A. Ahlstrom Corporation

Foster Wheeler Energia Oy

Yam Y Lee

Matti A Hiltunen

Eric J Oakes

York Tsuo

Charles Viel Lamare

Carl Johnk

Folke Engstrom

Reijo J Kuivalainen

Karukkampalayam M Sellakumar

Mikko Hupa

Ragnar G Lundqvist

Charles M Davis

An apparatus for reducing the concentration of nitrogen oxides in flue gases produced in a furnace of a combustion unit includes a device for maintaining combustion reactions in the furnace, the combustion reactions resulting in the production of hot gases containing nitrogen oxides, the hot gases flowing mainly upwardly within the furnace, internal heat transfer surfaces within the furnace for recovering heat from the mainly upward flow of hot gases, an introducer for introducing nitrogen oxides reducing agent into the upward flow of hot gases in the furnace, for reducing the concentration of nitrogen oxides in the hot gases, wherein the introducer is integrally connected to the internal heat transfer surfaces, for keeping the temperature of the reducing agent at a sufficiently low temperature level upon introduction thereof into the furnace, and for efficiently mixing the reducing agent with the upward flow of hot gases, and a discharge for discharging flue gases from the furnace.

Method and apparatus for injection of NO.sub.x reducing agent

A method of reducing the nitrogen oxide level in the flue gases issuing from combustion units by introduction of reducing agents into contact with gases containing nitrogen oxides in first and second reducing stages, is provided. The first reducing stage is a non-catalytic stage (e.g. at temperatures over 800.degree. C.), while the second stage is a catalytic stage (e.g. at temperatures of about 300-400.degree. C.). A steam generation boiler with improved nitrogen reduction facilities is also provided. The amount of nitrogen oxides in the hot gases is reduced in the combination of the first and second reducing stages while producing steam in a steam generation boiler system, thus resulting in gases essentially free from nitrogen oxides while eliminating the possibility of NH.sub.3 (or other reducing agent) slip in the exhausted flue gases. Heat transfers in a convection section as used to establish stabilized temperature conditions for catalytic reduction.

Method of purifying gases containing nitrogen oxides and an apparatus

The present invention refers to an improved method and an improved apparatus for reducing the concentration of nitrogen oxides in flue gases produced by the combustion of carbonaceous fuel in combustion units having a furnace with a fluidized bed of solids therein. Hot gases produced within the furnace flow mainly upward within the furnace. Heat is recovered from the hot gases and hot solid material by heat transfer surfaces within the furnace. A nitrogen oxides reducing agent is introduced into the furnace through injection means integrally connected to the heat transfer surfaces, for keeping the temperature of the reducing agent at a sufficiently low temperature level at the introduction thereof and for efficiently mixing it with the mainly upward flowing hot gases.

Method and an apparatus for injection of NO.sub.x reducing agent

The amount of N.sub.2 O emission from a fluidized bed reactor is reduced by adding a hydrogen radical providing additive (e.g. a hydrogen containing fuel such as natural gas or alcohol) to the flue gases discharged from the fluidized bed. Sufficient oxygen is present in the flue gases--either by addition with the additive, or by addition of an excess to the combustion chamber--so that the additive reacts with the oxygen, typically raising the temperature of the flue gases (e.g. from about 700.degree.-900.degree. C. to about 950.degree.-1100.degree. C.) so that N.sub.2 O production is reduced about 10-90%. The additive may be injected in or just prior to a cyclone for separating particles from the flue gases, in a gas discharge immediately after the cyclone (e.g. just downstream of a heat exchanger for cooling the flue gases and flattening the velocity profile of the flue gases), just prior to a superheater of a convection section, or in a combustion chamber just prior to a gas turbine.

