National Research Council of Canada

Other

Tsinghua University

Samsung Display Co., Ltd.

Ye Tao

Zhiyi Zhang

Jianping Lu

Gaozhi Xiao

Ta-Ya Chu

Yuning Li

Jianfu Ding

Heping Ding

Christophe Py

Afshin Dadvand

Salima Alem

Marie D'lorio

Yun Chi

Pi-Tai Chou

Mario Leclerc

Zhao Li

Shoude Chang

Jan J Dubowski

Ryan Griffin

Jean-Francois Morin

Arthur Carty

Michael Day

Hiroshi Fukutani

Nicolas Drolet

Kathleen Sirois

Yung-Liang Tung

Mark Bortolus

Jesse Quinn

George Xiao

Man Shing Wong

Arthur J Carty

Gaozhi George Xiao

Zhao Ll

Marie D'iorio

The present application relates to copolymer-silica hybrid aerogels as well as methods for the preparation thereof. The methods comprise hydrolyzing a silica precursor in an organic solvent to obtain a partially polymerized silica wet gel, reacting the partially polymerized silica wet gel with a copolymer of Formula (II) to obtain a copolymer-silica hybrid wet gel, reacting the copolymer-silica hybrid wet gel with a surface passivation agent and removing solvent from the copolymer-silica hybrid wet gel to obtain the copolymer-silica hybrid aerogel. The mechanical properties of the copolymer-silica hybrid aerogels can be further improved by blending cellulose nanofibrils into the hybrid aerogels. (II)

Copolymer-silica hybrid aerogels and methods for the preparation thereof

The development of air-stable unipolar n-type semiconductors with good solubility in organic solvents at room temperature remains a critical issue in the field of organic electronics. Moreover, most of the existing semiconducting materials exhibit LUMO energy levels higher than &#x2212;4.0 eV, making electron transport sensitive to both moisture and oxygen. Bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide or derivatives thereof are disclosed herein. More specifically, bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide or derivatives thereof for use in organic electronics are disclosed. A process for the preparation of bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide and derivatives is also disclosed. The bis(2-oxoindolin-3-ylidene)benzodifurandione dicyanide or derivatives thereof are characterized by high electron mobilities and are suitable for use as n-type semiconductors in organic electronics.

3,7-bis(2-oxoindolin-3-ylidene)benzo[1,2-b:4,5-b']difuran-2,6-dione dicyanide-based materials and uses thereof in organic electronic devices

Disclosed is a method of printing an ultranarrow line of a functional material. The method entails providing a substrate having an interlayer on the substrate and printing the ultranarrow line by depositing ink on the interlayer of the substrate, the ink comprising the functional material and a solvent mixture that partially dissolves the interlayer on the substrate to cause the ink to shrink and sink into the interlayer on the substrate thereby reducing a width of the line.

Method of printing ultranarrow line

A method is disclosed for aligning layers in fabricating a multilayer printable electronic device. The method entails providing a transparent substrate upon which a first metal layer is deposited, providing a transparent functional layer over the first metal layer, depositing metal nano particles over the functional layer to form a second metal layer, exposing the metal nano particles to intense pulsed light via an underside of the substrate to partially sinter exposed particles to the functional layer whereby the first metal layer acts as a photo mask, and washing away unexposed particles using a solvent to leave partially sintered metal nano particles on the substrate.

Self-aligning metal patterning based on photonic sintering of metal nanoparticles

Methods are provided for fabricating photodetector arrays using passive matrix addressing technology. The photodetector arrays use a pair of switching diode and photo diode to overcome crosstalk issues within the passive matrix. The switching diode and the photo diode of each pixel may be connected using a cathode-to-cathode connection, or an anode-to-anode connection. The photodetector arrays are fabricated by assembling on a first substrate, an array of photodetector pixels comprising a switching diode and a photo diode, providing conductive lines for each row of the array and conductive lines for each column of the array, and attaching a second substrate to the first substrate. The photodetector array may also be fabricated by assembling on a first substrate an array of switching diodes, and assembling on a second substrate an array of photo diodes, and bonding the first and second substrates together.

Methods of manufacturing printable photodetector array panels

The present disclosure relates to conductors comprising a conducting member comprising silver and a functionalized organosiloxane network having at least one functional group capable of trapping silver or a silver ion as well as to methods of preparing the same. For example, the functionalized organosiloxane network can at least substantially inhibit dendrite formation between a first conducting member and a second conducting member. For example, the conductors may be used in an electronic circuit such as a printed electronic circuit.

