Nippondenso Co., Ltd.

Kabushiki Kaisha Toyota Chuo Kenkyusho

Yasuo Nakamura

Osami Kamigaito

Hideyuki Masaki

Masami Oki

Masatoshi Suzuki

Haruo Doi

Toshio Kandori

Masatosi Suzuki

Kazuya Soda

An oxygen concentration detector comprises an oxygen concentration sensor made of an oxygen ion conductive metal oxide which produces an electromotive force in accordance with a difference between an oxygen concentration in gas components of a gas under test and an oxygen concentration in a reference gas, an electrode formed on a surface of the oxygen concentration sensor which is to be exposed to the gas under test and an electrode formed on a surface of the oxygen concentration sensor which is to be exposed to the reference gas so that the electromotive force produced by the oxygen concentration sensor is taken across the electrodes, a first porous coating of a refractory metal oxide formed on the surface of the electrode which is to be exposed to the gas under test, said first coating having a number of pores through which the gas under test can pass, and a second porous coating of a refractory metal oxide formed on the surface of the first coating, said second coating having a number of pores which are larger than the pores of the first coating.

Oxygen concentration detector and method of use thereof

A resistor built-in spark plug comprising an insulator formed therein with an axially extending bore, a terminal nut fitted in an upper end portion of the bore, a center electrode fitted in a lower end portion of the bore, a resistor arranged in a central portion of the bore, one copper-glass electrode interposed between the resistor and the terminal nut, and another copper-glass electrode interposed between the resistor and the center electrode, such resistor being made by firing (calcining) and solidifying a resistor powder mixture consisting of 30 to 10 volume % of a principal resistor component containing tin oxide, 35 to 85 volume % of insulating ceramic filler powder of a higher electric resistivity than the principal resistor component which is selected from the group consisting of quartz glass, alumina, zircon, zirconia, silica (SiO.sub.2) and .beta.-spodumene, and 35 to 5 volume % of glass powder having a softening temperature in a range between 300.degree. and 600.degree. C. One or both of the two copper-glass electrodes may consist of two electrode layers, one copper-glass layer maintained in contact wth the resistor and having a higher copper content than the other copper-glass electrode layer.

Resistor built-in spark plug

A resistor built-in spark plug comprises an insulator formed with an axially extending inner hole, a stem fitted in the upper part of said hole in said insulator, a center electrode fitted in the lower part of said hole, a resistor disposed in the central part of said hole, and copper-glass electrode layers disposed between said resistor and said stem and between said resistor and said center electrode. Said resistor is made by firing and solidifying powder of resistor mixture consisting of 75 to 38 volume percent of main resistor component containing tin oxide and 25 to 62 volume percent of glass powder with softening temperature of 300.degree. to 600.degree.C. Said copper-glass electrode layers are made by firing and solidifying a mixture of copper powder and glass powder with the softening temperature of above 530.degree.C and more than 30.degree.C higher than the softening point of glass in the resistor portion.

Growing community of inventors

Nagoya, Japan

Yasuo Nakamura