Toyota Jidosha Kabushiki Kaisha

Takeda Chemical Industries, Inc.

Takemoto Yushi Kabushiki Kaisha

Toho Beslon Co., Ltd.

Yasuhiro Mishima

Ken Hatta

Takashi Shibata

Hisayuki Iwai

Koichi Akiyama

Sanzi Aoki

Kenichi Nishino

Sanji Aoki

Takashi Ino

Mitsuo Kinoshita

Tatsuhiko Ozaki

Hiroyuki Kosuda

Masahiro Nakagawa

Yasuo Kogo

Hiromu Miyashita

Atsuyuki Tsuzuki

Hiroma Miyashita

Kunihiro Takenaka

Hidehiro Hayasaki

Tokio Yamamuro

Resin compositions containing (a) unsaturated polyester, (b) polymerizable monomer, (c) thermoplastic resin, (d) a polymerization initiator, and (e) hollow glass microspheres with a true density of 0.5 to 1.3 g/cm.sup.3 and an elution alkalinity of 0.05 meq/g or less; molding materials obtained by impregnating glass fibers with such resin compositions; and molded products obtained by curing such molding materials. The molding materials have a superior workability and are useful for the production of parts to be coated, such as automotive external body panels. The molded products are light in weight and are highly resistant to water. Defective adhesion of coating or blisters does not occur.

Unsaturated polyester resin compositions, molding materials, and molded

Quickly curable unsaturated polyester composition with improved surface characteristics and stability in storage contains 20-40 weight parts of unsaturated polyester, 20-60 weight parts of vinyl monomer, 0.01-1.0 weight parts of BHT (ditertiary butyl hydroxy toluene), and 10-40 weight parts of thermoplastic resin such that the total is 100 weight parts. In addition, 0.001-0.1 weight parts of compound with effect of inhibiting polymerization at temperatures over 100.degree. C. are contained against the total of 100 weight parts. Molding materials are obtained by impregnating glass fibers with such compositions and products are obtained by curing such molding materials.

Unsaturated polyester compositions, molding materials and molded products

A camshaft for internal combustion engines, the camshaft having a double-pipe shaft portion comprising an outer pipe, an inner pipe, and an intermediate layer therebetween. The intermediate layer is composed of a layer of a thermoplastic liquid crystalline polyester resin that has been injected into a gap between the outer pipe and the inner pipe, by an injection molding machine. The camshaft is lightweight and has excellent vibration-damping properties, and further, has a structure allowing an easy manufacture thereof, and thus is suitable for mass production.

Camshaft for internal combustion engines

Curable unsaturated polyester resin compositions from which molded products with superior surface smoothness can be obtained include a block copolymer of a specified form, an unsaturated polyester, a vinyl monomer, a filler, a curing catalyst and a reinforcing fiber. The block copolymer is of the form A--(B).sub.n where A is non-hydrogenated polyisoprene block having viscosity average molecular weight of 10000 or more, B is saturated polyester block obtainable by condensation of organic dicarboxylic anhydride and 1,2-epoxide, more than 50 mol % of terminal groups of the polyester block being carboxylic acid group, A and B are connected by ester linkage and n is not less than 2. Block copolymers of this type can be formed by starting with carboxylic acid or hydroxyl group in polyisoprene and by alternate condensation of organic dicarboxylic anhydride and 1,2-epoxide.

Curable unsaturated polyester dresin composition

A quickly curable unsaturated polyester composition with high surface quality contains an unsaturated polyester, a vinyl monomer, either an alkane polyol polyacrylate or an alkane polyol polymethylacrylate, a thermoplastic resin, and one or more curing catalysts selected from t-butylperoxy benzoate, t-butylperoxy octoate and 2,5-dimethyl-2,5-di(benzoilperoxy) hexane. Molding compounds are obtained by impregnating glass fibers with such composition and molded products obtained by curing such molding material have improved surface smoothness.

Unsaturated polyester compositions molding materials therefrom and

Unsaturated polyester compositions which are quickly curable and from which molded products with superior surface quality can be obtained are characterized as being composed of an unsaturated polyester, an olefinic unsaturated monomer, an aromatic vinyl-conjugated diene block copolymer or a hydrogenated aromatic vinyl-conjugated diene block copolymer, a mixture of t-butylperoxy benzoate, t-butylperoxy octoate and 1,1-bis(t-butylperoxy) 3,3,5-trimethyl cyclohexane, and at least one selected from organic compounds of cobalt, copper and manganese.

Unsaturated polyester compositions and molded products therefrom

A rocker arm made from a carbon-fiber reinforced resin is disclosed wherein various axes are defined with particularity such as the central axis of the hole through which the rocker shaft is inserted (Z-axis), a line parallel to the edge of the valve side (Y-axis) and the line that is parallel to the cam side (Y'axis). The bisect of the angle at which the Y-axis crosses the Y'axis is the X-axis. Further, cos.sup.2 .beta. of the carbon fibers present in the Y- or Y'axis side with respect to the X-Z axis is defined in detail where .beta. is a defined angle of orientation as is cos.sup.2 .alpha. which is defined in the specification. The rocker arm is produced by filling a rocker arm mold with a carbon fiber-containing synthetic resin such that cos.sup.2 .beta. of the carbon fibers meets a defined value to such an extent that the cos.sup.2 .alpha. meets a defind value. The rocker arm is lighter and stronger than conventional rocker arms.

Rocker arm and process for producing the same

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Aichi, Japan

Yasuhiro Mishima