Nec Tokin Corporation

Tokin Corporation

Yasuhisa Sugawara

Tomoki Nobuta

Satoshi Suzuki

Naoki Takahashi

Yasuhiro Tomioka

Ryuta Kobayakawa

Masami Ishijima

Toshihiko Nishiyama

Yuji Yoshida

Masako Ohya

Yusuke Hoshina

Hiroki Satoh

Hiroyuki Demizu

Tadamasa Asami

Kenji Araki

Katsuhiro Yoshida

Kazuyuki Katoh

Yuji Murayama

A solid electrolytic capacitor according to one aspect of the present disclosure includes: an anode body made of a valve metal; a dielectric layer formed on the anode body; and a solid electrolyte layer formed on the dielectric layer. The solid electrolyte layer includes: a first conductive polymer layer formed on the dielectric layer and heterogeneously doped with a monomolecular dopant; a block layer formed on the first conductive polymer layer; and a second conductive polymer layer formed on the block layer and composed of a self-doped-type conductive polymer containing a plurality of side chains containing a functional group that can be doped. The block layer blocks a migration of the self-doped-type conductive polymer from the second conductive polymer layer into the first conductive polymer layer and/or a migration of the self-doped-type conductive polymer from the second conductive polymer layer into pores of the porous anode body.

Solid electrolytic capacitor and method for manufacturing solid electrolytic capacitor comprising a block layer formed using a conductive polymer heterogeneously doped with a polymer dopant

A solid electrolytic capacitor according to an aspect includes an anode body made of a valve metal, a dielectric layer formed on the anode body, a solid electrolyte layer formed on the dielectric layer, and a cathode body layer formed on the solid electrolyte layer. The solid electrolyte layer includes a first layer containing a first conductive polymer doped with a monomolecular dopant, and a second conductive polymer composed of a self-doped-type conductive polymer containing a plurality of side chains containing a functional group, the functional group being able to be doped, and a second layer formed on the first layer and containing a third conductive polymer doped with a polymer dopant; and the first conductive polymer is in contact with the third conductive polymer (the second layer).

Solid electrolytic capacitor using a doped conductive polymer

An electrolytic capacitor according to an aspect of the present disclosure includes a valve metal, a dielectric oxide film layer formed on a surface of the valve metal, a surface treatment agent layer formed on the dielectric oxide film layer, and an electrolyte layer formed on the surface treatment agent layer. The electrolyte layer includes a conductive polymer layer and an ionic liquid. For example, the conductive polymer layer is formed so that the conductive polymer layer is in contact with the surface treatment agent layer, and at least some of voids present in an interface between the conductive polymer layer and the surface treatment agent layer are filled with the ionic liquid.

Electrolytic capacitor and method for manufacturing electrolytic capacitor

The solid electrolytic capacitor according to the present invention is a solid electrolytic capacitor including a valve metal, an oxide film layer formed on a surface of the valve metal, and a solid electrolyte layer formed on the oxide film layer, wherein the solid electrolyte layer contains a conductive polymer and a gel of an organic solvent solidified with a chemical gelling agent.

Solid electrolytic capacitor

An electrically conductive polymer composition has high electrical conductivity, excellent water resistance, high density, and excellent smoothness. Also disclosed is a solid electrolyte capacitor which is prevented from the reduction in electrical conductivity, has low ESR, and also has excellent reliability. Further disclosed is a method for producing the solid electrolyte capacitor. The electrically conductive polymer composition is produced by removing a dispersion medium from an electrically conductive polymer suspension, wherein the electrically conductive polymer suspension includes: an electrically conductive polymer material including a dopant composed of a polyacid or a salt thereof and an electrically conductive polymer; at least one compound (A) selected from erythritol, xylitol and pentaerythritol; and the dispersion medium.

An electric conductive polymer suspension is produced by performing chemical oxidative polymerization of a monomer for providing an electric conductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant to form an electric conductive polymer, recovering the electric conductive polymer, allowing an oxidant to act on the electric conductive polymer in an aqueous solvent containing a polyacid, and further mixing a dispersant with a branched structure and then pulverizing the electric conductive polymer. According to the electric conductive polymer suspension, an organic material high in conductivity, and excellent in adhesiveness to a substrate and water resistance, and a method for producing the material, as well as an electrolytic capacitor and a method for producing the capacitor can be provided.

Electric conductive polymer suspension and method for producing the same, electric conductive polymer material, and electrolytic capacitor and method for producing the same

Provided is an electroconductive polymer composition with a good film forming property and a high electroconductivity. Also, provided is an electroconductive polymer material and an electroconductive substrate with a high electroconductivity and transparency. Further, provided is a solid electrolytic capacitor with a high capacity and a low ESR. Disclosed is an electroconductive polymer composition, containing an electroconductive polymer obtained by an oxidation polymerization by using an oxidant in a reaction solution which contains at least one monomer selected from the group consisting of pyrrole, thiophene and derivatives thereof, a polyacid or a salt thereof as a dopant, and a solvent containing water and an aprotic solvent.

