Lg Energy Solution, Ltd.

Lg Chem, Ltd

Dongguk University Industry-Academic Cooperation Foundation

Ye Ri Kim

Oh Byong Chae

Sang Wook Woo

Eun Kyung Kim

Seung Hae Hwang

Jun Hyuk Song

Ju Ho Chung

Byung Hun Oh

Su Yeon Lee

Seo Young Jeon

Yong Ju Lee

Je Young Kim

Sung Bin Park

Hyun Woong Yun

Rae Hwan Jo

Dong Sub Jung

Mi Ru Jo

Yong Mook Kang

A method of manufacturing a negative electrode wherein, in the pre-lithiation of a negative electrode structure including a negative electrode active material layer formed therein through electrochemical charging in a roll-to-roll manner, the negative electrode active material layer is divided into a central part and a side part. The charge current applied to the central part is higher than the charge current applied to the side part. In addition, in the method of manufacturing the negative electrode a pre-lithiation section is divided into a first section and a second section, the central part is electrochemically charged in the first section, the side part is electrochemically charged in the second section, and the central part and the side part are alternately electrochemically charged in one or more cycles.

Method of manufacturing negative electrode

An apparatus for pre-lithiating a negative electrode includes a pre-lithiation reactor having a pre-lithiation solution accommodated therein, a high-pressure chamber surrounding the pre-lithiation reactor, wherein an internal air pressure of the high-pressure chamber is configured to exceed atmospheric pressure, at least one lithium metal counter electrode disposed in the pre-lithiation solution, the lithium metal counter electrode being disposed to face a negative electrode receivable in the pre-lithiation solution in a state that the lithium metal counter electrode is spaced apart from the negative electrode by a predetermined interval, and a charge and discharge unit being connectable to the negative electrode and the lithium metal counter electrode to provide a circuit.

Apparatus for pre-lithiation of negative electrode and method for pre-lithiation of negative electrode

A device for pre-lithiation including a pre-lithiation reactor sequentially divided into an impregnation section, a pre-lithiation section, and an aging section. The pre-lithiation reactor accommodates a pre-lithiation solution through which a negative electrode structure is moved. A negative electrode roll is arranged outside the pre-lithiation solution, and the pre-movement negative electrode structure is wound. A lithium metal counter electrode is arranged in the pre-lithiation solution of the pre-lithiation section, and is arranged to be spaced apart from the negative electrode structure to face the negative electrode structure moving in the pre-lithiation solution. A charging and discharging unit is connected to the negative electrode structure and connected to the lithium metal counter electrode. The lithium metal counter electrode is tilted and a separation distance between the lithium metal counter electrode and the negative electrode structure gradually increases in the moving direction of the negative electrode structure.

Device for pre-lithiation of negative electrode and method for pre-lithiation of negative electrode

Disclosed is a method of preparing a negative electrode which includes the steps of: forming a cell by sequentially stacking a preliminary negative electrode, a separator, and a lithium metal, immersing the cell in an electrolyte solution comprising a lithium salt and a solvent; applying a current after the cell is immersed in the electrolyte solution containing the lithium salt and the solvent, separating the preliminary negative electrode from the cell after removing the cell immersed in the electrolyte solution from the electrolyte solution, washing the separated preliminary negative electrode, performing a first drying on the washed preliminary negative electrode at room temperature, and performing a second drying on the first dried preliminary negative electrode at a temperature ranging from 30° C. to 70° C. in a vacuum state.

Method of preparing negative electrode

A method for manufacturing negative electrode active material including the steps of manufacturing a pellet by extruding a mixture of lithium metal and negative electrode active material, immersing the pellet in an electrolyte comprising an SEI film-forming additive, and manufacturing the pellet into powder form by grinding, washing and drying same. A negative electrode and a lithium rechargeable battery manufactured using the lithium-active material powder has an SEI film that is uniformly formed by having lithium uniformly doped in the negative electrode. During initial charging, the SEI film is stably formed, and thus an effect is achieved whereby the initial efficiency of the lithium rechargeable battery is improved.

Material, negative electrode comprising same and methods for manufacturing same

Disclosed is a method of manufacturing a negative electrode, wherein a negative electrode structure is electrochemically charged while being pressed with a plurality of pre-lithiation rolls in performing pre-lithiation of the negative electrode structure by a roll-to-roll method, and here, the pressing pressures of the plurality of pre-lithiation rolls are increased in a movement direction of the negative electrode structure. Since the pressing pressures are increased in the movement direction of the negative electrode structure, volume expansion, structural deformation, and damage to an active material due to the pre-lithiation may be prevented, and at the same time, the pre-lithiation may be performed uniformly, and thus it is preferable for improving lifespan characteristics of a negative electrode.

A method of producing a negative electrode for a lithium secondary battery. The production method of the present invention includes a process of charging the negative electrode at a low current during pre-lithiation and a process of aging the negative electrode after the pre-lithiation for a sufficient time, thereby producing a negative electrode for a lithium secondary battery having excellent cycle performance.