Conductors comprising a functionalized organosiloxane network and methods for the preparation thereof

A voltage and current triggered switch that turns on when a voltage across the switch reaches a turn-on voltage and that turns off when a current through the switch drops below a holding current. The switch features a Zener diode having a breakdown voltage. The Zener diode is connected to set the turn-on voltage of the switch to be the breakdown voltage of the Zener diode. Also provided is a step-down DC-DC converter comprising such a switch. Also provided is a system that has a tribo-electricity source or a piezo-electricity source, the provided step-down DC-DC converter and a load connected to an output of the stepdown DC-DC converter.

Voltage and current triggered switch, and step-down DC-DC converters containing such a switch

Disclosed is a method of printing ultranarrow-gap lines of a functional material, such as an electrically conductive silver ink. The method entails providing a substrate having an interlayer coated on the substrate and printing the ultranarrow-gap lines by depositing ink on the interlayer of the substrate, the ink comprising the functional material and a solvent that swells the interlayer to cause the interlayer to bulge at edges of the ink to thereby define embankments that confine the ink.

Method of printing ultranarrow-gap lines

A process for depositing a metal on a substrate involves the use of two reduction reactions in a bottom-up based tandem manner starting from a substrate surface and working upward. A first reduction reaction starts on the substrate surface at ambient temperature, and a second reduction reaction, which is initiated by the reaction heat of the first reduction reaction, occurs in a reactive ink solution film coated on top, which becomes solid after the reaction. Gas and other small molecules generated from the reduction reactions, and the solvent, can readily escape through the upper surface of the film before the solid metal layer is formed or during post-treatment, with no or few voids left in the metal film. Thus, the process can be used to form highly conductive films and features at ambient temperature on various substrates.

Process for depositing metal on a substrate

Compounds of Formula (I): (formula (I)) where: Xand Xare the same or different and each is independently Cl, Br, I, a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group; and, Y is O, S, Se, NR, RC&#x2014;CRor RC&#x2550;CR, wherein Rand Rare the same or different and are each independently H or an organic group, are useful as monomers to produce oligomers or polymers that are useful in organic electronic devices. 

Fluorinated monomers, oligomers and polymers for use in organic electronic devices

Organic Field Effect Transistor (OFET), an Organic Light Emitting Diode (OLED), an and an Organic Photovoltaic Cell (OPC) including as active material a conjugated oligomeric or polymeric 2,7-carbazolenevinylene derivative described by the formula (I) or (II):  Such OFETs, OLEDs and OPCs have improved devices properties and efficiencies.

2,7-carbazolenevinylene derivatives as novel materials in producing organic based electronic devices

There is disclosed herein phosphorescent compounds, uses thereof, and devices including organic light emitting diode (OLEDs) including such compounds. Compounds of interest include:  The anionic chelating chromophores N^N, which are formed by connecting one pentagonal ring structure containing at least two nitrogen atoms to a hexagonal pyridine type of fragment via a direct carbon-carbon linkage. L is a neutral donor ligand; the typical example includes carbonyl, pyridine, phosphine, arsine and isocyanide; two neutral L's can also combine to produce the so-called chelating ligand such as 2,2'-bipyridine, 1,10-phenanthroline and N-heterocyclic carbene (NHC) ligand, or bidentate phosphorous ligands such as 1,2-bis(diphenylphosphino)ethane, 1,2-bis(diphenylphosphino)benzene. L can occupy either cis or trans orientation. When L occupies the trans position, the preferred structure contains both the hexagonal fragment of N^N as well as its pentagonal fragment located at the trans position respect to their counterparts of the second N^N chromophore. When L occupies the cis position, the preferred structure consists of the pentagonal unit of N^N chromophores residing opposite to the L. 

Phosphorescent Osmium (II) complexes and uses thereof

The invention disclosed relates to cross-linkable composites of boronic acid or a boronic acid derivative such as a boronate, and an organic or organo-metallic moiety having a functionality such as hole transporting, electron transporting and light emitting, to cross-linked composites and to methods for making same. Multi-layer materials and optoelectronic devices including such cross-linked composites are also disclosed.

Thermally crosslinkable materials and multi-layered devices therefrom

A method of making an organic light emitting device (OLED) is disclosed wherein an inert insulating conformal smoothing layer is deposited over a protruding structure. The smoothing layer is patterned to expose portions of the structure underlying the smoothing layer and defining active regions of the device. The inert smoothing layer is treated, preferably by heat reflow, to taper the layer over the stepped edges of the structure on the exposed portions. Additional layers are then deposited over the smoothing layer and the exposed portions of the structure. The smoothing layer blunts all underlying layer edges and provides sloped edges wherever a step occurs from one layer to another. This effect results in a homogeneous field across the pixel and the continuity in the layers deposited after the photoresist layer.

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Ottawa, Canada

Ye Tao