Lg Chem, Ltd

Yang Jun Jeon

Hyun Kyou Ha

Jin Hyuck Ju

Kwang Jin Lee

Joong Chul Lim

Min Jeong Kang

Jae Hyun Park

Hyun Min Lee

Kun Ji Kim

A method for producing a vinyl chloride-based polymer, wherein the vinyl chloride-based polymer is produced by sequentially adding a first emulsifier and a second emulsifier, which are different from each other, during polymerization and using a succinate compound as a first emulsifier. The method provides improved processability by achieving low-viscosity properties when plastisol is mixed using the produced polymer, and improved fogging properties by suppressing generation of volatile organic compounds.

Method for producing vinyl chloride-based polymer

The present disclosure relates to a composition for preparing a vinyl chloride-based polymer and a method of preparing a vinyl chloride-based polymer using the same, and provides the composition giving excellent productivity for preparing a vinyl chloride-based polymer includes while maintaining excellent foaming and viscosity properties of a plastisol including the prepared vinyl chloride-based polymer, by including a pH regulator composed of a carbonate-based metal salt, and a transition metal catalyst in the composition, and controlling an amount of the transition metal catalyst, and controlling an amount of a reducing agent such that a trace amount or none of the reducing agent is included, and the method of preparing a vinyl chloride-based polymer using the same.

Composition for preparing vinyl chloride-based polymer and method of preparing vinyl chloride-based polymer using the same

The present disclosure provides a method for preparing a vinyl chloride-based polymer, the method including a step of injecting an ionizable normal salt and polymerizing a vinyl chloride monomer in the presence of one or more emulsifiers and a polymerization initiator, wherein the ionizable normal salt includes a carbonate metal salt or a sulfite metal salt, and the ionizable normal salt is continuously injected in an amount of 70 to 1200 ppm based on the total weight of the vinyl chloride monomer when a polymerization conversion rate is in a range of 0% to 20%. The method capable of preparing a vinyl chloride-based polymer suitable as an eco-friendly material, while not affecting the rate of polymerization reaction and decreasing the generation amount of total volatile organic compounds by controlling the injection time, injection amount and kind of the ionizable normal salt, is provided.

Method for preparing vinyl chloride-based polymer

The present disclosure relates to a vinyl chloride-based polymer having a pH of 7 to 11 and satisfying the number of olefin-type defects (N) of 1.5 or less and the number of chloro-type defects (N) of 11.0 or less. The vinyl chloride-based polymer contains reduced defects in the entire polymer and may suppress dehydrochlorination reaction or crosslinking reaction during processing, and effects of preventing discoloration phenomenon, improving heat resistance and preventing the deterioration of physical properties may be expected.

Vinyl chloride-based polymer and method for preparing same

The present disclosure provides a method of preparing a vinyl chloride-based polymer, and the method provides excellent productivity while having reduced amount of a volatile organic compound generated so as to provide the vinyl chloride-based polymer suitable for an eco-friendly material, and improved foaming and viscosity properties of a plastisol including the prepared polymer, by adding a carbonate-based metal salt and a transition metal catalyst together, and controlling input time and amount of the transition metal catalyst.

Method of preparing vinyl chloride-based polymer

The present invention relates to a method for preparing vinyl chloride-based polymers, which is provided to improve polymerization productivity. An initial stage polymerization temperature is raised, the temperature is then lowered at a certain cooling rate from the time when an initial target polymerization temperature until a polymerization reaction is completed, and thus, a vinyl chloride-based polymer with excellent physical properties may be prepared while reducing a polymerization time and improving polymerization productivity even without additionally installing a polymerization reactor and heat removal equipment.

The present invention provides a method for preparing a vinyl chloride-based polymer and a vinyl chloride-based polymer prepared thereby, the method comprising a step for performing suspension polymerization of a monomer for preparing a vinyl chloride-based polymer in the presence of a polymerization initiator, a dispersant, and water soluble cellulose ether, wherein the dispersant includes a mixture of two or more kinds of polyvinyl alcohol having different degrees of saponification, and the mole average degree of saponification of the polyvinyl mixture is from 76 mol % to 80 mol %, and the water soluble cellulose ether has a gel point of 60&#xb0; C. to 90&#xb0; C. and is added before the initiation of polymerization or at a time in which the polymerization conversion rate is 70% or less.

Method for preparing vinyl chloride-based polymer, and vinyl chloride-based polymer prepared thereby

The present invention relates to a method of preparing a vinyl chloride-based polymer, and more specifically, to a method comprising the steps of, (S1) preparing a mixture in which a first protective colloid auxiliary agent and a chain regulator are mixed; (S2) preparing a second protective colloid auxiliary agent including the chain regulator activated by stirring the mixture prepared in step (S1); and (S3) performing polymerization by adding a vinyl chloride-based monomer and a polymerization initiator in the presence of the second protective colloid auxiliary agent prepared in step (S2).

The present invention provides a method for preparing a vinyl chloride-based polymer comprising performing suspension polymerization of vinyl chloride-based monomer, wherein an aromatic hydrocarbon-based compound is added when a pressure change is 0.5 to 1.5 kg/cmwith respect to an equilibrium pressure at a polymerization temperature in a polymerization reactor after the vinyl chloride-based monomer is added to the polymerization reactor, wherein the aromatic hydrocarbon-based compound comprises a reactive functional group having an intracarbon double bond and a hydroxyl group; and a vinyl chloride-based polymer prepared by the method and having a high polymerization degree and excellent fusion processability.

Method for preparing vinyl chloride-based polymer and vinyl chloride-based polymer prepared by the same

The present invention relates to a method for preparing a vinyl chloride copolymer having good heat resistance and a vinyl chloride copolymer produced by the same. In the preparation method, by not injecting an N-substituted maleimide based compound used as a comonomer together with a vinyl chloride monomer at one time in a pre-polymerization step, but in division in a specific ratio, a copolymer with a uniform distribution of the N-substituted maleimide based compound and the vinyl chloride monomer may be easily prepared, and the vinyl chloride copolymer may have good heat resistance. Accordingly, the preparation method of a vinyl chloride copolymer and the vinyl chloride copolymer according to the present invention may be easily applied to industries requiring the copolymer, particularly industries requiring a resin having good heat resistance as well as industries using a vinyl chloride resin.

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Daejeon, South Korea

Yang Jun Jeon