Shandong University

Xiuhao Li

Shucai Li

Rentai Liu

Mengjun Chen

Chenyang Ma

Shaolong Duan

Zhenjun Wang

Chunyu Zhang

Jiwen Bai

Huasheng Zhang

Yankai Liu

Xiangchao Sheng

Mi Zhang

Jiawei Tian

A karst channel type water inrush efficient-blocking ultra-high expansion grouting material, preparation, methods and application thereof, the grouting material includes macromolecule polymer particles A and a cross-linking solidifying fluid B, wherein the macromolecule polymer particles A are an inlaid type core-shell structure, primary macromolecule water-absorbent resin serves as an inner core, part of a gelling catalyzer is attached to an the inner core surface forming a shell, and the gelling catalyzer permeates the inner core forming an inlaid structure; before use, the macromolecule polymer particle A and the cross-linking solidifying fluid B are stirred; and then obtained mixed liquid is used as the grouting material to be injected into a fracture of a rock mass fracture zone. By means of the grouting material, high-pressure large-flow karst water inrush can be efficiently treated, the blocking efficiency of water inrush is improved, and major underground engineering construction of China is further facilitated.

Karst channel type water inrush efficient-blocking ultra-high expansion grouting material and preparation and using methods and application thereof

A preparation method of an expansive polymer grouting material for treating high-pressure large-flow-rate karst water inrush includes: 1) adding a crosslinking agent to acrylic acid; then adding a polymer water-absorbent resin comonomer and performing a polymerization reaction to obtain a precursor; 2) adding an initiator to the precursor obtained in step 1), heating the mixture, performing a reaction to obtain a hydrogel, and grinding the hydrogel to obtain a primary polymer water-absorbent resin; 3) spraying a surface crosslinking agent onto a surface of the primary polymer water-absorbent resin obtained in step 2), and drying the product; and 4) preparing a suspension from an inorganic water conducting agent, spraying the suspension onto the product obtained in step 3), and performing drying to obtain the expansive polymer grouting material.

Expansive polymer grouting material for treating high-pressure large-flow-rate karst water inrush and preparation method thereof

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Jinan, China

Xiuhao Li