Nippon Steel Corporation

Nippon Steel & Sumitomo Metal Corporation

Nippon Steel Chemical & Material Co., Ltd.

Nippon Steel & Sumikin Materials Co., Ltd.

Yasuto Goto

Kiyokazu Ishizuka

Kohei Tokuda

Mamoru Saito

Takehiro Takahashi

Masao Kurosaki

Shinichi Yamaguchi

Kenichiro Matsumura

Jun Maki

Takuya Mitsunobu

Fumiaki Nakamura

Kosuke Kawamoto

Koichi Nose

Masaharu Ibaragi

Hiroto Unno

Nobuyuki Shimoda

Akinobu Kobayashi

Koji Kawanishi

Koki Shimada

Hidetoshi Shindo

Shuji Nagasaki

Takashi Futaba

Yuto Fukuda

Yuta Dairokuno

Kotaro Ishii

Masayuki Abe

Atsushi Morishita

Hiroshi Takebayashi

Hiromasa Shoji

Tatsuo Nagata

Nobuo Kadowaki

Yasuaki Kawamura

Seiji Sugiyama

Teruaki Izaki

Yoshinari Ishida

Toshinori Mizuguchi

Katsumasa Matsumoto

Ikumi Tokuda

Hironori Satoh

Tetsuya Toba

Kensuke Mizuno

Yusho Oyama

Hisashi Baba

Takumi Kozaki

Manabu Kumagai

Tomohide Kamiyama

Ryohei Mimura

Yuji Kajii

Yasuhiro Majima

Naoyuki Yamato

Yuta Tajima

This metallic coated steel includes a steel material and a metallic coating layer. The metallic coating layer has an average chemical composition including Al: 0.2% to less than 4.0%, Mg: more than 4.0% and less than 12.5%, Ca: 0.15% to less than 3.00%, Zn: 65% or more, and impurities. In an any perpendicular cross section (in a thickness direction) in the metallic coating layer, a metallurgical structure observed in a scanning electron microscope observed visual field contains, in terms of area fraction, an MgZnphase: 10 to 40%, an Al—Zn phase: 0 to 15%, an Al phase: (Zn<10%): 0 to 5%, a CaZnphase: 1.0 to 15%, and a total of a [ternary eutectic structure of Al/MgZn/Zn] and a [binary eutectic structure of MgZn/Zn]: 30% or more.

Metallic coated steel

A hot-dip plated steel material has a plating layer on a surface of a steel material, in which the plating layer contains Al: more than 22.5% and 50.0% or less, Mg: more than 3.0% and 15.0% or less, Ca: 0.03 to 0.6%, Si: 0.03 to 1.0%, Fe: 2 to 25%, and a remainder consisting of Zn and impurities, and, in an X-ray diffraction pattern of a surface of the plating layer, measured under conditions in which an X-ray output is a voltage of 50 kV and a current of 300 mA using a Cu-Kα ray, Iobtained from an X-ray diffraction peak of AlFeis 1.1 or more, and Iobtained from X-ray diffraction peaks of Zn, Al, and MgZnis 0.25 or less.

Hot-dip plated steel material

A surface-treated steel sheet of the present disclosure includes a steel sheet, and an alloy layer containing Ni and Co on a surface of the steel sheet. A surface roughness Ra1 of the surface of the alloy layer over a sampling length of 5.0 mm in the width direction of the steel sheet is 2.0 μm or less. Ra2 that denotes the arithmetic mean height of a roughness curve of the surface of the alloy layer over a sampling length of 10 μm in the width direction of the steel sheet is 20 nm or less, and RSm that denotes the mean length of roughness curve elements over the sampling length of 10 μm in the width direction of the steel sheet is 700 nm or more, Ra2 and RSm being measured using an atomic force microscope.

Surface-treated steel sheet

The surface-treated steel sheet includes an alloy layer containing Ni and Co. In a case where, in a cross section obtained by cutting the alloy layer in the thickness direction, a range having a width of 2000 nm and extending from the surface of the alloy layer to a depth of 100 nm is partitioned into regions each having a width of 100 nm and a depth of 100 nm, within the range the alloy layer includes a plurality of high Co concentration regions in each of which the ratio of a Co concentration to a sum of the Co concentration and a Ni concentration within the partitioned region is 0.8 or more, and a plurality of alloyed regions in each of which a ratio of the Co concentration to a sum of the Co concentration and the Ni concentration within the partitioned region is less than 0.8.

A plated steel sheet comprises a plated layer on a surface of a steel sheet, in which in the plated layer, the total amount ΣA of Sn, Bi, and In is less than 0.75%, the total amount ΣB of Ca, Y, La, and Ce is 0.03 to 0.60%, the total amount ΣC of Cr, Ti, Ni, Co, V, Nb, Cu, and Mn is 0 to 1.00%, Sn≤Si, and 20.0≤Mg/Si are satisfied, and in an X-ray diffraction pattern of a surface of the plated layer, an X-ray diffraction peak of AlZnCa, an X-ray diffraction peak of CaZn, and an X-ray diffraction peak of η'-MgZnsatisfy a predetermined relationship.

Plated steel sheet

A surface-treated steel sheet includes a steel sheet, and an Ni—Co—Fe alloy layer containing Ni, Co, and Fe on the steel sheet surface. In the thickness direction of the Ni—Co—Fe alloy layer, a Co concentration in the Ni—Co—Fe alloy layer is highest at a position which is on an outermost surface side of the Ni—Co—Fe alloy layer relative to a position where the Ni concentration is highest in the Ni—Co—Fe alloy layer, and which is between the outermost surface of the Ni—Co—Fe alloy layer and a depth of 100 nm from the outermost surface. In the Ni—Co—Fe alloy layer, an Ni-concentrated region in which the Ni concentration increases toward the outermost surface of the Ni—Co—Fe alloy layer is formed between the outermost surface of the Ni—Co—Fe alloy layer and the position where the Co concentration is highest.

