Bridgestone Corporation

Yasuo Horikawa

Daniel F Graves

Masato Yoshikawa

Olivier Tardif

Shojiro Kaita

Junko Matsushita

Takao Ogino

Masashi Otsuki

Shigeki Endo

Hideki Kitano

Aya Yanagisawa

Taro Akazawa

Shinichi Eguchi

David M Roggeman

Shinichi Toyosawa

Taichi Kobayashi

Yoshinori Iwabuchi

Hideo Sugiyama

Shingo Ohno

Shigenaga Takano

Madoka Kimura

Toshiki Takizawa

Takayuki Sugimura

Osamu Shiino

Masashi Ohtsuki

William J Kern

Yamato Ono

Midori Kawada

To provide a method for producing a multicomponent copolymer with which a multicomponent copolymer having excellent rupture strength can be obtained, and a multicomponent copolymer, a rubber composition and a tire having excellent rupture strength. The method is a method for producing a multicomponent copolymer having a conjugated diene unit, a non-conjugated olefin unit and an aromatic vinyl unit, comprising adding a conjugated diene compound in divided portions into a reactor containing a catalyst and at least one selected from the group consisting of a non-conjugated olefin compound and an aromatic vinyl compound. The multicomponent copolymer is obtained with the production method. The rubber composition comprises the multicomponent copolymer as a rubber component. The tire uses the rubber composition.

Method for producing multicomponent copolymer, multicomponent copolymer, rubber composition, and tire

Provide is a polymer that can provide excellent toughness and weather resistance to a rubber composition and a rubber product such as a tire. The multicomponent copolymer contains a conjugated diene unit, a non-conjugated olefin unit and an aromatic vinyl unit, where a proportion of conjugated diene units bonded to a unit other than a conjugated diene unit out of the total conjugated diene units is 50% or more.

Multicomponent copolymer, rubber composition, crosslinked rubber composition and rubber product

Provided is a multi-component copolymer comprising conjugated diene units, non-conjugated olefin units and aromatic vinyl units, wherein: a weight-average molecular weight of chain parts, divided by the conjugated diene units and each containing one or more of the non-conjugated olefin units and/or one or more of the aromatic vinyl units, is 50,000 or more. A rubber composition comprising the multi-component copolymer, a crosslinked rubber composition, and a rubber article comprising the crosslinked rubber composition are also provided.

Multi-component copolymer, rubber composition, crosslinked rubber composition and rubber article

To provide a method for producing a multicomponent copolymer with which a multicomponent copolymer having excellent rupture strength can be obtained, and a multicomponent copolymer, a rubber composition and a tire having excellent rupture strength. The method is a method for producing a multicomponent copolymer having a conjugated diene unit, a non-conjugated olefin unit and an aromatic vinyl unit, comprising adding continuously or intermittently continuously a conjugated diene compound into a reactor containing a catalyst and at least one selected from the group consisting of a non-conjugated olefin compound and an aromatic vinyl compound. The multicomponent copolymer is obtained with the production method. The rubber composition comprises the multicomponent copolymer as a rubber component. The tire uses the rubber composition.

An object of the present invention is to provide a multicomponent copolymer for use for producing a crosslinked rubber composition and a rubber product excellent in fracture performance (strength and elongation) at high temperatures while maintaining high weather resistance. Further, the invention provides a rubber composition containing the multicomponent copolymer, a crosslinked rubber composition obtained by crosslinking the rubber composition, and a rubber product and a tire using the rubber composition or the crosslinked rubber composition. The multicomponent copolymer of the invention contains a conjugated diene unit, a non-conjugated olefin unit and an aromatic vinyl unit, wherein the main chain is formed of an acyclic structure alone, the content of the aromatic vinyl unit is 3 mol % or more of the whole multicomponent copolymer, and the content of the non-conjugated olefin unit is more than 44 mol % and less than 97 mol % of the whole multicomponent copolymer.

Multicomponent copolymer, rubber composition, cross-linked rubber composition, rubber product, and tire

Provided is a multi-component copolymer comprising conjugated diene units, non-conjugated olefin units and aromatic vinyl units, wherein: a peak top molecular weight of chain parts, divided by the conjugated diene units and each containing one or more of the non-conjugated olefin units and/or one or more of the aromatic vinyl units, is 1,000 or more and less than 40,000. A rubber composition comprising the multi-component copolymer, a crosslinked rubber composition, and a rubber article comprising the crosslinked rubber composition are also provided.

