Asahi Glass Company, Limited

Agc Inc.

Gunma University

Yasuhiko Matsuoka

Shinya Higuchi

Jun Hoshikawa

Shigeki Kobayashi

Hiroki Kamiya

Hiroshi Funaki

Toru Sasaki

Tomoya Hosoda

Wataru Kasai

Hiroki Nagai

Jumpei Nomura

Nobuyuki Yamagishi

Junko Haga

Makoto Honda

Shin Tatematsu

Eiichi Nishi

Takehiro Kose

Kazuo Umemura

Nobuyuki Kasahara

Masahide Yodogawa

Daisuke Taguchi

Junji Saito

Masao Umino

Mitsuru Seki

Satoko Yasuda

Hiroki Uehara

Takeshi Yamanobe

Yasumasa Yukawa

Toshinori Tomita

Ken Iruya

Kunio Watanabe

Go Mizuno

Yuichi Iwano

Terence Edwin Attwood

Steven McDonald

Philip David Mackrell

Shigeki Hiraoka

To provide an adhesive film comprising a polyimide film and a fluorinated resin layer directly laminated, in which blisters (foaming) in an atmosphere corresponding to reflow soldering at high temperature are suppressed, and a flexible metal laminate. An adhesive film having a fluorinated resin layer containing a fluorinated copolymer (A) directly laminated on one side or both sides of a polyimide film, wherein the fluorinated copolymer (A) has a melting point of at least 280&#xb0; C. and at most 320&#xb0; C., is melt-moldable, and has at least one type of functional groups selected from the group consisting of a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, and the fluorinated resin layer has a thickness of from 1 to 20 &#x3bc;m.

Adhesive film and flexible metal laminate

To provide an insulating tape for covering, in which a polyimide film and a fluorinated resin film are laminated with excellent adhesion, and a method for producing a structure, which comprises covering a conductor with such an insulating tape for covering, followed by thermal treatment. The insulating tape for covering, comprises a polyimide film and a fluorinated resin film directly laminated on one or both surfaces of the polyimide film, wherein the fluorinated resin film contains a fluorinated copolymer (A) which has a melting point of from 220 to 320&#xb0; C. and can be melt-molded and which has at least one type of functional groups selected from the group consisting of carbonyl group-containing groups, hydroxy groups, epoxy groups and isocyanate groups.

Insulating tape for covering, and method for producing structure

To provide a fluorinated elastomer composition which is excellent in flexibility, heat resistance and flame retardance, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b), an ethylene copolymer (c) containing epoxy groups and a flame retardant (d), wherein the mass ratio [(a)/(b)] of (a) to (b) is from 70/30 to 40/60, the mass ratio [(b)/(c)] of (b) to (c) is from 100/0.1 to 100/10, and the content of (d) is from 0.1 to 30 parts by mass per 100 parts by mass of the total content of (a), (b) and (c).

Fluorinated elastomer composition and method for its production, molded product, cross-linked product, and covered electric wire

To provide a fluorinated elastomer composition which is excellent in flexibility and oil resistance to lubricant oil such as automatic transmission oil, is less susceptible to heat discoloration and is excellent also in moldability, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b) and an ethylene copolymer (c) containing epoxy groups, wherein the mass ratio [(a)/(b)] of the tetrafluoroethylene/propylene copolymer (a) to the ethylene/tetrafluoroethylene copolymer (b) is from 70/30 to 40/60, and the mass ratio [(b)/(c)] of the ethylene/tetrafluoroethylene copolymer (b) to the ethylene copolymer (c) containing epoxy groups is from 100/0.1 to 100/10.

A method of manufacturing a PTFE stretched film that has higher tensile strength at its breaking point. In the method, a resin composition is obtained by mixing an emulsion of PTFE (A) with a number average molecular weight of 5&#xd7;106 or more and an emulsion of PTFE (B) with a number average molecular weight of 1&#xd7;106 to 4&#xd7;106 so that the solid content ratio (A/B) of the PTFE (A) and the PTFE (B) is 99/1 to 10/90. The mixed emulsion is subjected to compression molding in a melted state under a reduced-pressure atmosphere to obtain a film.

