Shin-etsu Chemical Co., Ltd.

Yasuaki Hara

Fumio Okada

Hisashi Aoki

Masahiko Ogawa

Minoru Takamizawa

Meguru Kashida

Shunji Aoki

Toshio Ohba

Kazuma Momii

Kiyohiro Kondow

Toshinobu Ishihara

Yoshio Inoue

Tohru Kubota

Kunio Itoh

Masanao Kamei

Shinji Irifune

Kenichi Isobe

Hiroshi Ohashi

Morizo Nakazato

Tsuyoshi Aoyama

Nobuyuki Hasebe

Takeshi Mihama

Tomohiro Yamazaki

Tsuyoshi Urashima

Yasunori Takaichi

Seiichi Nishimura

Aoki, Hisashi

Hsashi Aoki

A curable silicone composition based on an organopolysiloxane having a cyclotrisiloxane structure quickly cures by brief heating or ultraviolet exposure. It further contains an acid, acid generator, base or base generator or an oniom salt photo-initiator as a curing agent. The cured product has release property from adhesive substance which remains unchanged with the lapse of time and good mold release properties, and thus provides a lightly releasable cured film. The composition is widely used as adhesive tape backing agents, mold release agents, protective coating agents, water and oil repellent agents, and paint base.

Curable silicone compositions

A UV light-curable organopolysiloxane composition which comprises (A) 100 parts by weight of an organopolysiloxane having at least one functional epoxy group in one molecule, (B) from 1 to 100 parts by weight of a polyether compound of the formula, R.sup.1 --(OR.sup.2).sub.n --OR.sup.3, wherein R.sup.1 represents an alkyl or alkenyl group having from 1 to 8 carbon atoms, R.sup.2 represents an alkylene group having from 2 to 4 carbon atoms, R.sup.3 represents a hydrogen atom or an alkyl or alkenyl group having from 1 to 8 carbon atoms, and n is an integer of from 1 to 50, and (C) from 0.01 to 40 parts by weight of all onium salt photoinitiator.

UV light-curable epoxy-functional organopolysiloxane/polyether

A coating composition comprising (A) a polyorganosiloxane graft copolymer emulsion, (B) a reaction product between an amino functional silane and/or a hydrolyzate thereof and an acid anhydride, (C) colloidal silica, (D) a curing catalyst, and (E) an inorganic filler is useful in coating exterior and interior building materials. The composition is applicable to a substrate to form a coating at room temperature having sufficient extensibility to follow cracks in the underlying substrate as well as low-to-high temperature sensitive performance, moisture permeability, flame retardance, and decorative effect.

Flame retardant coating compositions and coated articles

A fiber treating composition based on an organopolysiloxane of the average compositional formula:

Fiber treating compositions

The invention provides a high-sensitivity ultraviolet-curable organopolysiloxane composition suitable for use as a surface-release treatment of various substrate such as release-paper sheets and the like. The composition comprises, as the essential ingredients, (a) an organopolysiloxane having a viscosity in the range from 50 to 3000 centipoise at 25.degree. C. and containing, in a molecule, at least one (meth)acryloxy-substituted monovalent hydrocarbon group or at least one epoxy- or glycidyloxy-substituted monovalent hydrocarbon group, and (b) a sulfonate compound such as 2-hydroxy-3-oxy-2,3-diphenylpropyl methanesulfonate as the photopolymerization initiator. The sensitivity of the composition to photopolymerization can be further increased by the addition of a specific salt such as sodium hexafluoroantimonate and sodium hexafluorophosphate.

Ultraviolet-curable organopolysiloxane composition containing a

A radiation curable organopolysiloxane-containing composition is disclosed which is curable by the irradiation with actinic rays in a relatively low dose to give a cured layer having excellent surface-releasability so that the composition is useful, for example, as a coating agent of release paper for temporary protection of adhesive surface. The composition comprises (a) 0.1 to 20 parts by weight of a linear organopolysiloxane having at least one vinylphenyl or isopropenylphenyl group bonded to only one of the terminal silicon atoms in the molecular chain and (b) 99.9 to 80 parts by weight of a (meth)acrylate compound which is a (meth)acrylic acid ester of a polyhydric alcohol or a polyester of a polyhydric alcohol and a dibasic carboxylic acid esterified with (meth)acrylic acid at the residual hydroxy groups.

