Exxonmobil Technology and Engineering Company

Exxonmobil Upstream Research Company

Marathon Gtf Technology, Ltd.

Gtc Technology US LLC

Imperial Oil Resources

Yijun Liu

Fritz Pierre, Jr

Ananda K Nagavarapu

Sabah A Kurukchi

Anand Moodley

Xiaoli Y Wright

Philip J Lenart

Atoosa Zahabi

Michael A Marr

Tine B Schaffer

Jason M Mcmullan

David C Rennard

Jorge Vincentelli

Wei Ren

Weerakone Sidantha Weerakone

Hugh R Stewart

Nathalie Carson

Alok R Seth

Scott R Hickman

A method of producing LNG. According to the method, a natural gas stream is compressed using first and second compressors. A cooler cools the natural gas stream so that the second compressor produces a cooled, compressed natural gas stream, which is liquefied in a liquefaction process. The liquefaction process uses a refrigerant compressor configured to compress a stream of refrigerant used to chill, condense, or liquefy the cooled, compressed natural gas stream. Using a heat recovery steam generation (HRSG) system, heat is recovered from a power source of the refrigerant compressor. A stream of pressurized steam is generated from the recovered heat. At least one of the first and second compressors is powered using at least part of the stream of pressurized steam.

Heat recovery steam generation integration with high pressure feed gas processes for the production of liquefied natural gas

A method for liquefying a feed gas stream. A refrigerant stream is cooled and expanded to produce an expanded, cooled refrigerant stream. Part or all of the expanded, cooled refrigerant stream is mixed with a make-up refrigerant stream in a separator, thereby condensing heavy hydrocarbon components from the make-up refrigerant stream and forming a gaseous expanded, cooled refrigerant stream. The gaseous expanded, cooled refrigerant stream passes through a heat exchanger zone to form a warm refrigerant stream. The feed gas stream is passed through the heat exchanger zone to cool at least part of the feed gas stream by indirect heat exchange with the expanded, cooled refrigerant stream, thereby forming a liquefied gas stream. The warm refrigerant stream is compressed to produce the compressed refrigerant stream.

Managing make-up gas composition variation for a high pressure expander process

A method and apparatus for producing liquefied natural gas (LNG) from a natural gas stream. Heavy hydrocarbons are removed from the natural gas stream in a separator to generate a bottom stream and a separated natural gas stream, which is used as a coolant in a heat exchanger to generate a pretreated natural gas stream. The pretreated natural gas stream is compressed and cooled to form a chilled pretreated natural gas stream, part of which forms a recycle stream to exchange heat with the separated natural gas stream in the heat exchanger, thereby generating a cooled recycle stream. The temperature and pressure of the cooled recycle stream are reduced. The cooled recycle stream is then separated into an overhead stream and a reflux stream, which is directed to the separator. The chilled pretreated gas stream is liquefied to form LNG.

Pretreatment, pre-cooling, and condensate recovery of natural gas by high pressure compression and expansion

A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a first heat exchanger and re-combined with the natural gas stream, and heavy hydrocarbons are removed therefrom to generate a separated natural gas stream and a separator bottom stream. Liquids are separated from the separator bottom stream to form an overhead stream, which is cooled and separated to form a recycle gas stream. The recycle gas stream is compressed. A first portion of the compressed recycle gas stream is directed through the first heat exchanger and directed to the separator as a column reflux stream. The separated to natural gas stream is used as a coolant in the first heat exchanger to thereby generate a pretreated natural gas stream, which is compressed and liquefied.

Pretreatment and pre-cooling of natural gas by high pressure compression and expansion

A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a heat exchanger and combined with the natural gas stream. Heavy hydrocarbons are removed from the combined natural gas stream, and the resulting separated natural gas stream is partially condensed in the first heat exchanger, with a liquid stream separated therefrom. The natural gas stream is warmed in the first heat exchanger and then is compressed and cooled. The resultant cooled compressed natural gas stream is expanded, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream recycled to the heat exchanger to be warmed through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are liquefied.

A method is disclosed for start-up of a system for liquefying a feed gas stream comprising natural gas. The system has a feed gas compression and expansion loop, and a refrigerant system comprising a primary cooling loop and a sub-cooling loop. The feed gas compression and expansion loop is started up. The refrigerant system is pressurized. Circulation in the primary cooling loop is started and established. Circulation in the sub-cooling loop is started and established. A flow rate of the feed gas stream and circulation rates of the primary cooling loop and the sub-cooling loop are ramped up.

Primary loop start-up method for a high pressure expander process

A method and apparatus for producing liquefied natural gas. A pretreated natural gas stream is compressed in at least two serially arranged compressors to a pressure of at least 1,500 psia and cooled. The resultant cooled compressed natural gas stream is expanded in at least one work producing natural gas expander to a pressure less than 2,000 psia and no greater than the pressure to which natural gas stream has been compressed, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream is warmed in a heat exchanger through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are then liquefied.

Process and systems for converting lower molecular weight alkanes to higher molecular weight hydrocarbons that include fractionation of brominated hydrocarbons, wherein the brominated hydrocarbons are formed by reaction of the lower molecular weight alkanes with bromine.

Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons

Processes and systems for drying liquid bromine utilizing two fractionators to produce a substantially dry liquid bromine stream and a substantially bromine-free water stream. Wet bromine liquid may be conveyed to a first fractionator wherein a substantially dry bromine liquid is produced, while a vapor stream from the first fractionator may be condensed into a first liquid phase comprising bromine saturated with water and a second liquid phase comprising water saturated with bromine. The water saturated with bromine may be conveyed to a second fractionator to produce at least substantially bromine-free water.

Processes and systems for drying liquid bromine

Process and systems for converting lower molecular weight alkanes to higher molecular weight hydrocarbons that include demethanization of brominated hydrocarbons, wherein the brominated hydrocarbons are formed by reaction of the lower molecular weight alkanes with bromine.

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Houston, TX, United States of America

Yijun Liu