Exxonmobil Upstream Research Company

Exxonmobil Technology and Engineering Company

Yitian Xiao

Michael Siskin

Martin Leo Gorbaty

Preeti Kamakoti

William Neergaard Olmstead

Stuart Ronald Keller

Simon Robert Kelemen

Howard J Freund

Cara L Davis

Gary F Teletzke

Clifford C Walters

Michael J Formolo

Jasper L Dickson

William B Maze

David T Wang

Sarah E Gelman

Michael Lawson

Peter G Smith, Jr

David J Curry

A E Bence

A Edward Bence

A quantitative simulation process for producing quantitative model predictions of hydrocarbon composition. The quantitative simulation may include measuring a chemical and isotopic composition of a hydrocarbon sample from a hydrocarbon reservoir. The quantitative simulation may further include measuring geochemical data, geophysical data, and/or geological data for the hydrocarbon reservoir and/or source rock; deriving temperature versus time relationships from a basin model for the hydrocarbon reservoir and/or source rock based on the geochemical data, geophysical data, and/or geological data; generating estimated source-rock maturity parameters based on the temperature versus time relationships; generating an estimated compositional yield for hydrocarbon fractions based on the temperature versus time relationships and the chemical composition of the hydrocarbon sample; and generating, using a mass-conserving isotopic fraction (MCIF) simulator, an estimated isotopic composition of the hydrocarbon fractions based on the estimated compositional yield and the isotopic composition of the hydrocarbon sample.

Systems and methods for predicting the composition of petroleum hydrocarbons

A method for recovering oil from a subterranean, hydrocarbon-bearing formation includes at least one injection well and injecting a carrier fluid including a diverting agent into a high permeability pathway within the formation. An activating fluid is injected into the high permeability pathway within the formation, resulting in the precipitation or swelling of the diverting agent. The permeability of the high permeability pathway is decreased within the formation containing the diverting agent to a permeability less than the permeability of the adjacent areas of the formation. A mineralization fluid may be injected that is oversaturated or becomes oversaturated upon interacting with the acid gas that causes mineral precipitation to seal off high-permeability pathways.

Methods for improving the sweep efficiency of gas injection

A method of predicting the composition of hydrocarbon products of a complex carbonaceous material when exposed to specific time and temperature conditions is disclosed. In one embodiment, the material is characterized to obtain elemental, chemical and structural parameters. A representative chemical structure of the material is constructed based on the characterization information. The representative chemical structure is then stochastically expanded to a molecular ensemble chemical structural model that includes heteroatoms. The chemical structural model is coupled to a compositional yield model and the composition of the material products is determined using kinetic modeling. Methods are provided of constructing a chemical structural model of complex carbonaceous material, of coupling a molecular ensemble of chemical structures to a thermal chemical mechanism, of updating an ensemble of chemical structures during the kinetic modeling to reflect chemical reaction products and of eliminating molecules from the system.

Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products

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Sugar Land, TX, United States of America

Yitian Xiao