Mitsubishi Rayon Company, Limited

Yasuo Hiromoto

Toshinori Sumi

Hiroyuki Fujiki

Masaki Kurashina

Tsuneo Takano

Katsuhiko Shimada

Kei Murase

Hirotoshi Mizota

Yoichi Nagai

Masakazu Minagawa

Masashi Teramachi

Hisaaki Yoshimura

Michisuke Edamatsu

Osamu Itamoto

Yoshihide Nagafuchi

Hiroyuki Kumaoka

Takeshi Kato

Tatsuki Yajima

Disclosed is a method for manufacturing a composite porous film having a stable film quality and a desired hollow shape by controlling the entrance of a film-forming resin solution into a hollow part of a hollow reinforcement support. The method is provided with a step of adhering a film-forming resin solution to the outer peripheral surface of the hollow reinforcement support and thereby forming a film intermediate, a step of adhering a coagulating liquid to the outer peripheral surface of the film intermediate, and a step of flowing the coagulating liquid along the outer peripheral surface of the film intermediate so that at least a part of the outermost interface of the coagulating liquid in the circumferential direction is a free surface and thereby coagulating the film-forming resin solution adhering to the outer peripheral surface of the hollow reinforcement support.

Method for manufacturing a porous composite membrane

A method of manufacturing a porous film includes a decomposition step of introducing a porous film precursor which is formed by coagulating an undiluted film forming solution containing a hydrophilic polymer and a hydrophobic polymer, into a decomposition container; bringing a heated chemical containing an oxidizing agent into contact with the porous film precursor in the decomposition container; warming the porous film precursor in contact with the chemical; and decomposing the hydrophilic polymer remaining inside the porous film precursor using the oxidizing agent. An apparatus for manufacturing a porous film includes a decomposition device provided with the decomposition container.

Porous film manufacturing method and apparatus

Disclosed is a drying device for a hollow fiber membrane, including: a tubular drying member that is formed with an opening portion through which a hollow fiber membrane is input and output at at least one end thereof in a length direction, the hollow fiber membrane passing inside the tubular drying member while forming a gap between the hollow fiber membrane and an inner circumferential surface of the tubular drying member; and a gas supply unit that is formed on a side surface of the tubular drying member and supplies a drying gas into the tubular drying member. Thus, it is possible to dry the hollow fiber membrane in a short time at a low cost without the necessity of large equipment.

Drying device and drying method for hollow fiber membranes

A hollow porous membrane with a reduced cost and excellent separation characteristic, water permeability, and mechanical strength and a process of producing the hollow porous membrane with an excellent adhesive property between a support and a porous membrane layer at a low cost are provided. The hollow porous membrane includes a porous membrane layer in which dense layers are disposed in the vicinities of an outer surface and an inner surface. In the process of producing the hollow porous membrane, membrane-forming dopes of a first membrane-forming dope and a second membrane-forming dope, which contain the material of the porous membrane layer and a solvent, are successively applied and stacked onto the outer circumferential surface of a hollow support and the applied membrane-forming dopes are simultaneously coagulated. In the process of producing the hollow porous membrane, a porous membrane layer is formed by applying a membrane-forming dope containing a material of the porous membrane layer and a solvent to the outer circumferential surface of the hollow support and coagulating the applied dope, and a hollow braid obtained by circularly knitting a yarn formed of multi-filaments is used as the support.

Hollow porous membrane and process for producing the same

A vinyl-based polymer having a mass average molecular weight of 1500 to 10000, which is prepared by a first step of continuously feeding a material mixture containing a vinyl-based monomer to a continuous tank type first reactor, and polymerizing the vinyl-based monomer under the conditions of a polymerization temperature of 150&#xb0; to 300&#xb0; C. and a retention time of 1 to 60 minutes at a rate of polymerization of 50 to 99% to obtain a reaction intermediate mixture; and a second step of feeding a polymerization initiator in the amount of 0.01 to 5 parts by mass based on 100 parts by mass of the vinyl-based monomer and the reaction intermediate mixture to a second reactor, and further polymerizing the vinyl-based monomer under the conditions of a polymerization temperature of 100&#xb0; to 200&#xb0; C. and a retention time of 10 to 240 minutes at a rate of polymerization of 80% or more.

Vinyl polymer, process for producing vinyl polymer, thermosetting coating composition, and coating material

A method and apparatus for producing a polymer-clad silica (PCS) optical fiber comprising a core of a transparent inorganic glass and a cladding of a transparent organic polymer characterized in that the amount of volatile components in its cladding is not more than 1 wt %, which method and apparatus comprise forming the core fiber, forming the cladding around the core fiber, and treating the cladding with a far infrared heater.

Plastic-clad silica (PCS) fibers and methods and apparatuses for

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Otake, Japan

Yasuo Hiromoto