Contemporary Amperex Technology Co., Ltd.

Contemporary Amperex Technology (hong Kong) Limited

Contemporary Amperex Technology Limited

Yao Jiang

Chunhua Hu

Shushi Dou

Chengdu Liang

Tiancheng Yi

Jinhua He

Qi Wu

Bin Deng

Peipei Chen

Lu Miao

Limei Zhang

Jiao Liu

Xiaomei Liu

Jiang Liu

Baiqing Li

Xiang Zhou

Yonghuang Ye

Qian Liu

Xiaofu Xu

This application discloses a positive electrode active material, including bulk particles and a coating layer applied on an exterior surface of each of the bulk particles, where the bulk particle includes a lithium composite oxide that contains element nickel and a doping element M, and the coating layer includes an oxide of element M. When the positive electrode active material is in a 11% delithiated state, average valences of element Mand Mare αand β, respectively; when the positive electrode active material is in a 78% delithiated state, average valences of element Mand Mare αand β, respectively; and α>α, β=β. Element Mincludes one or more of Si, Ti, Cr, Mo, V, Se, Nb, Ru, Rh, Pd, Sb, Te, Ce, and W, and element Mis selected from one or more of Mg, Al, Ca, Zr, Zn, Y, and B.

Positive electrode active material and preparation method thereof, positive electrode plate, lithium-ion secondary battery, and apparatus containing such lithium-ion secondary battery

A positive electrode active material and a preparation method thereof, a positive electrode plate, a lithium-ion secondary battery, and a battery module, a battery pack, and apparatus containing the lithium-ion secondary battery are provided. The positive electrode active material includes secondary particles formed by agglomeration of primary particles, where the primary particles include a layered nickel-containing lithium composite oxide, and the nickel-containing lithium composite oxide includes a doping element; and when the positive electrode active material is charged from an 11% delithiated state to a 78% delithiated state at a rate of 0.1 C, a lattice of the primary particles has a maximum shrinkage rate satisfying Δa≤3.00% in an a-axis direction, and a maximum swelling rate satisfying Δc≤3.02% in a c-axis direction.

Positive electrode active material and preparation method thereof, positive electrode plate, lithium-ion secondary battery, and battery module, battery pack, and apparatus containing such lithium-ion secondary battery

A positive electrode active material and a preparation method thereof, a positive electrode plate, a lithium-ion secondary battery, and a battery module, battery pack, and apparatus containing such lithium-ion secondary battery are provided. The positive electrode active material includes matrix particles and a coating layer covering an exterior surface of the matrix particle, where the matrix particle includes a lithium nickel cobalt manganese oxide, and the coating layer includes an oxide of element M; the matrix particle is doped with element Mand element M, element Min the matrix particle is uniformly distributed, and element Min the matrix particle has a decreasing concentration from the exterior surface to a core of the matrix particle; and element Mand element Mare each independently selected from one or more of Mg, Al, Ca, Ba, Ti, Zr, Zn, and B, and element Mincludes one or more of Si, Ti, Cr, Mo, V, Ge, Se, Zr, Nb, Ru, Rh, Pd, Sb, Te, Ce, and W.

This application provides a positive electrode active material, a method for preparing a positive electrode active material, a positive electrode plate, a secondary battery, a battery module, a battery pack, and an electric apparatus. The positive electrode active material includes a first positive electrode active material and a second positive electrode active material. The first positive electrode active material includes a compound LiNiCoMnM'O, and the second positive electrode active material includes a core, a first coating layer enveloping the core, and a second coating layer enveloping the first coating layer, where the core includes a compound LiMnAPRO, the first coating layer includes pyrophosphate MPOand phosphate XPO, and the second coating layer includes carbon.

Positive electrode active material, method for preparing positive electrode active material, positive electrode plate, secondary battery, battery module, battery pack, and electric apparatus

Provided are a secondary battery, a battery module, a battery pack, and an electrical apparatus. The secondary battery comprises a positive electrode plate and a non-aqueous electrolyte solution, where the positive electrode plate comprises a positive electrode active material having a core-shell structure and comprising an inner core and a shell cladding the inner core, where the inner core has a chemical formula of LiMnAPRO, a first cladding layer comprises crystalline pyrophosphates LiMPOand/or M(PO), a second cladding layer comprises a crystalline phosphate XPO, and a third cladding layer is carbon; and the non-aqueous electrolyte solution comprises a first additive comprising one or more compounds in the group consisting of a compound represented by formula 1, a compound represented by formula 2, and a compound represented by formula 3, thereby improving rate performance, cycling performance, and high-temperature stability of a lithium manganese phosphate secondary battery.

Secondary battery, battery module, battery pack, and electrical apparatus

A secondary battery includes a positive electrode plate and a non-aqueous electrolyte. The positive electrode plate includes a positive electrode active material including a core and a shell enveloping the core. A chemical formula of the core is LiMnAPRO, where the first coating layer includes a crystalline pyrophosphate LiMPOand/or M(PO), the second coating layer includes a crystalline phosphate XPO, and the third coating layer is carbon. The non-aqueous electrolyte includes a first additive including one or more selected from a group consisting of compounds represented by formula 1 and compounds represented by formula 2.

