3m Innovative Properties Company

Xuan Jiang

Naiyong Jing

Klaus Hintzer

Jeffrey N Bartow

Fee Zentis

Hongying Jiang

Ta-Hua Yu

Chunjie Zhang

Gabriele H Gottschalk-Gaudig

Richard John Pokorny

Robert J DeVoe

Tatsuo Fukushi

Sheng Ye

Daniel J Schmidt

Catherine A Bothof

Derek J Dehn

Justin A Riddle

Carsten Franke

Zhigang Yu

Masayuki Nakamura

Michelle M Mok

Tho Q Nguyen

Kevin M Casey

Mingna Xiong

Sebastian F Zehentmaier

Fuxia Sun

Shupeng Wu

Kuan-Yin Lin

Dirk H C Arren

Jiafeng Liu

Dirk HC Arren

Described herein is a curable composition comprising an amorphous fluoropolymer having an iodine, bromine and/or nitrile cure site; a peroxide cure system comprising a peroxide and a Type II coagent; and a photoinitiator, wherein the curable composition is substantially free of a binder material. Also described herein, are methods of curing the curable composition using actinic radiation and articles thereof.

Fluorinated elastomers cured by actinic radiation and methods thereof

Provided are method of producing a shaped fluoropolymer articles. The methods include subjecting a composition comprising a fluoropolymer to additive processing in an additive processing device. Also provided are articles obtained with the methods and 3D-printable compositions.

Additive processing of fluoropolymers

Provided are method of producing a shaped fluoroelastomer articles. The methods include subjecting a composition comprising a fluoroelastomer to additive processing in an additive processing device. Also provided are articles obtained with the methods and 3D-printable compositions.

Additive processing of fluoroelastomers

The present disclosure provides a multilayer article. The multilayer article includes a) a microfiltration membrane substrate, the microfiltration membrane substrate having a first major surface; and b) a first layer having a first major surface and a second major surface disposed opposite the first major surface. The first major surface of the first layer is directly attached to the first major surface of the microfiltration membrane substrate. The first layer includes a first polymeric binder and a plurality of acid-sintered interconnected first silica nanoparticles arranged to form a continuous three-dimensional porous network. The multilayer article further includes c) a second layer attached to the second major surface of the first layer. The second layer includes i) a metal coating or ii) a composite coating comprising a second polymeric binder and at least one of metal nanoparticles or metal nanowires.

Multilayer articles including coatings containing metal on microfiltration membrane substrates

Luciferin-containing substrates are provided including a substrate and luciferin dried on the substrate. The luciferin-containing substrate is free of a detectable amount of reactive luciferase. The substrate is optionally a nonwoven substrate. Monitoring devices are also provided. The monitoring devices include a test element having a test portion, a detection reagent comprising luciferase, a luciferin-containing substrate, and a container having a first end with an opening and a second end opposite the first end. The container is configured to receive the test portion and configured to be operationally coupled to an analytical instrument. The detection reagent and the luciferin each are capable of participating in one or more chemical reaction that results in the formation of a detectable product.

Luciferin-containing substrate and monitoring device including the substrate

The present disclosure provides a multilayer article. The multilayer article includes a) a microfiltration membrane substrate; b) a first layer directly attached to the first major surface of the microfiltration membrane substrate; and c) a second layer directly attached to the first layer. The first layer includes a first polymeric binder and acid-sintered interconnected first silica nanoparticles arranged to form a continuous three-dimensional porous network. The second layer includes acid-sintered interconnected second silica nanoparticles arranged to form a continuous three-dimensional porous network. The present disclosure also provides a method for forming a multilayer article. The method includes (a) saturating a microfiltration membrane substrate with a liquid; (b) applying a first aqueous coating formulation to at least a portion of a first major surface of the microfiltration membrane substrate to form a coated substrate; (c) sintering the coated substrate, thereby forming a first layer; (d) applying a second aqueous coating formulation to the first major surface of the first layer to form a twice-coated substrate; and (e) sintering the twice-coated substrate.

Multilayer articles including coatings on microfiltration membrane substrates and methods of making same

A composition having pH of 5 or less comprises composite particles dispersed in an aqueous continuous liquid phase. Each composite particle comprises a polymer core surrounded by a silicaceous shell. From 3 to 50 percent of silicon atoms in the silicaceous shells are bonded to respective organic groups via a silicon-carbon covalent bond. The weight ratio of the total amount of the silica in the composition to the total amount of the at least one polymer is from 0.1 to 19. The composition is useful for making various articles. A method for making the composition is also disclosed. Silicaceous particles dispersed in an aqueous phase, wherein from 3 to 50 percent of silicon atoms in the silicaceous particles are bonded to organic groups via a silicon-carbon covalent bond are also disclosed.

Composition, method of making composition, and article

A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition. The silica nanoparticles have a polymodal particle size distribution, wherein the polymodal particle size distribution comprises a first mode having a first particle size in the range of from 8 to 35 nanometers, wherein the polymodal particle size distribution comprises a second mode having a second particle size in the range of from 2 to 20 nanometers, wherein the first particle size is greater than the second particle size. Coatable compositions, antistatic compositions, preparable by the method are also disclosed. Soil-resistant articles including the antistatic compositions are also disclosed.

Coatable composition, antistatic composition, antistatic articles, and methods of making the same

Articles are described including a first microfiltration membrane layer having a first major surface and a second major surface disposed opposite the first major surface, and a first silica layer directly attached to the first major surface of the first microfiltration membrane layer. The first silica layer includes a polymeric binder and acid-sintered interconnected silica nanoparticles arranged to form a continuous three-dimensional porous network. A method of making an article is also described, including providing a first microfiltration membrane layer having a first major surface and a second major surface disposed opposite the first major surface, and forming a first silica layer on the first major surface.

Microporous articles with a three-dimensional porous network of acid-sintered interconnected silica nanoparticles and methods of making the same

A method of making a coated article is described comprising providing an inorganic substrate and coating the substrate with a coating composition. The coating composition comprises a plurality of siloxane nanoparticles dispersed in an organic solvent. A portion of the nanoparticles comprise the reaction product of a first alkoxy silane compound having a first organofunctional group and a second organofunctional group of a second compound and the reaction between the first and second organofunctional groups form an organic linking group. The method further comprises drying the coating composition and heating the coated substrate to volatilize the organic linking groups thereby forming a porous surface layer on the inorganic substrate. In another embodiment an article is described comprising an inorganic substrate, such as glass, and a porous inorganic (e.g. silica) surface layer having an average pore size of less than 30 nm. Also described are coating compositions and methods of making a nanoparticle coating compositions.

Siloxane nanoparticle coating useful for antireflection

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Maplewood, MN, United States of America

Xuan Jiang