Nitto Boseki Co., Ltd.

Yasuhito Nakata

Yusuke Fukushima

Minoru Takeuchi

Ikuo Hayashi

Tadashi Kato

Tadao Endo

Hiroyuki Takayama

Yusuke Sato

Provided is a process for producing a copolymer of a diallylamine and sulfur dioxide which copolymer has a higher molecular weight and water-solubility than that obtained by a conventional production process by copolymerizing the diallylamine and sulfur dioxide in the presence of an acid and a radical polymerization initiator in a polar solvent.

Method for producing copolymer of diallylamine and sulfur dioxide

Provided is a process for producing a copolymer of diallyldialkylammonium salt and a maleic acid which copolymer is free of residual monomers and polymerization initiator and hence stably exhibits excellent performances in various uses, and the process comprises polymerizing a monomer mixture comprising diallyldialkylammonium salt and maleic acid in the presence of persulfate as a radical polymerization initiator in water or a polar solvent, and completion of the polymerization-reaction, decomposing the radical polymerization initiator to produce a copolymer comprising diallyldialkylammonium salt constituent unit and a maleic acid constituent unit.

Method for producing diallyldialkylammonium salt/maleic acid copolymer

Provided is a method for producing a diallylamine acetate polymer comprising polymerizing diallylamine acetate in water or a polar solvent in the presence of a radical initiator, the radical initiator being an organic acid addition salt of a specific cyclic amidinoazo compound, and a diallylamine acetate polymer solution free of halogen.

Method for producing diallylamine acetate polymer

Provided is an industrially advantageous process for producing allylamine polymers from various allylamines in an organic solvent with ease and at high yields, and the process comprises polymerizing allylamines in a medium containing an organic solvent in the presence of an azo compound selected from azo compounds of the formulae (I) and (II),

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Fukushima, Japan

Yasuhito Nakata