Method of manufacture of polytetrafluoroethylene stretched film, and polytetrafluoroethylene stretched film

To produce a PTFE aqueous emulsion, whereby the environmental load is little, the stability of the aqueous emulsion is high, and a molded product having high heat resistance can be obtained. A process for producing a PTFE aqueous emulsion, which comprises emulsion-polymerizing tetrafluoroethylene (TFE) by means of at least one fluorinated emulsifier selected from the group consisting of a Cfluorinated carboxylic acid having from 1 to 4 etheric oxygen atoms in its main chain, and its salts, to obtain an aqueous emulsion containing polytetrafluoroethylene (PTFE) microparticles having an average primary particle size of from 0.1 to 0.3 &#x3bc;m, wherein at the beginning of the emulsion polymerization of TFE, a (polyfluoroalkyl)ethylene (a) represented by 'CH&#x2550;CH&#x2014;Rf', and/or a comonomer (b) having a monomer reactivity ratio rof from 0.1 to 8 in copolymerization with tetrafluoroethylene, is incorporated to the emulsion polymerization system, so as to be from 0.001 to 0.01 mass % relative to the final amount of polytetrafluoroethylene produced.

Polytetrafluoroethylene aqueous emulsion and process for its production, polytetrafluoroethylene aqueous dispersion obtainable by using such an aqueous emulsion, polytetrafluoroethylene fine powder, and stretched porous material

To provide a fluorinated elastomer composition which can improve, in production of a fluorinated foamed rubber by foaming and crosslinking a fluorinated elastomer using an organic peroxide as a crosslinking agent, the foamed state and physical properties of the fluorinated foamed rubber. A fluorinated elastomer composition which comprises 100 parts by mass of a fluorinated elastomer, from 0.1 to 20 parts by mass of a blowing agent and from 0.05 to 10 parts by mass of a crosslinking agent comprising a peroxide compound, and which contains no crosslinking aid or contains a crosslinking aid comprising a compound having at least two carbon-carbon double bond-containing groups in the same molecule, in a content of at most 0.3 part by mass, is foamed and crosslinked to produce a fluorinated foamed rubber.

Fluorinated elastomer composition and fluorinated foamed rubber

To provide a fluorinated elastic copolymer having high crosslinkability, having high flowability and excellent in the compression set and the resistance to bases, and its production process. A process for producing a fluorinated elastic copolymer, which comprises copolymerizing (a) tetrafluoroethylene and (b) propylene and as the case requires, (c) a perfluoro(alkyl vinyl ether) in the presence of an iodine compound represented by the formula RI(wherein R is a hydrocarbon group or perfluoroalkyl group having at least 3 carbon atoms) at a temperature of from 0&#xb0; C. to 50&#xb0; C., and a fluorinated elastic copolymer obtained by the production process.

Fluorinated elastic copolymer and production process

To provide a method for producing a PTFE fine powder having a low paste extrusion pressure property by a simple method. The method for producing a PTFE fine power comprises emulsion polymerizing tetrafluoroethylene in the presence of an aqueous medium, a fluorinated surfactant and a radical polymerization initiator, to produce an aqueous PTFE emulsion, and coagulating it in the presence of at least one bulk density-reducing compound selected from the group consisting of ammonia, an ammonium salt and urea in an amount of from 0.4 to 10 parts by mass per 100 parts by mass of PTFE.

Method for producing polytetrafluoroethylene fine powder

To provide a method for recovering an anionic fluorinated emulsifier, capable of easily and efficiently recovering an anionic fluorinated emulsifier adsorbed on a basic ion exchange resin. A basic ion exchange resin is brought into contact with a mixture of an aqueous inorganic acid solution and a non-aqueous fluorinated medium, or the basic ion exchange resin is brought into contact with an aqueous inorganic acid solution and then brought into contact with a non-aqueous fluorinated medium, then a phase of the non-aqueous fluorinated medium is recovered, and an acid of the anionic fluorinated emulsifier is recovered from the phase of the non-aqueous fluorinated medium.

