Ifp Energies Nouvelles

Yannick Lorgouilloux

Nicolas Bats

Philippe Caullet

Joel Patarin

Jean-Louis Paillaud

Jean Louis Paillaud

Joël Patarin

Mathias Dodin

The invention concerns a crystalline solid designated IM-20 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO: nGeO: pZO: qR: sF: wHO, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

IM-20 crystalline solid and process for its preparation

The invention relates to a crystallized solid, referred to by the name IM-13, which has an X-ray diffraction diagram as provided below. Said solid has a chemical composition that is expressed according to the general formula mXO: nYO: pZO: qR: sF: wHO, where R represents one or more organic radical(s), X represents one or more tetravalent element(s) different from germanium, Y represents germanium, Z represents at least one trivalent element, and F is fluorine.

IM-13 crystallized solid and its process for preparation

The invention concerns a crystalline solid designated IM-18 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO:nGeO:pZO:qR:sF:wHO, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

IM-18 crystalline solid and process for its preparation

The invention concerns a crystalline solid designated IM-17 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO: nGeO: pZO: qR: wHO, in which R represents one or more organic nitrogen-containing species, X represents one or more tetravalent element(s) other than germanium and Z represents at least one trivalent element.

IM-17 crystalline solid and process for its preparation

A crystallized solid, referred to by the name IM-14, which has an X-ray diffraction diagram as provided below, is described. Said solid has a chemical composition that is expressed according to the formula GeO:nYO:pR:qF:wHO, where R represents one or more organic radical(s), Y represents at least one trivalent element, and F is fluorine.

IM-14 crystallized solid and its process for preparation

The invention relates to a crystallized solid, denoted by the name IM-16, which has an X-ray diffraction pattern as provided hereinafter. Said solid has a chemical composition expressed in accordance with the empirical formula mXO:nGeO:pZO:qR:sF:wHO, where R represents one or more organic species, X represents one or more tetravalent elements different from germanium, Z represents at least one trivalent element and F is fluorine.

IM-16 crystallised solid and process for the preparation thereof

A crystallized solid, referred to by the name IM-15, which has an X-ray diffraction diagram as provided below, is described. Said solid has a chemical composition that is expressed according to the formula mXO:nGeO:pZO:qR:sF:wHO, where R represents one or more organic radical(s), X represents one or more different tetravalent element(s) of germanium, Z represents at least one trivalent element, and F is fluorine.

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Limoges, France

Yannick Lorgouilloux