Idemitsu Kosan Company, Limited

Idemitsu Petrochemical Co., Ltd.

Yasuhiro Ishikawa

Tomoko Abe

Yukiko Nagao

Hiroaki Motegi

Aki Yamada

Masaya Okamoto

Hiroshi Kawato

Yohei Koori

Koichi Suga

Hirotoshi Ishii

Takafumi Akimoto

Kazushige Ideta

Masami Kogure

Yusuke Aoki

Yoshio Ikeda

Yoshihiko Horio

Makoto Ando

Atsushi Sato

Akio Nodera

Masaru Nakagawa

Toshio Isozaki

Takayoshi Tanaka

Masami Takimoto

Mitsugu Nakae

Hiroshi Yamaguchi

Munehiro Chosa

Eiji Tamura

Masatoshi Saitou

Yumi Nakayama

Sadayuki Sato

Provided is a molded body, including a polycarbonate-based resin composition containing: a polycarbonate-polyorganosiloxane copolymer (A); and at least one kind of compound (B) selected from the group consisting of an antioxidant, a dye, a release agent, a light-diffusing agent, a flame retardant, a UV absorber, a silicone-based compound, an epoxy compound, and a polyether compound, wherein the polycarbonate-polyorganosiloxane copolymer (A) contains a polycarbonate block (A-1) and a polyorganosiloxane block (A-2), and contains the polyorganosiloxane block (A-2) at a content of from 20 mass % to 70 mass %, and wherein the molded body has a durometer hardness of from 25 to 72, which is measured with a type D durometer in conformity with JIS K 6253-3:2012.

Molded body including polycarbonate-based resin composition

Provided is a polycarbonate-polyorganosiloxane copolymer (A), including: a polycarbonate block (A-1) formed of a repeating unit having a specific structure; and a polyorganosiloxane block (A-2) containing a repeating unit having a specific structure, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following requirements (1) to (3): (1) the content of the polyorganosiloxane block (A-2) in the polycarbonate-polyorganosiloxane copolymer (A) is from more than 40 mass % to 70 mass % or less; (2) the polycarbonate-polyorganosiloxane copolymer has a viscosity-average molecular weight of from 10,000 or more to 23,000 or less; and (3) the polycarbonate-polyorganosiloxane copolymer includes a specific polycarbonate block as the polycarbonate block (A-1).

Polycarbonate-polyorganosiloxane copolymer

A polycarbonate-based resin composition, including: a polycarbonate-based resin satisfying requirements (1) and (2); and an inorganic filler blended into the polycarbonate-based resin, wherein a ratio of the filler in 100 mass % of a total amount of the polycarbonate-based resin and the filler is from 0.1 mass % or more to 50 mass % or less: (1) the polycarbonate-based resin contains a polycarbonate-polyorganosiloxane copolymer containing a polycarbonate block formed of a specific repeating unit and a polyorganosiloxane block containing a specific repeating unit, and an aromatic polycarbonate-based resin except the polycarbonate-polyorganosiloxane copolymer; and (2) the polycarbonate-based resin has a structure in which a domain containing the polyorganosiloxane block is present in a matrix containing the aromatic polycarbonate-based resin as a main component, and a domain containing at least one selected from a block derived from the aromatic polycarbonate-based resin and the polycarbonate block is present inside the domain.

Polycarbonate resin composition and molded product thereof

Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a):15&#x2264;1&#x2003;&#x2003;(F1a)wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.

Polycarbonate-polyorganosiloxane copolymer, polycarbonate resin composition including same, and molded product thereof

Provided is a molded body including a polycarbonate-polyorganosiloxane copolymer which contains a polycarbonate block (A-1) formed of a repeating unit having a specific structure and a polyorganosiloxane block (A-2) containing a repeating unit having a specific structure, and in which the content of the polyorganosiloxane block (A-2) is from 20 mass % or more to 70 mass % or less, wherein the molded body has a durometer hardness of from 25 or more to 72 or less measured with a type D durometer in conformity with JIS K 6253-3:2012.

Molded body containing polycarbonate-polyorganosiloxane copolymer

A flame-retardant polycarbonate-based resin composition, including: a polycarbonate-based resin satisfying requirements (1) and (2); and a flame retardant, wherein the flame retardant is in an amount of from 0.001 part by mass or more to 20 parts by mass or less with respect to 100 parts by mass of the polycarbonate-based resin: (1) the polycarbonate-based resin contains a polycarbonate-polyorganosiloxane copolymer containing a polycarbonate block formed of a specific repeating unit and a polyorganosiloxane block containing a specific repeating unit, and an aromatic polycarbonate-based resin except the polycarbonate-polyorganosiloxane copolymer; and (2) the polycarbonate-based resin has a structure in which a domain containing the polyorganosiloxane block is present in a matrix containing the aromatic polycarbonate-based resin as a main component, and a domain containing at least one selected from a block derived from the aromatic polycarbonate-based resin and the polycarbonate block is present inside the domain.

