0 or any positive integer, R.sup.1 -R.sup.18 and R.sup.a and R.sup.b denote each H, a halogen atom or a hydrocarbon group, wherein R.sup.15 -R.sup.18 may form, by combining with each other, a monocyclic or polycyclic ring, which may have double bond(s), and wherein R.sup.15 -R.sup.16 may have terminal-located alkylidene group.

Polyolefin multilayer laminate, vessel and packaging material

A thermoplastic resin composition according to the present invention comprises a polymer comprising recurring units derived from a polycyclic (meth)acrylate represented by the following formula [I] and a soft polymer in the proportion by weight of the polymer to the soft polymer of 99:1 to 40:60 ##STR1## where m is 0 or a positive integer, n is 0 or 1, R is hydrogen or methyl, R.sup.1 -R.sup.18 are each independently an atom or a group selected from the group consisting of hydrogen, halogen and hydrocarbon groups, R.sup.15 -R.sup.18, linked together, may form a monocyclic or polycyclic group which may have a double bond, or an alkylidene group, p is 0 or 1, and R.sup.a and R.sup.b each independently represent a hydrogen atom or a hydrocarbon group when p is 1.

Thermoplastic resin composition

A polyol resin substantially free of epoxy groups is useful as a coating material and is prepared by

Epoxy resin reacted with primary amine active hydrogen compound and

A thermoplastic resin composition according to the present invention comprises a polymer comprising recurring units derived from a polycyclic (meth)acrylate represented by the following formula [I] and a soft polymer in the proportion by weight of the polymer to the soft polymer of 99:1 to 40:60 ##STR1## wherein m is 0 or a positive integer, n is 0 or 1, R is hydrogen or methyl, R.sup.1 -R.sup.18 are independently an atom or a group selected from the group consisting of hydrogen, halogen and hydrocarbon groups, R.sup.15 -R.sup.18, linked together, may form a monocyclic or polycyclic group which may have a double bond, or an alkylidene group, p is 0 or 1, and R.sup.a and R.sup.b each independently represent a hydrogen atom or a hydrocarbon group when p is 1.

A sheet or a film composed of at least one cyclo-olefin polymer selected from the group consisting of ring-opened polymers derived from at least one cyclo-olefin of formula (I) ##STR1## wherein R.sup.1 to R.sup.12, independently from each other, represent a member selected from the class consisting of a hydrogen atom, halogen atoms and hydrocarbon groups; two of R.sup.9 to R.sup.12 may be linked to each other together with the carbon atoms to which they are bonded to form a monocyclic or polycyclic group which may contain a double bond; R.sup.9 and R.sup.10, or R.sup.11 and R.sup.12 may each form an alkylidene group together with the carbon atoms to which they are bonded; and n is 0 or a positive integer, ring-opened copolymers derived from the cyclo-olefins of formula (I), hydrogenation products of said polymer or copolymers and addition polymers of the cyclo-olefins of formula (I) with ethylene, said cyclo-olefin polymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of 0.01 to 10 dl/g and a softening temperature of at least 70.degree. C.

Sheet or film composed of cyclo-olefin polymer

A flame retardant cyclic olefinic polymer composition which comprises

Flame retardant cyclic olefinic polymer composition

A foamable polymer composition comprising

Foamable polymer composition and foamed article

There is provided a process for preparing a novel polyol resin which does not substantially contain epoxy group wherein a bisphenol type epoxy resin (a) is subjected to the following steps (i), (ii) or (i), (iii) and (ii) in an optional sequence:

Epoxy resin reacted with primary amine, active hydrogen compound and

A modified epoxy resin provided with improved flexibility and curing properties is prepared by subjecting a bisphenol type epoxy resin (a) to steps (i) and (ii):

Growing community of inventors

Yamaguchi, Japan

Yohzoh Yamamoto