A Ni-plated steel sheet includes a base steel sheet and a Ni-based coating layer that is disposed on a surface of the base steel sheet. The distribution of carbon concentration in a depth direction obtained by performing GDS analysis on the Ni-plated steel sheet has a peak indicating the carbon concentration that is equal to or more than twice the carbon concentration of a thickness middle portion of the base steel sheet in the vicinity of an interface between the base steel sheet and the Ni-based coating layer.

Ni-plated steel sheet, and method for manufacturing Ni-plated steel sheet

A plated steel material having a plating layer having an average chemical composition containing, in mass %, Zn: more than 50.00%, Al: more than 15.0% and less than 30.0%, Mg: more than 5.0% and less than 15.0%, and Si: 0.25% or more and less than 3.50%, and impurities, and wherein a total amount (ΣA) of at least one selected from the group consisting of Sn, Bi and In is less than 1.00%, a total amount (ΣB) of at least one selected from the group consisting of Ca, Y, La, Ce and Sr is 0.02% or more and less than 0.60%, 2.0≤SMg/Si<20.0 (Formula 1), 3.0≤Si/ΣB<24.0 (Formula 2), and 26.0≤(Si/ΣB)×(Mg/Si)<375.0 (Formula 3) are satisfied, and in an X-ray diffraction pattern of the surface of the plating layer, a diffraction intensity ratio R1 defined by R1={I(16.18°)+I(32.69°)}/I(27.0°) (Formula 4) satisfies 2.5<R1 (Formula 5) is used.

Plated steel material

A Ni diffusion-plated steel sheet of the present invention includes a base steel sheet and a Fe—Ni diffusion alloy-plating layer positioned on at least one surface of the base steel sheet, an Ni coating weight of the Fe—Ni diffusion alloy-plating layer is 9.0 to 20 g/m, a Fe concentration Cs of an outermost layer of the Fe—Ni diffusion alloy-plating layer is 10 to 55 mass %, the base steel sheet has a predetermined chemical composition, and a ferrite grain size number specified by JIS G 0551 (2013) of the base steel sheet is 11.0 or more.

Ni diffusion-plated steel sheet and method for manufacturing Ni diffusion-plated steel sheet

A novel battery container that can be obtained by welding plated steel sheets, has sufficient sealing ability over a long period of time, and is able to keep the base material of the plated steel sheets from being exposed and eluting into the electrolyte solution is provided. That is, a battery case comprised of a container body and a container lid, wherein the container body and the container lid are each comprised of a plated steel sheet, a joint part between the container and the container lid is comprised of a plating welded part containing a main constituent component of the plating of the plated steel sheet in 60 mass % or more and a steel sheet welded part containing the main constituent component of the plating in less than 60 mass %, and the plating welded part has a length of 0.5 μm or more and less than 1.0 mm in a joint longitudinal direction.

Battery case

A Ni-plated steel sheet according to one aspect of the present invention includes a base steel sheet; and a Ni plating layer provided on a surface of the base steel sheet, wherein the Ni plating layer includes a Ni—Fe alloy layer formed on the surface of the base steel sheet, and a ratio of a Sn content to a Ni content in the Ni plating layer is 0.0005% to 0.10%.

Ni-plated steel sheet and manufacturing method thereof

A Ni-plated steel sheet according to one aspect of the present invention includes a base steel sheet and a Ni plating layer provided on a surface of the base steel sheet, the Ni plating layer has a Ni—Fe alloy layer formed on a surface of the base steel sheet, and a ratio of a Zn content to a Ni content in the Ni plating layer is 0.0005% to 0.10%. A manufacturing method of the Ni-plated steel sheet according to one aspect of the present invention has electroplating a base steel sheet using a Ni plating bath in which [Zn]/[Ni] is set to 0.0005% to 0.10% to obtain a material Ni-plated steel sheet, and annealing the material Ni-plated steel sheet.

A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of φ30 μm using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.

Surface-treated metal material

The plated steel material is a plated steel material including a steel material and a plating layer provided on the surface of the steel material, wherein the plating layer has a predetermined average chemical composition, when the amount of Mg is % Mg and the amount of Al is % Al, % Mg/% Al is 0.80 or more, and a metal structure in a total field of view of 25,000 μmin a vertical cross section which is a cross section in a thickness direction of the plating layer includes 10 to 40 area % of a MgZnphase, 10 to 30 area % of an Al—Zn phase with a Zn content of 10% or more, 0 to 15 area % of an Al phase with a Zn content of less than 10%, and 25 area % or more of an Al/MgZn/Zn ternary eutectic structure.

A coated steel product including a base steel, and a coating layer containing a Zn&#x2014;Al&#x2014;Mg alloy layer disposed on a surface of the base steel, in which the coating layer has a predetermined chemical composition, the coated steel product including dendrite-shaped MgZnphase having a surface roughness Sa of 50 nm or less on a surface of the Zn&#x2014;Al&#x2014;Mg alloy layer, an area ratio of the dendrite-shaped MgZnphase having a surface roughness Sa of 50 nm or less being from 30% to 80% within a region of an observable field of view of 5 mm, and among the dendrite-shaped MgZnphase having a surface roughness Sa of 50 nm or less, a number of dendrite-shaped MgZnphase having an area ofmmor more being from 5 to 100 within a region of an observable field of view of 25 mm.

Coated steel product

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Tokyo, Japan

Yasuto Goto