Flame-retardant polycarbonate-based resin composition and molded product thereof

Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing 0.1 mass % or more to 100 mass % or less of a polycarbonate-polyorganosiloxane copolymer (A), which contains a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and 0 mass % or more to 99.9 mass % or less of an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); and 1 mass % or more to 50 mass % or less of a polyester-based resin (C), wherein the polyorganosiloxane block (A-2) has an average chain length of from 20 or more to less than 50, and a 3-millimeter thick plate formed of the polycarbonate-based resin composition has a total light transmittance of 80% or more.

Polycarbonate-based resin composition and molded article thereof

Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing 0.1 mass % or more to 100 mass % or less of a polycarbonate-polyorganosiloxane copolymer (A), which contains a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and 0 mass % or more to 99.9 mass % or less of an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); 1 mass % or more to 50 mass % or less of a polyester-based resin (C); and 0.001 part by mass or more to 1 part by mass or less of an amide compound (D) with respect to 100 parts by mass of a total amount of the polycarbonate-based resin (S) and the polyester-based resin (C).

Polycarbonate resin composition and molded article thereof

A polycarbonate-based resin composition, including: a polycarbonate-based resin satisfying requirements (1) and (2); and a styrene-based resin blended into the polycarbonate-based resin, wherein a ratio of the polycarbonate-based resin in 100 mass % of a total amount of the polycarbonate-based resin and the styrene-based resin is from 50 mass % or more to 99 mass % or less: (1) the polycarbonate-based resin contains a polycarbonate-polyorganosiloxane copolymer containing a polycarbonate block formed of a specific repeating unit and a polyorganosiloxane block containing a specific repeating unit, and an aromatic polycarbonate-based resin except the polycarbonate-polyorganosiloxane copolymer; and (2) the polycarbonate-based resin has a structure in which a domain containing the polyorganosiloxane block is present in a matrix containing the aromatic polycarbonate-based resin as a main component, and a domain containing at least one selected from a block derived from the aromatic polycarbonate-based resin and the polycarbonate block is present inside the domain.

Polycarbonate-polyorganosiloxane copolymer, flame-retardant polycarbonate resin composition including same, and molded product thereof

Provided is a polycarbonate-based resin composition, including: 50 mass % or more to 99 mass % or less of a polycarbonate-based resin (S) containing a polycarbonate-polyorganosiloxane copolymer (A) containing a polycarbonate block (A-1) formed of a specific repeating unit and a polyorganosiloxane block (A-2) containing a specific repeating unit, and an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); and 1 mass % or more to 50 mass % or less of a polyester-based resin (C), wherein the polyorganosiloxane block (A-2) has an average chain length of from 50 or more to 500 or less.

Polycarbonate-based resin composition and molded product thereof

Provided is a polycarbonate-based resin composition containing: a polycarbonate-polyorganosiloxane copolymer (A-1) which contains a specific repeating unit and in which a polyorganosiloxane block has an average chain length of 20 or more and less than 60; a polycarbonate-polyorganosiloxane copolymer (A-2) which contains a specific repeating unit and in which a polyorganosiloxane block has an average chain length of 60 or more and less than 500; and a polycarbonate-based resin (A-3) except the polycarbonate-polyorganosiloxane copolymer (A-1) and the polycarbonate-polyorganosiloxane copolymer (A-2), wherein the ratio of the polycarbonate-based resin (A-3) to the total weight of the polycarbonate-polyorganosiloxane copolymer (A-1), the polycarbonate-polyorganosiloxane copolymer (A-2), and the polycarbonate-based resin (A-3) is 10 mass % or more.

Polycarbonate resin composition

Provided is a polycarbonate-based resin composition, including: 10 to 90 mass % of a polycarbonate-polyorganosiloxane copolymer (E-1); and 10 to 90 mass % of an aromatic polycarbonate resin (E-2) except the polycarbonate-polyorganosiloxane copolymer (E-1), in which the molecular weight distribution of the polyorganosiloxane block of the polycarbonate-polyorganosiloxane copolymer is controlled within a specific region.

Polycarbonate resin composition and molded body of same

Provided is a polycarbonate-based resin composition containing a polycarbonate-based resin containing a polycarbonate-polyorganosiloxane copolymer, and 0.01 to 1.0 part by mass of a UV absorber with respect to 100 parts by mass of the polycarbonate-based resin, in which the molecular weight distribution of a polyorganosiloxane block in the polycarbonate-polyorganosiloxane copolymer is controlled within a specific region.

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Ichihara, Japan

Yasuhiro Ishikawa