The present invention provides a random copolymer that is used for manufacturing a rubber having high fracture strength and excellent low loss properties (low heat generation properties) and that includes randomly arranged monomer units of a conjugated diene compound and of a non-conjugated olefin, a rubber composition containing the random copolymer, a cross-linked rubber composition obtained by crosslinking the rubber composition, and a tire manufactured by using the rubber composition or the cross-linked rubber composition. A copolymer of a conjugated diene compound and a non-conjugated olefin includes a random copolymer having randomly arranged monomer units of the conjugated diene compound and of the non-conjugated olefin, which random copolymer contains, by at least 5 mol %, alternate bonding units of the conjugated diene compound and the non-conjugated olefin in a unit derived from the non-conjugated olefin.

Copolymer, rubber composition, crosslinked rubber composition and tire

Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a tapered copolymer including: at least one of a block sequence including monomer units of the conjugated diene compound and a block sequence including monomer units of the non-conjugated olefin; and a random sequence including randomly arranged monomer units of the conjugated diene compound and monomer units of the non-conjugated olefin.

Copolymer, rubber composition, crosslinked rubber composition, and tire

This invention relates to a method for producing a copolymer of a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound having a high cis-1,4 bond content of a conjugated diene compound portion, and more particularly to a method for producing a copolymer characterized by comprising a step of polymerizing a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound in the presence of a polymerization catalyst composition including at least one complex selected from a metallocene complex represented by the following general formula (I): (wherein M is a lanthanoid element, scandium or yttrium, and Cpis independently a non-substituted or substituted indenyl, and R-Rare independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on.

Method for producing copolymer

The present invention provides a rubber composition that is used for manufacturing a rubber excellent in weather resistance, fracture resistance and crack growth resistance, and that contains a conjugated diene compound/non-conjugated olefin copolymer, a conjugate diene-based polymer and a non-conjugated diene compound/non-conjugated olefin copolymer, a rubber composition for tire side use using the rubber composition for tire sidewall members, a crosslinked rubber composition obtained by crosslinking the rubber composition, and a tire. The rubber composition includes: (A) a conjugated diene compound/non-conjugated olefin copolymer containing a conjugated diene compound-derived unit by at least 40 mol %; (B) a conjugated diene-based polymer; and (C) a non-conjugated diene compound/non-conjugated olefin copolymer containing an ethylene-propylene-diene rubber.

Rubber composition, rubber composition for tire side use, crosslinked rubber composition and tire

Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a block copolymer, the conjugated diene compound unit having 1,2 adduct (including 3,4 adduct) content of 5% or less or the conjugated diene compound unit having a cis-1,4 bond content of more than 92%, in which preferred examples of the conjugated diene compound include 1,3-butadiene and isoprene, and preferred examples of the non-conjugated olefin include ethylene, propylene, and 1-butene.

Provided is a block copolymer of a conjugated diene compound and a non-conjugated olefin, a rubber composition including the block copolymer, a crosslinked rubber obtained by crosslinking the rubber composition, and a tire using the rubber composition or the crosslinked rubber composition. The copolymer of the present invention is a block copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer having a peak area in a temperature range in a range of 70&#xb0; C. to 110&#xb0; C. that accounts for at least 60% of a peak area in a range of 40&#xb0; C. to 140&#xb0; C. and a peak area in a range of 110&#xb0; C. to 140&#xb0; C. that accounts for 20% or less of a peak area in a range of 40&#xb0; C. to 140&#xb0; C., the peak areas being measured by the differential scanning calorimetry (DSC) according to JIS K 7121-1987.

In a copolymer of a conjugated diene compound and a non-conjugated olefin, the conjugated diene unit has a cis-1,4 bond content of greater than 70.5% and the non-conjugated olefin is contained in an amount of 10 mol % or more.

Copolymer of conjugated diene compound and non-conjugated olefin, rubber composition, cross-linked rubber composition and tire

Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a random copolymer including randomly arranged monomer units of the conjugated diene compound and of the non-conjugated olefin, in which the non-conjugated olefin is preferably an acyclic olefin, the non-conjugated olefin preferably has 2 to 10 carbon atoms, and specific examples of the non-conjugated olefin preferably include ethylene, propylene, and 1-butene.

Copolymer of a conjugated diene compound and a non-conjugated olefin, rubber composition, crosslinked rubber composition, and tire

The present invention provides a copolymer of a conjugated diene compound and a non-conjugated olefin that is used for manufacturing a rubber excellent in crack growth resistance, heat resistance and ozone resistance and that includes a cis-1,4 bond at a unit derived from the conjugated diene compound, a rubber composition containing the copolymer, a rubber composition for tire treads using the rubber composition for tire tread members, a crosslinked rubber composition obtained by crosslinking the rubber composition, and a tire using the rubber composition or the crosslinked rubber composition. In the copolymer of a conjugated diene compound and a non-conjugated olefin, the cis-1,4 bond content of a unit derived from the conjugated diene compound is more than 92%.

Copolymer of conjugated diene compound and non-conjugated olefin, rubber composition, rubber composition for tire tread, crosslinked rubber composition, and tire

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Kodaira, Japan

Yasuo Horikawa