Method for recovering anionic fluorinated emulsifier

This invention provide an aqueous PTFE dispersion and a process for efficiently producing the aqueous PTFE dispersion for coagulation processing having excellent coagulation properties of PTFE microparticles. The process involves adding a synthetic adsorbent, having a specific surface area of from 100 to 2,000 m/g, to an aqueous PTFE dispersion containing both PTFE microparticles, having an average particle size of from 0.10 to 0.50 &#x3bc;m, and a nonionic surfactant, followed by stirring or shaking and then separation into a liquid phase and a solid phase, and recovering an aqueous PTFE dispersion which contains from 45 to 70 mass % of PTFE microparticles having an average particle size of from 0.10 to 0.50 &#x3bc;m and from 1.4 to 2.1 mass %, based on the mass of the PTFE microparticles, of a nonionic surfactant.

Process for producing aqueous polytetrafluoroethylene dispersion for coagulation processing, and aqueous polytetrafluoroethylene dispersion for coagulation processing

A polymerization medium having small ozone depletion potential and small global warming potential and having a small chain transfer constant is used, to efficiently produce a fluoropolymer having a high molecular weight and having excellent heat resistance, solvent resistance, chemical resistance, etc. A process for producing a fluoropolymer, which comprises polymerizing a fluoromonomer having a carboxylic acid type functional group and a fluoroolefin using a hydrofluorocarbon as a medium, wherein the hydrofluorocarbon as the medium has 4 to 10 carbon atoms and has a ratio (molar basis) of the number of hydrogen atoms/the number of fluorine atoms (H/F ratio) of from 0.05 to 20.

Process for producing fluoropolymer, and fluorinated ion exchange membrane

A gas/liquid mixing equipment of the present invention comprises a stirring vessel, a stirring shaftinserted horizontally in the stirring vesseland a helical ribbon impellerattached to the stirring shaft, whereby a high gas absorption performance can be secured even with low shearing. Further, a polymer can be produced with high productivity. A gas/liquid mixing method of the present invention is a method which comprises employing the above-mentioned gas/liquid mixing equipment, and a method for producing a polymer of the present invention is a method which comprises polymerizing feed monomers containing gaseous monomers in aqueous solvents, wherein the gaseous monomers and the aqueous solvents are mixed by such a gas/liquid mixing method. A polymer of the present invention is produced by the above-mentioned method for producing a polymer.

Gas/liquid mixing equipment, gas/liquid mixing method, polymer and method for its production

To provide a good and simple method for decomposing and detoxifying a hardly decomposable fluorinated organic compound. Specifically, a fluorinated organic compound is decomposed by bringing an aqueous solution of the fluorinated organic compound into contact with a catalyst containing a metal oxide. The metal oxide may preferably be an oxide of at least one metal selected from the group consisting of Ni, Pd, Cu, Mn, Fe and Co, and more preferably be nickel oxide. The contact temperature is preferably within the range of from 0 to 100&#xb0; C. Preferably, the fluorinated organic compound to be decomposed is an organic fluorocarboxylic acid, an organic fluorosulfonic acid or a salt thereof, which is used as a surfactant or an surface treatment agent.

Method for decomposing water-soluble fluorinated organic compound

The present invention provides a method for producing a polytetrafluoroethylene fine powder, which comprises emulsion polymerizing tetrafluoroethylene in the presence of an aqueous medium, a fluorinated surfactant and a radical polymerization initiator to produce an aqueous polytetrafluoroethylene emulsion, mixing and coagulating the aqueous emulsion to separate a polytetrafluoroethylene fine powder, and then drying the polytetrafluoroethylene fine powder in a wet state in an atmosphere containing ammonia.

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Tokyo, Japan

Yasuhiko Matsuoka