Secondary battery, battery module, battery pack, and electric apparatus

A lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolytic solution. The electrode assembly includes a positive electrode sheet, a negative electrode sheet, and a separation film A positive active material in the positive electrode sheet includes LiCoMOQ. A negative active material in the negative electrode sheet includes one or more of Si, SiO, a Si/C composite material, and a Si alloy. The electrolytic solution contains an additive A and an additive B, the additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential, and the additive B is a halogen-substituted cyclic carbonate compound. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

Lithium-ion battery and apparatus

Provided are a secondary battery, a battery module, a battery pack and an electrical apparatus. The secondary battery includes a positive electrode plate and a non-aqueous electrolyte solution. A positive electrode active material includes an inner core and a shell cladding the inner core. The inner core includes LiMnAPRO. The shell includes a first cladding layer cladding the inner core and a second cladding layer cladding the first cladding layer. The first cladding layer includes pyrophosphate MPOand phosphate XPO. The second cladding layer includes carbon. The non-aqueous electrolyte solution includes a first additive. The first additive includes one or more compounds in a group consisting of a compound shown in Formula 1, a compound shown in Formula 2 and a compound shown in Formula 3. The rate performance, cycling performance and high temperature stability of a lithium manganese phosphate secondary battery are increased.

Secondary battery comprising positive electrode plate and non-aqueous electrolyte solution

The present application provides a lithium-ion battery and an apparatus, the lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separation film. The positive active material in the positive electrode sheet includes LiCoMOQ, 0.5≤x1≤1.2, 0.8≤y1<1.0, 0≤z1≤0.1, and M is selected from one of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A and an additive B, the additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential, and the additive B is an aliphatic dinitrile or polynitrile compound with a relatively high oxidation potential. The lithium-ion battery of the present application has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

The present application provides a lithium-ion battery and an apparatus, and the lithium-ion battery includes an electrode assembly and an electrolytic solution, the electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separation film. A positive active material of the positive electrode sheet includes LiCoMOQ, 0.5≤x1≤1.2, 0.85≤y1≤1.0, 0≤z1≤0.1 M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolytic solution contains vinylene carbonate, fluoroethylene carbonate, 1,3-propane sultone, and an additive A. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

The present application provides a secondary battery and a battery module, battery pack and electrical device containing the same. The secondary battery comprises a positive electrode plate and an non-aqueous electrolytic solution, wherein the positive electrode plate comprises a positive electrode active material with a core-shell structure, said positive electrode active material comprising an core and a shell covering said core, said core has a chemical formula of LiMnAPRO; said shell comprises a first cladding layer covering said core, a second cladding layer covering said first cladding layer and a third cladding layer covering said second cladding layer, said non-aqueous electrolytic solution comprises a first additive, said first additive comprises one or more of compounds as shown by Formula 1, Formula 2 and Formula 3.

Secondary battery and battery module, battery pack and electrical device containing the same

This application discloses a positive electrode active material, including secondary particles and a coating layer applied on an exterior surface of each of the secondary particles, where the secondary particle includes a lithium transition metal oxide that contains a doping element M, the coating layer includes an oxide of element M, Mis selected from one or more of Si, Ti, Cr, Mo, V, Ge, Se, Zr, Nb, Ru, Rh, Pd, Sb, Te, Ce, and W, and Mis selected from one or more of Mg, Al, Ca, Ce, Ti, Zr, Zn, Y, and B; a relative deviation of local mass concentration of element Min the secondary particle is less than 20%; and the secondary particle from the core to the exterior surface of the particle includes a plurality of layers of primary particles arranged along radial direction of the secondary particle.

A novel positive electrode sheet, a secondary battery, a battery module, a battery pack and an electrical apparatus are described. The positive electrode sheet includes a positive electrode current collector and a positive electrode film layer with a single-layer structure or a multi-layer structure. When the positive electrode film layer is a single-layer structure, at least one of the positive electrode film layers comprises a first positive electrode active material and a second positive electrode active material; and/or, when the positive electrode film layer is a multi-layer structure, at least one layer of at least one of the positive electrode film layers comprises a first positive electrode active material and a second positive electrode active materials. The first positive electrode active material includes an inner core, a first cladding layer comprising crystalline pyrophosphates, a second cladding layer comprising crystalline phosphate, and a third cladding layer.

Positive electrode sheet, secondary battery, battery module, battery pack, and electrical apparatus

A positive electrode sheet may comprise a positive electrode current collector and a positive electrode film layer having a single-layer structure or a multi-layer structure provided on at least one surface thereof; when the positive electrode film layer is of a single-layer structure, at least one positive electrode film layer may comprise both a first positive electrode active material and a second positive electrode active material; and/or, when the positive electrode film layer is of a multi-layer structure, at least one layer of the at least one positive electrode film layer may comprise both a first positive electrode active material and a second positive electrode active material; the first positive electrode active material may comprises an inner core containing LiMnAPRO, a first coating layer containing pyrophosphate MPOand phosphate XPOand covering the inner core, and a second coating layer containing carbon element and covering the first coating layer.

Positive electrode sheet, secondary battery, battery module, battery pack and electrical apparatus

The present application discloses a positive electrode active material including a lithium nickel cobalt manganese oxide, the molar content of nickel in the lithium nickel cobalt manganese oxide accounts for 60%-90% of the total molar content of nickel, cobalt and manganese, and the lithium nickel cobalt manganese oxide has a layered crystal structure of a space group Rm; a transition metal layer of the lithium nickel cobalt manganese oxide includes a doping element, and the local mass concentration of the doping element in particles of the positive electrode active material has a relative deviation of 20% or less; and in a differential scanning calorimetry spectrum of the positive electrode active material in a 78% delithiation state, an initial exothermic temperature of a main exothermic peak is 200&#xb0; C. or more, and an integral area of the main exothermic peak is 100 J/g or less.

Positive electrode active material, method for preparation thereof, positive electrode plate, lithium-ion secondary battery and related battery module, battery pack and apparatus

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Ningde, China

Yao Jiang