Jiangsu Arit New Materials Co., Ltd.

Yangcheng Hu

Shanshan Qian

Chunyang Zheng

Chunman Huang

Jiezhong Gan

Haidong Jiang

Wei Li

An early-strength polycarboxylate superplasticizer with an MOF structure and a preparation method thereof are provided. The preparation method includes the following steps: 1) performing an amidation reaction on amine-containing nanocrystalline MOFs and a halogen acyl halide organic molecule to form the halogen-containing ATRP initiator; 2) performing an ATRP reaction on the obtained ATRP initiator, an unsaturated ester monomer, an unsaturated polyether macromonomer and a transition metal complex to obtain the early-strength polycarboxylate superplasticizer with the MOF structure. The present invention regulates the number and length of branch chains and product performance by controlling the number of amine groups contained in the nanocrystalline MOFs and ATRP, and has the advantages of rapid reaction, high efficiency, non-toxic and non-pollution, and simple operation. The prepared early-strength polycarboxylate superplasticizer with the MOF structure has early-strength performance and stable product performance.

Early-strength polycarboxylate superplasticizer with MOF structure and preparation method thereof

A fluorescent polycarboxylate superplasticizer and a preparation method thereof. The preparation process of the polycarboxylate superplasticizer is as follows. Firstly, a redox radical polymerization is performed on a monomer of an unsaturated acid and a derivative thereof, and an unsaturated polyether monomer to form a polycarboxylate superplasticizer pre-product. Then, the polycarboxylate superplasticizer pre-product is subjected to an esterification reaction with an organic molecule having a fluorescent property to obtain the fluorescent polycarboxylate superplasticizer. The method effectively reduces the reaction difficulty and makes the reaction rapid and efficient. The fluorescent polycarboxylate superplasticizer is non-toxic and non-polluting, and has good controllability in the production process and less side reactions. The fluorescent polycarboxylate superplasticizer can be applied to different kinds of cement, having a high water-reducing rate, and a relatively high cost performance and competitive advantage.

Fluorescent polycarboxylate superplasticizer and preparation method thereof

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Nanjing, China

Yangcheng Hu