3m Innovative Properties Company

Xue Tian

Naiyong Jing

Jun Ma

Gezahegn D Damte

Zhigang Yu

Garry W Lachmansingh

Xiaohai Sheng

Zhengjun Wang

Xi Chen

Jordan C Ducharme

Articles are described comprising a substrate and a hardcoat layer disposed on the substrate. The hardcoat layer comprises the hydrolyzed and condensed reaction product of a composition comprising: i) first hydrophobic silane monomer(s) having the formula RSi(OR)wherein R and Ris methyl or ethyl; ii) optional second silane monomer(s) having the formula (R)Si(OR)or Si(OR), wherein R, Rand Rare organic groups with the proviso that Ris not methyl or ethyl and m ranges from 1 to 3. The hardcoat layer may further comprises 10 to 30 wt. % silica nanoparticles. A surface layer comprising a hydrophilic silane may be disposed on the hardcoat layer. Also described is a method of using an article having a rewritable surface, hardcoat coating compositions, and methods of making hardcoat compositions and articles.

Hardcoat composition comprising methyl or ethyl trialkoxy silane, articles and methods

A film including: an organic polymeric substrate having a first major surface and a second major surface; an optional acrylic hardcoat layer disposed on the first major surface of the substrate; a siliceous primer layer disposed on the organic polymeric substrate or on the optional acrylic hardcoat layer, wherein the siliceous primer layer includes composite particles including an organic polymer portion and a siliceous portion; and a superhydrophilic surface layer disposed on the siliceous primer layer, wherein the superhydrophilic surface layer includes hydrophilic-functional groups.

Films with a primer layer containing composite particles that include an organic polymer portion and a siliceous portion

A film including: an organic polymeric substrate having a first major surface and a second major surface; an optional acrylic hardcoat layer disposed on the first major surface of the substrate; a siliceous primer layer disposed on the organic polymeric substrate or on the optional acrylic hardcoat layer, wherein the siliceous primer layer includes silica nanoparticles modified by an organic silane; and a superhydrophilic surface layer disposed on the siliceous primer layer, wherein the superhydrophilic surface layer includes hydrophilic-functional groups.

Films with a primer layer containing silica nanoparticles modified by an organic silane

Coating compositions are described including silica nanoparticles functionalized with an alkenyl silane, a dispersing agent, and a compound including a polyethylene oxide segment containing at least one hydroxyl group, at least one silane, and optionally a hydrophobic group. The coating compositions further include at least two multifunctional (meth) acrylate monomers. Also described are articles including the dried and cured coating composition disposed on a substrate. The articles exhibit anti-fog characteristics and often also mechanical durability.

Growing community of inventors

Woodbury, MN, United States of America

Xue Tian