Taiwan Semiconductor Manufacturing Comp. Ltd.

Yao-Teng Chuang

Kuei-Lun Lin

Kuo-Feng Yu

Jian-Hao Chen

Shan-Mei Liao

Yen-Jui Chiu

Chi On Chui

Da-Yuan Lee

Weng Chang

Te-Yang Lai

Yung-Hsiang Chan

Chih-Yu Hsu

Semiconductor structures and methods are provided. An exemplary method according to the present disclosure includes providing a workpiece comprising a first channel member directly over a first region of a substrate and a second channel member directly over the first channel member, the first channel member being vertically spaced apart from the second channel member, conformally forming a dielectric layer over the workpiece, conformally depositing a dipole material layer over the dielectric layer, after the depositing of the dipole material layer, performing a thermal treatment process to the workpiece, after the performing of the thermal treatment process, selectively removing the dipole material layer, and forming a gate electrode layer over the dielectric layer.

P-type semiconductor devices with different threshold voltages and methods of forming the same

In an embodiment, a semiconductor device is provided, which includes a first doped gate dielectric layer and a second doped gate dielectric layer, wherein the first doped gate dielectric layer and the second doped gate dielectric layer comprise a high-k material doped with a dipole dopant. The second doped gate dielectric layer has a second concentration of the first dipole dopant. The concentration of the dipole dopant in the first doped gate dielectric layer is greater than the concentration, and the concentration peak of the dipole dopant in the first doped gate dielectric layer is deeper than the concentration peak of the dipole dopant in the second doped gate dielectric layer. A first gate electrode over the first doped gate dielectric layer, and a second gate electrode over the second doped gate dielectric layer, the first gate electrode and the second gate electrode have a same width.

Semiconductor device having doped gate dielectric layer and method for forming the same

A method includes following steps. A first gate dielectric layer is deposited over a first semiconductor channel and a second semiconductor channel. A second gate dielectric layer is deposited over the first gate dielectric layer. A layer is formed over the second gate dielectric layer using atomic layer deposition (ALD) cycles each comprising sequentially performing a first pulse step for a first pulse time, a first purge step for a first purge time, a second pulse step for a second pulse time, and a second purge step for a second purge time. A ratio of the first purge time to the first pulse time is greater than a ratio of the second purge time to the second pulse time. The layer is patterned to expose a portion of the second gate dielectric layer. The exposed portion of the second gate dielectric layer is etched.

Formation of transistor gates

A method includes receiving a workpiece having a first stack of semiconductor layers in a first region and a second stack of semiconductor layers in a second region; forming a first gate dielectric layer surrounding each layer of the first stack and a second gate dielectric layer surrounding each layer of the second stack; forming a first dipole layer surrounding the first gate dielectric layer and merging between vertically adjacent portions of the first gate dielectric layer, and a second dipole layer surrounding the second gate dielectric layer and merging between vertically adjacent portions of the second gate dielectric layer; removing the first dipole layer; after the removing of the first dipole layer, conducting a first annealing on the workpiece; removing a remaining portion of the second dipole layer; and forming a gate electrode layer in the first region and the second region.

Semiconductor structures with multiple threshold voltage offerings and methods thereof

A method comprises forming first and second fins each comprising alternately stacking first and second semiconductor layers; forming dummy gate structures over the first and second fins, and gate spacers on either side of the dummy gate structures; removing the dummy gate structures to form first and second gate trenches; removing the first semiconductor layers such that the second semiconductor layers are suspended in the first and second gate trenches; depositing a first dielectric layer around the second semiconductor layers and a second dielectric layer around the first dielectric layer; performing an ALD process to form a hard mask layer around the second dielectric layer, the ALD process comprising pulsing a first precursor for a first pulse time longer than about one second; patterning the hard mask layer; and etching a portion of the second gate dielectric layer in the second gate trench.

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Hsinchu, Taiwan

Yao-Teng Chuang