Hewlett-packard Development Company, L.p.

Hewlett-packard Development, L.p.

Yi Feng

Carolin Fleischmann

Ali Emamjomeh

Shannon Reuben Woodruff

Erica Montei Fung

Rachael Donovan

Geoffrey Schmid

Jesiska Tandy

Hector Jose Lebron

Yubai Bi

Stanley J Kozmiski

Alay Yemane

Shao-Wei Li

Daniel Vincent Keane

Winthrop D Childers

Alexey S Kabalnov

Keshava A Prasad

Terry M Lambright

Si-lam Choy

John M Altendorf

Paul F Reboa

Michael A Novick

Chris Aschoff

Leo C Clarke

Pamela Woody

Carl L Baker

This disclosure relates to a material set including a build material for 3-D printing including particles of a polymer comprising polymer chains having at least one reactive group that is protected with a protecting group. The material set further includes an inkjet composition including a de-protecting agent for removal of the protecting group, and a liquid carrier.

3-D printing

Compositions including polyamides and methods of employing compositions including polyamides are described herein. For instance, composition for three-dimensional (3D) printing can include a polymer build material comprising of at least two polyamides including a first polyamide and a second polyamide, where the first polyamide is present in an amount ranging of from about 95% to about 99% of a total weight of the polymer build material and where the second polyamide is present in an amount ranging of from about 1% to about 5% of the total weight of the polymer build material.

Three-dimensional (3D) printing

The present disclosure relates to a composition for printing a three-dimensional object. The composition comprises composite particles comprising a thermoplastic polymer and a colour-masking pigment. The colour-masking pigment is encapsulated by the thermoplastic polymer and is present in an amount of from about 1.5 to less than about 6 wt % of the total weight of the composite particles.

Compositions for printing

The present disclosure relates to a composition for printing a three-dimensional object. The composition comprises composite particles comprising a thermoplastic 5 polymer and a colour-masking pigment. The colour-masking pigment is encapsulated by the thermoplastic polymer and is present in an amount of from about 1.5 to less than about 6 wt % of the total weight of the composite particles.

An example of a three-dimensional (3D) printing kit includes a build material composition and a fusing agent to be applied to at least a portion of the build material composition during 3D printing. The build material composition includes composite particles of titanium dioxide at least partially coated with a polyether block amide polymer. The fusing agent includes an energy absorber to absorb electromagnetic radiation to coalesce the composite particles in the at least the portion.

Three-dimensional printing

This disclosure relates to a method of 3-D printing comprising: applying a layer of build material onto a print platform, wherein the build material comprises particles of a polymer comprising polymer chains having at least one reactive group that is protected with a protecting group; printing a de-protecting agent at selected locations on the layer of build material; and coalescing particles of the polymer at the printed locations on the layer of build material to form a coalesced polymer layer.

A material set can include a powder bed material, including a polymer powder and a fusing agent. The polymer powder can have a particle size distribution having the following profile: D10 of 30 &#x3bc;m or more, D50 from 50 &#x3bc;m to 65 &#x3bc;m, and D90 of 100?m or less. Other parameters can include a melting point from 100&#xb0; C. to 300&#xb0; C., a processing window temperature of 20&#xb0; C. or more, an energy density absorption of 20% or less, and a melt flow index from 10 cc to 80 cc at 10 minutes. The fusing agent can include an energy absorber capable of absorbing electromagnetic radiation to produce heat.

Material sets

The present disclosure is drawn to material sets for 3-dimensional printing, 3-dimensional printing systems, and 3-dimensional printed parts. A material set can include a polyamide polymer powder having an average particle size from 20 &#x3bc;m to 120 &#x3bc;m and a fusing agent. The polyamide-11 can have a solution viscosity from 1.5 to 1.75 at room temperature, and may increase by no more than 5% after exposure to 180&#xb0; C. for 20 hours. The fusing agent can include an energy absorber capable of absorbing electromagnetic radiation to produce heat.

The present disclosure is drawn to material sets for 3-dimensional printing, 3-dimensional printing systems, and 3-dimensional printed parts. A material set can include a powder bed material of composite particles including glass beads coated with polyamide-12 polymer. The composite particles can have an average particle size from 20 &#x3bc;m to 200 &#x3bc;m, and the polyamide-12 polymer can include greater than 80 meq/g carboxylic end groups and less than 40 meq/g amino end groups. The fusing agent can include an energy absorber capable of absorbing electromagnetic radiation to produce heat.

A three-dimensional (3D) printing method includes applying a build material, including: a plurality of first reactive particles; a plurality of second reactive particles, the first and second reactive particles to react with each other upon contact there with; and a coating on i) the plurality of first reactive particles; or ii) the plurality of second reactive particles; or iii) both i) and ii). The coating is to isolate the plurality of first reactive from the plurality of second reactive particles. A fluid is selectively applied on a portion of the build material, the fluid disrupting the coating on the portion of the build material to render the first and second reactive particles in the portion of the build material in contact with each other. The contact initiates mutual reacting and fusing between the first and second reactive particles.

The present disclosure discloses a charge roller () particularly but not exclusively for charging a photoconductor in a liquid electro-photograph (LEP) image-forming apparatus. The charge roller includes a cured composition of an epichlorohydrin/ethylene oxide/allyl glycidyl ether terpolymer, a lithium salt and carbon black.

Charge roller

A fixable, UV curable ink includes an aqueous ink vehicle including water and a co-solvent, a pigment, and a dispersant. A polyurethane polymer dispersion is suspended as droplets within the aqueous ink vehicle. The polyurethane polymer dispersion includes a polyurethane polymer selected from the group consisting of a polyether-based polyurethane, a polyester-based polyurethane, a polycarbonate-based polyurethane, and mixtures thereof. The polyurethane polymer has i) an acid number ranging from 0 mg/g to less than 20 mg/g and ii) a glass transition temperature of less than 0&#xb0; C. A water soluble or water dispersible photoinitiator is present in the fixable, UV curable ink. A base may be included in an amount sufficient to adjust a pH of the UV curable ink so that it ranges from 7.5 to 9.5. An additive may be included and selected from the group consisting of a biocide, a non-ionic surfactant, an anti-kogation agent, a buffer, and combinations thereof.

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San Diego, CA, United States of America

Yi Feng