Daiso Co., Ltd.

Yasushi Hamura

Toshiyuki Funayama

Toyofumi Otaka

Shigeru Shoji

The present invention provides a vulcanized rubber material having improved heat resistance while maintaining ozone resistance of an epihalohydrin rubber, and a rubber composition for vulcanization for producing the same. The invention further provides a vulcanized rubber material and a rubber composition for vulcanization, that can achieve the above objects without using an organonickel compound having a concern about toxicity, or if used, using the same as less as possible. The present invention relates to a rubber composition for vulcanization comprising (a) 100 parts by weight of an epihalohydrin rubber, (b) 0.01 to 0.5 part by weight of a copper salt of dithiocarbamic acid, (c) an acid acceptor, and (d) a polythiol type vulcanizing agent or a polyol type vulcanizing agent, a vulcanized rubber material obtained by vulcanizing the composition, and an automotive rubber part comprising the vulcanized rubber material.

Rubber composition for vulcanization

The invention provides a vulcanized rubber laminate obtained by firmly bonding an unvulcanized epichlorohydrin rubber layer and an organic peroxide-containing fluororubber layer. The laminate is obtained by thermal adhesion a layer of an unvulcanized epichlorohydrin rubber composition to a layer of an unvulcanized fluororubber composition. The epichlorohydrin rubber composition comprises 1) an unvulcanized epichlorohydrin rubber containing 3 to 15 mol % of allyl glycidyl ether unit, 2) quinoxaline-based vulcanizing agents, mercaptotriazine-based vulcanizing agents or bisphenol-based vulcanizing agents, and 3) 1,8-diazabicyclo(5,4,0)undecene-7 salts, 1,5-diazabicyclo(4,3,0)nonene-5 salts, quaternary ammonium salts, quaternary phosphonium salts, basic white carbons or an alkaline metal salt of higher fatty acid the fluororubber composition comprises an fluororubber and an organic peroxide-based vulcanizing agent.

Vulcanized rubber laminate

A composition for epihalohydrin vulcanized rubber excellent in heat resistance while keeping good vulcanization rate and store stability, comprising (a) an epihalohydrin robber, (b) a metal soap, (c) an acid acceptor, and (d) a vulcanizing agent, the composition further preferably containing (e) a fatty acid for suppressing vulcanization, or preferably containing (f) an alcohol for accelerating vulcanization.

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Osaka, Japan

Yasushi Hamura