Electroconductive polymer composition, electroconductive polymer material, electroconductive substrate, electrode and solid electrolytic capacitor

Provided is an electroconductive polymer composition with a good film forming property. Also, provided is an electroconductive polymer material with a high electroconductivity and a high transparency as well as an electroconductive substrate having the electroconductive polymer material on a substrate, and an electrode. Further, provided is an electronic device having the electrode as well as a solid electrolytic capacitor with a high capacitance and a low ESR. Disclosed is an electroconductive polymer composition, containing an electroconductive polymer in which a dopant is doped, a water-soluble polymer resin, and a solvent which contains water and an organic solvent whose dielectric constant is higher than that of water.

Provided are an electroconductive polymer suspension solution and a method for producing the same, which has excellent adhesion to a substrate and excellent liquid resistance and which can provide an organic material having high electroconductivity. An electroconductive polymer suspension solution of an exemplary embodiment of the invention contains an electroconductive polymer, at least one kind of a water-soluble polyhydric alcohol, and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol. The electroconductive polymer suspension solution can be produced by collecting an electroconductive polymer which is obtained by chemical oxidative polymerization of a monomer giving the electroconductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant, by contacting the electroconductive polymer with an oxidant in an aqueous solvent containing a polyacid, and further by mixing at least one kind of a water-soluble polyhydric alcohol and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol.

Conductive polymer suspension and method for producing the same, conductive organic material, and electrolytic capacitor and method for producing the same

The present invention provides an electroconductive polymer suspension solution and an electroconductive polymer material which has a high electroconductivity and in which the time-related deterioration of the electroconductivity is suppressed. Also, the present invention provides an electrolytic capacitor with a low ESR using the electroconductive polymer material as a solid electrolyte and a method for producing the same. In the present invention, electroconductive polymer particlesin the electroconductive polymer material are bonded via organic dispersantand cross-linkerto obtain a strong bond between electroconductive polymer particles

Electroconductive polymer suspension solution, electroconductive polymer material, and electrolytic capacitor and method for producing the same

The present invention provides an electroconductive polymer solution in which the good dispersibility is maintained and the pH is arbitrarily adjusted, and an electroconductive polymer composition having an excellent heat resistance. Further, the present invention provides a solid electrolytic capacitor having an excellent reliability. The present invention is an electroconductive polymer solution, containing an electroconductive polymer in which a dopant is doped, a first compound having an amino group and a hydroxyl group, a second compound having a carboxylic acid group, and a dispersing medium.

Electroconductive polymer solution, electroconductive polymer composition, and solid electrolytic capacitor therewith and method for producing same

An exemplary embodiment of the invention provides an electroconductive polymer composition having high electroconductivity which is suitable for a solid electrolytic capacitor, and provides a solid electrolytic capacitor having low ESR as well as low leakage current (LC). In an exemplary embodiment of the invention, an electroconductive polymer composition having high electroconductivity is formed by drying an electroconductive polymer suspension solution which comprises a polyanion having a cross-linked structure, an electroconductive polymer, and a solvent. In an exemplary embodiment of the invention, a solid electrolytic capacitor having low ESR as well as low LC is obtained by using the electroconductive polymer composition for a solid electrolyte layer that is an electroconductive polymer layer.

Electroconductive polymer composition, method for producing the same, and solid electrolytic capacitor using electroconductive polymer composition

The present invention provides a conductive polymer suspension for providing a conductive polymer material having high conductivity and a method for producing the same, and particularly provides a solid electrolytic capacitor having low ESR and a method for producing the same. In an emulsion comprising a dopant of a low molecular organic acid or a salt thereof, obtained by emulsifying a monomer providing a conductive polymer, using a nonionic surfactant, in a water, the monomer is subjected to chemical oxidative polymerization, using an oxidant, to synthesize a conductive polymer. The obtained conductive polymer is purified, and then, the purified conductive polymer and an oxidant are mixed in an aqueous solvent containing a polyacid component to produce a conductive polymer suspension.

Conductive polymer suspension and method for producing the same, conductive polymer material, and solid electrolytic capacitor and method for producing the same

A conductive polymer composition with excellent water resistance and conductivity, and a solid electrolytic capacitor with low ESR, excellent reliability, and especially moisture resistance. The conductive polymer composition includes a conductive polymer, a polyanion that includes a hydrophilic group, where the polyanion functioning as a dopant of the conductive polymer. At least a part of the hydrophilic group of the polyanion is condensed with an epoxy group in a compound with one epoxy group. A solid electrolytic capacitor of the present invention includes the conductive polymer composition.

Conductive polymer composition, method of producing the same, and solid electrolytic capacitor

The present invention provides a solid electrolytic capacitor having sufficiently low impedance at high frequencies in which a conductive polymer formed on a dielectric oxide film has good adherence to the dielectric oxide film, and a manufacturing method of the solid electrolytic capacitor. The solid electrolytic capacitor of the present invention includes a valve metal; a dielectric oxide film layer formed on a surface of the valve metal; and a solid electrolyte layer, comprising a conductive polymer layer, formed on the dielectric oxide film layer. The conductive polymer layer contains, as an additive, 0.1 wt % to 30 wt % of an organic oligomer having an average degree of polymerization of 2 to 100.

Growing community of inventors

Sendai, Japan

Yasuhisa Sugawara