Method of producing negative electrode for lithium secondary battery

A device for producing a negative electrode, which includes: a pre-lithiation bath containing a pre-lithiation solution, which is sequentially divided into an impregnation section, a pre-lithiation section, and an aging section; a negative electrode roll present outside the pre-lithiation solution, wherein the negative electrode roll is configured to allow a negative electrode structure to be wound and unwound; and one or more pre-lithiation rolls which are present inside the pre-lithiation solution, wherein the one or more pre-lithiation rolls allow the negative electrode structure unwound from the negative electrode roll to move in the pre-lithiation bath, wherein the pre-lithiation roll includes an inner ring, an outer ring which is formed on the inner ring and is rotatable, and a rolling element present between the inner ring and the outer ring, and the outer ring in the pre-lithiation roll comprises a non-conductor.

Device for producing negative electrode and method of producing negative electrode

A method of producing a negative electrode, which includes: providing a negative electrode roll on which a negative electrode structure is wound, the negative electrode structure includes a negative electrode current collector and a negative electrode active material layer on at least one surface of the negative electrode current collector; providing a pre-lithiation bath containing a pre-lithiation solution, which is sequentially divided into an impregnation section, a pre-lithiation section, and an aging section; impregnating the negative electrode structure with the pre-lithiation solution while unwinding the negative electrode structure from the negative electrode roll and moving the same through the sections. The pre-lithiation is performed by disposing a lithium metal counter electrode, which is spaced apart from the negative electrode structure and impregnated with the pre-lithiation solution, in the pre-lithiation section and electrochemically charging the negative electrode structure.

Method of producing negative electrode

A negative electrode for a lithium secondary battery, a negative electrode in which the negative electrode is pre-lithiated, a method of manufacturing the negative electrode, and a lithium secondary battery including the negative electrode. The pre-lithiated negative electrode may increase the capacity and improve the electrochemical performance of a lithium secondary battery by securing the initial reversibility of a negative electrode.

Negative electrode for lithium secondary battery, method for pre-lithiation thereof, and lithium secondary battery including same

A method of producing a negative electrode for a secondary battery, which includes: forming a negative electrode structure including a negative electrode current collector having two surfaces and a negative electrode active material layer formed on at least one surface of the negative electrode current collector; preparing a pre-lithiation cell including the negative electrode structure, a lithium metal counter electrode disposed to face the negative electrode active material layer of the negative electrode structure, and a separator interposed between the negative electrode structure and the lithium metal counter electrode; immersing the pre-lithiation cell in a pre-lithiation solution; and carrying out pre-lithiation by electrochemically charging the pre-lithiation cell while pressing the pre-lithiation cell at a pressure of 15 kPa to 3,200 kPa.

Method of producing negative electrode for secondary battery

A method of manufacturing a negative electrode for lithium secondary batteries. With the method, a negative electrode for lithium secondary batteries having excellent cycle performance may be manufactured by performing a process of compressing the negative electrode after pre-lithiation of the negative electrode so that the porosity of the negative electrode after the pre-lithiation is maintained within a certain range.

Method of manufacturing negative electrode for lithium secondary batteries

A method of manufacturing a negative electrode for a secondary battery, which includes: forming a negative electrode structure including a negative electrode current collector and a negative electrode active material layer formed on a surface of the negative electrode current collector; providing a pre-lithiation solution in which a lithium metal counter electrode is immersed and immersing the negative electrode structure in the pre-lithiation solution so that the negative electrode structure is spaced apart from the lithium metal counter electrode; and subjecting the negative electrode structure to a pre-lithiation process, which includes an electrochemical charging process and an electrochemical discharging process performed after the electrochemical charging process, wherein a state of charge (SOC) of the negative electrode structure subjected to the pre-lithiation process is in a range of 5% to 50%.

Method of manufacturing negative electrode for secondary battery

A method of manufacturing a negative electrode for a secondary battery. The method includes forming a first negative electrode active material layer including a carbon-based active material on at least one surface of a negative electrode current collector; and forming a second negative electrode active material layer including a silicon-based active material on a surface of the first negative electrode active material opposite the negative electrode current collector, wherein the silicon-based material is intercalated with lithium by pre-lithiation on the first negative electrode active material layer.

A method of producing a negative electrode is disclosed which is capable of preventing volume expansion and structural deformation caused by pre-lithiation, maintaining proximity and contact between negative electrode active materials, preventing an increase in resistance of a negative electrode, and realizing an excellent capacity retention rate by performing pre-lithiation while pressurizing a negative electrode at a specific pressure. In addition, the method of producing a negative electrode is capable of improving quality consistency of a product and processability by performing pre-lithiation of a negative electrode in a roll-to-roll manner.

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Daejeon, South Korea

Ye Ri Kim