Radiation-curable organopolysiloxane-containing composition

A release silicone emulsion composition comprising:

Release silicone emulsion composition and process for preparing it

Release silicone emulsion composition

A releasing silicone composition, which in cured form has from medium to high bond release strength, comprising 0.1 to 10 parts by weight of an organopolysiloxane of the formula ##STR1## wherein R.sup.1 is alkyl of 1-3 carbon atoms, or a phenyl group; each R.sup.2 is R.sup.1 or R.sup.3 ; R.sup.3 is C.sub.l H.sub.2l+1 COOCH.sub.2 CH.sub.2 CH.sub.2 -- in which l is an integer from 14-20; m is an integer from 50-200; and n is an integer from 0-20, in a silicone composition comprising 100 parts by weight of an organopolysiloxane which contains at least two vinyl groups bonded directly to silicon atoms, from 0.1 to 30 parts by weight of an organohydrogenpolysiloxane which contains at least two hydrogen atoms bonded directly to silicon atoms, and a platinum catalyst.

Releasing silicone composition and cured matter thereof

A solventless silicone composition for release paper containing a partially branched organopolysiloxane as a vinyl base polysiloxane to be cured, which may be applied without containing any organic solvents, and which gives a cured film having excellent slip properties and releasability without using any slip-imparting materials.

Solventless silicone compositions for release paper

A releasing agent silicone composition which gives an improved cured film for rendering surfaces non-adherent having lasting releaseability, good slip factor, and stable peeling strength and rate of residual adhesive strength, even when the adhesive material is acrylic, employs a first organopolysiloxane having at least two silicon-bonded unsaturated groups, a second organopolysiloxane having at least two silicon-bonded hydrogen atoms, and a third organopolysiloxane having one end terminated by a Si--H bond.

Silicone composition for rendering surfaces non-adherent

Disclosed herein is an ultraviolet-curable organopolysiloxane composition which provides a cured film having improved brittleness, hardness, scratch resistance, and durability. The composition is composed of an acrylic-functional organopolysiloxane containing phenylsiloxane units and siloxane units having a specific acrylic functional group, a specific acrylate or methacrylate, and a photoinitiator.

Ultraviolet-curable composition

The invention provides a method for improving the stability of the surface-releasing performance of a silicone-coated release paper so as to minimize the changes in the peeling resistance between the release paper and an adhesive surface bonded thereto even after lapse of time from preparation of the release paper to bonding of the adhesive surface or from bonding of the adhesive surface to peeling thereof. The method comprises providing an overcoating layer of an organotin compound such as dibutyl tin diacetate on the surface of a cured coating layer of an organopolysiloxane composition comprising a vinyl-containing organopolysiloxane, an organohydrogenpolysiloxane and a platinum catalyst to promote the addition reaction between the silicon-bonded vinyl groups and the silicon-bonded hydrogen atoms.

Sheets with silicone-based surface-release film

A solvent-free releasing silicone composition for rendering surfaces non-adherent which gives a cured film having desirable slip factor, toughness, and high-speed peel characteristics without sacrificing its inherenty merits such as curability, uniformity in peel resistance, and the residual adhesive strength employs a diorganovinylpolysiloxane having trivinylsilyloxy as one end group and either a vinyldimethylsilyl or trimethylsilyl group as the other end group.

A releasing silicone composition comprising three ingredients including an organopolysiloxane having at least two specific organosiloxy units having an alkenyl group, a methylhydrogenpolysiloxane material, and a platinum catalyst.

Growing community of inventors

Annaka, Japan

Yasuaki Hara