Chisso Corporation

Yohji Terui

Isao Koga

Masuhito Ohgushi

Tohru Kitahara

Kenichi Watanabe

Nobumasa Ohtake

A method for producing mono-substituted dichlorosilanes selectively with a high yield from dichlorosilane is provided. According to this method, dichlorosilane and a specified compound having a double bond at .alpha.-position are reacted in the presence of a catalyst which is a homogeneous complex of ruthenium, rhodium, nickel or platinum, and a phosphine compound, or is a ruthenium chloride.

Method for producing substituted dichlorosilane

Novel disubstituted dichlorosilane compounds which have two different specified substituents and are necessary as monomers for preparing special silicone resin are provided and a method for producing same without accompaniment of by-product production is also provided.

Novel disubstituted dichlorosilane and method for producing same

In the method of producing 3-chloropropyltrichlorosilane by the addition reaction of trichlorosilane to allyl chloride, [Pt(PPh.sub.3).sub.2 Cl.sub.2 ] is used as the catalyst for the reaction. Side reactions are suppressed to give a high yield of the product.

Method for producing 3-chloropropyltrichlorosilane

Novel diaralkyldichlorosilanes expressed by the general formula (I) ##STR1## (wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent hydrogen atom or an alkyl group having 1.about.4 carbon atoms, but a case where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are all hydrogen atom is excluded), and a process for producing the same are provided. They are useful as monomers for producing polysiloxanes and as intermediates for synthesizing novel organosilicon compounds.

Diaralkyldichlorosilanes

Substituted phenethyldichlorosilanes having a longer chain alkyl group and diphenethyldichlorosilane which are useful as compounds for improving heat-resisting property and other properties of silicone-oils, -rubbers and -varnishes which are used as electric insulating materials, lubricating oils, water-repelling agents, paintings, releasing agents, etc. are provided. A method for producing these compounds with a high yield without producing by-products is also provided.

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Chibashi, Japan

Yohji Terui