Reducing N.sub.2 O emissions when burning nitrogen-containing fuels in

A method of reducing the nitrogen oxide level in the flue gases issuing from combustion units by introduction of reducing agents into contact with gases containing nitrogen oxides in first and second reducing stages, is provided. The first reducing stage is a non-catalytic stage (e.g. at temperatures over 800.degree. C.), while the second stage is a catalytic stage (e.g. at temperatures of about 300.degree.-400.degree. C.). A steam generation boiler with improved nitrogen reduction facilities is also provided. The amount of nitrogen oxides in the hot gases is reduced in the combination of the first and second reducing stages while producing steam in a steam generation boiler system, thus resulting in gases essentially free from nitrogen oxides while eliminating the possibility of NH.sub.3 (or other reducing agent) slip in the exhausted flue gases. Heat transfers in a convection section as used to establish stabilized temperature conditions for catalytic reduction.

The amount of N.sub.2 O emission from a fluidized bed reactor is reduced by adding a hydrogen radical providing additive (e.g. a hydrogen containing fuel such as natural gas or alcohol) to the flue gases discharged from the fluidized bed. Sufficient oxygen is present in the flue gases--either by addition with the additive, or by addition of an excess to the combustion chamber--so that the additive reacts with the oxygen, typically raising the temperature of the flue gases (e.g. from about 700.degree.-900.degree. C. to about 950.degree.-1100.degree. C.) that is from about 1292.degree.-1652.degree. F. to about 1742.degree.-2012.degree. F. so that N.sub.2 O production is reduced about 10-90%. The additive may be injected in or just prior to a cyclone for separating particles from the flue gases, in a gas discharge immediately after the cyclone (e.g. just downstream of a heat exchanger for cooling the flue gases and flattening the velocity profile of the flue gases), just prior to a superheater of a convection section, or in a combustion chamber just prior to a gas turbine.

The amount of N.sub.2 O in flue gases discharged from a fluidized bed combustion system is minimized by adding an N.sub.2 O decomposing catalyst in a reactor stage downstream of the combustor. The catalyst preferably is a calcium based sorbent, such as CaO or or limestone, although NiO and other catalysts also may be utilized. Typically, the N.sub.2 O decomposition takes place without increasing the temperature of the flue gases above the 700.degree.-1000.degree. C. level that exists combustor. However, under some circumstances, if a second fluidized bed is provided as the reactor stage, additional fuel and oxygen can be added to increase the temperature of the flue gases to insure that it is over 800.degree. C. After N.sub.2 O decomposition, the flue gases may be passed through pressurized filter tubes, or through a superheater, economizer, air preheater, optional cyclone separator, and baghouse filter. A cyclone separator is preferably provided between the combustor and reactor stage, and the removed particles are recirculated to the combustor. Removal of particles, including unused sorbent, after the reactor stage also preferably takes place, with recycle to the reactor stage (if a fluidized bed stage) and/or to the combustor.

Method for reducing emissions when burning nitrogen containing fuels

Hot flue or process gases are cleaned utilizing an apparatus containing a barrier filter module formed of a monolithic ceramic support structure coated with a thin porous ceramic layer having a pore size of about 0.04-0.5 microns, and a catalyst module formed of a support structure coated with catalyst. The hot flue gases may be associated with a fluidized bed boiler plant, such as a circulating fluidized bed reactor. Gases to be cleaned are passed through the barrier filter module into contact with the thin porous ceramic layer, and then through the catalyst module so that there is a catalytic reaction with the gas.

Method and apparatus for cleaning flue gases

The amount of N.sub.2 O emission from a fluidized bed reactor is reduced by adding a hydrogen radical providing additive (e.g. a hydrogen containing fuel such as natural gas or alcohol) to the flue gases discharged from the fluidized bed. Sufficient oxygen is present in the flue gases--either by addition with the additive, or by addition of an excess to the combustion chamber--so that the additive reacts with the oxygen, typically raising the temperature of the flue gases (e.g. from about 700.degree.-900.degree. C. to about 950.degree.-1100.degree. C.) so that N.sub.2 O production is reduced about 10-90%. The additive may be injected in or just prior to a cyclone for separating particles from the flue gases. In a gas discharge immediately after the cyclone, just prior to a superheater of a convection section, or in a combustion chamber just prior to a gas turbine.

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San Diego, CA, United States of America

Yam Y Lee