3m Innovative Properties Company

Ying Lin

Hassan Sahouani

Michael A Kropp

Matthew J Kryger

Joshua M Fishman

Caitlin E Meree

Duane Douglas Fansler

Jimmie Rae Baran, Jr

Sheng Ye

Bradley Dene Craig

Mary M Caruso Dailey

Jonathan W Kemling

Luke E Heinzen

Aaron T Hedegaard

Thomas P Klun

Jerald K Rasmussen

Richard John Pokorny

Brant Ulrick Kolb

Patricia M Savu

Ahmed Salih Abuelyaman

Wayne Scott Mahoney

Guy D Joly

Jeffrey O Emslander

Mahfuza B Ali

Joseph D Rule

Joachim Zech

Kim Marie Vogel

Yongshang Lu

William H Moser

Dong-Wei Zhu

Derek J Dehn

Terry R Hobbs

Timothy D Dunbar

Jacob D Young

John C Hulteen

Chuntao Cao

Semra Colak Atan

Jeffrey P Kalish

Paul J Homnick

Carla S Thomas

Gregory A Kobussen

Qin Lin

Ning Zhou

Jing Fang

Bradley L Givot

Paul D Pennington

Robert C Coffin

Kolby L White

Audrey S Forticaux

Justin M Bolton

Jimmie R Baran

A curable composition is provided comprising a urethane (meth)acrylate oligomer, a urethane (urea) phosphonate ad-hesion promoter, optionally reactive diluents, and an initiator. The use of the urethane (urea) phosphonate adhesion promotor provides better ageing stability and adhesion, as measured by T-peel adhesion test, than the use of other conventional adhesion promotors.

(Meth)acrylate urethane (urea) phosphonates as adhesion promoters

Disclosed herein are non-aqueous compositions including: a flowable Part A including at least one resin and Reactant A; and a flowable Part B including at least one resin and Reactant B; wherein at least one of flowable Part A and flowable Part B further includes a free radically polymerizable resin; wherein at least one of flowable Part A and flowable Part B further includes a free radical initiator system; wherein flowable Part A and flowable Part B are capable of being mixed to provide a flowable mixed composition; wherein when flowable Part A and flowable Part B are mixed, Reactant A and Reactant B are capable of interacting to cause a non-free radical reaction within a first staging time to provide a first staged stable consistency for the mixed composition; wherein Reactant A comprises an acid and Reactant B comprises a base, and upon mixing flowable Part A and flowable Part B, the Reactant A acid is capable of reacting with the Reactant B base in an ionic acid-base reaction; and wherein the mixed composition having the first staged stable consistency is capable of forming a hardened dental composition upon initiation of free radical polymerization.

Multi-part dental composition having staged viscosity prior to hardening

Foam compositions are provided including a polylactic acid polymer; second (e.g., polyvinyl acetate) polymer having a glass transition temperature (T) of at least 25&#xb0; C.; and plasticizer. Also described are articles comprising the foam compositions, such as a sheet or hearing protection article. Methods of making and using the foam compositions are further described herein.

Foam compositions comprising polylactic acid polymer, polyvinyl acetate polymer and plasticizer, articles, and methods of making and using same

A curable composition that includes a urethane multifunctional (meth)acrylate, an inorganic filler having a primary particle dimension of at least 200 nm, a photoinitiator system that can be activated by electromagnetic radiation in the range of 340-550 nm, a reactive diluent, and a reinforcing silica having a primary particle dimension of 100 nm of less. The sum of the absolute value of the difference in the refractive index of the filler and the refractive index of the composition cured without filler plus the birefringence of the filler is 0.054 or less, i.e. 0.054&#x2265;|n&#x2212;n|+&#x3b4;, where nis the refractive index of the filler, nis the refractive index of the composition cured without filler, and &#x3b4;is the birefringence of the filler.

Light curable compositions

Composite particles are provided including a chemical blowing agent particle encapsulated within a shell including an uncrosslinked thermoplastic material. The uncrosslinked thermoplastic material exhibits at least a certain minimum complex viscosity at a decomposition temperature of the chemical blowing agent particle. Also described are compositions and foam compositions containing the composite particles. Further, articles are provided including the foam compositions, such as a sheet, tape, or hearing protection article. Methods of making and using the foam compositions are additionally described herein.

Composite particles, composition and foam compositions containing composite particles, articles, and methods of making and using same

Reaction mixtures, foams prepared from the reaction mixtures, articles containing the foams, and methods of making the foams are provided. The polymeric material in the foam is formed from a polymerizable composition that includes a di(meth)acrylate oligomer and a monomer having a single ethylenically unsaturated group. The foams are highly filled (e.g., at least 60 volume percent of the foam is the filler) and can be thermally conductive. Although the foams contain a large amount of filler, the foams can be compressed at least 40 volume percent with an applied pressure of 50 pounds per square inch (345 kiloPascals).

Foams and methods of making

Curable compositions are provided including a curable system that requires a thermally generated amine to cause curing of the system, and a self-assembled particle distributed in the curable system. The curable system contains at least one reactive moiety and the self-assembled particle comprises a reactive amine ionically bound to a chromonic network. A multilayer article is also provided, including a substrate, a chromonic amine layer disposed on the substrate, and a curable layer disposed on the chromonic amine layer. Methods of making a cured composition and of adhering two substrates together are further provided.

Curable compositions including a chromonic network, articles, and methods

A catalyst-containing particle including a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for a thermoset polymeric system, and the acidic coating layer comprises a binder; and a method of making such particles. A curable, one-part epoxy/thiol resin composition that includes: an epoxy/thiol resin mixture including: an epoxy resin component that includes an epoxy resin having at least two epoxide groups per molecule; a thiol component that includes a polythiol compound having at least two primary thiol groups; and catalyst-containing particles dispersed in the epoxy/thiol resin mixture; wherein each particle includes a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for the epoxy resin; and a method of curing such curable composition.

Epoxy stabilization using acid-coated nitrogen containing catalysts, particles, and methods

The present disclosure provides a curable, one-part epoxy/thiol resin composition. The composition comprises an epoxy/thiol resin mixture including: an epoxy resin component including an epoxy resin having at least two epoxide groups per molecule, a thiol component including a polythiol compound having at least two primary thiol groups, and a nitrogen-containing catalyst for the epoxy resin. The epoxy/thiol resin mixture further includes metal nanoparticles (e.g., silver nanoparticles, copper nanoparticles, or both), dispersed in the epoxy/thiol resin mixture. The present disclosure provides a method of curing a curable, one-part epoxy/thiol resin composition, including providing a curable, one-part epoxy/thiol resin composition and heating the composition to a temperature of at least 50&#xb0; C.

Epoxy stabilization using metal nanoparticles and nitrogen-containing catalysts, and methods

Composite particles are provided that can be used to cure epoxy resins. More particularly, the composite particles have a porous polymeric core particle, a curing agent and/or a curing catalyst for an epoxy resin positioned within the porous polymeric core particle, and a fluoropolymer-containing coating layer around the porous polymeric core particle. Additionally, curable compositions are provided that are mixtures containing an epoxy resin and the composite particles. The epoxy resin typically does not react until the curable composition is heated causing the release of the curing agent and/or curing catalyst from the composite particle. Further, cured compositions formed from the curable composition are provided.

Composite particles for curing epoxy resin compositions and curable and cured epoxy resin compositions prepared using the particles

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Woodbury, MN, United States of America

Ying Lin