Huazhong University of Science and Technology

Xingping Zhou

Xiaolin Xie

Haiyan Peng

Yong Wang

Hongwei Ge

Yun Zhang

Huamin Zhou

Yajun Zhao

Jinlun Zhou

Mingli Ni

Guannan Chen

Ye Zhao

Xiaoyu Zhao

Yunsheng Ye

Yonggui Liao

Zhifang Yang

Zhigang Xue

Xiaojing Li

Xiaomei Zhang

Chengfu Zheng

A holographic wavefront printing system and method are provided. A two-dimension digital blazed grating is loaded on a phase hologram, and the emergent direction of active region diffracted light is adjusted to prevent overlapping with the dead region diffracted light after being Fourier transformed by a lens, and a phase spatial light modulator is inclined by a preset angle to change the emergent direction of the diffracted light, such that the dead region zeroth-order and first-order diffracted light on a focusing surface are symmetrical with respect to a main optical axis of a first lens, the frequency spectrum center of active region zeroth-order diffracted light is then loaded to the original frequency spectrum center without information change. In this way, the adverse effects of the dead region diffracted light and active region high-order diffracted light of the phase spatial light modulator on holographic wavefront printing are eliminated.

Holographic wavefront printing system and method

A method for synthesizing an aliphatic polyester block copolymer regulated by carbon monoxide. The method uses an organic cobalt metal complex as a convertible catalyst and includes: first regulating an anionic ring-opening copolymerization reaction between an aliphatic acid anhydride and an epoxy compound; then using carbon monoxide as a conversion agent for conversion to obtain a catalyst having a new catalytic active site; and regulating a vinyl monomer to perform active free radical polymerization to obtain an aliphatic polyester block copolymer having a controllable structure. The described synthesis method uses a convertible catalyst and a conversion agent, combines two controllable polymerization reactions which have different but compatible mechanisms, and obtains a block copolymer by means of a 'one-pot' reaction.

Method for synthesizing aliphatic polyester block copolymer regulated by carbon monoxide

The present invention belongs to the field of functional materials, and particularly relates to a directly printable image recording material, a preparation method and application thereof. The image recording material comprises 25 to 78.8 parts by mass of a photopolymerizable monomer, 0.2 to 5 parts by mass of a photoinitiator, 20 to 70 parts by mass of an inert component, and 0.05 to 2 parts by mass of a thermal polymerization inhibitor, and has an initial viscosity of 200 to 800 mPa&#xb7;s. The photopolymerizable monomer includes a thiol monomer and an olefin monomer, at least one of which is a silicon-based monomer with polyhedral oligomeric silsesquioxane as a silicon core. By introducing a POSS-based thiol or olefin monomer into the photopolymerizable monomer in combination with other material components, the recording material is allowed to have an initial viscosity of 200 to 800 mPa&#xb7;s, and meanwhile, the low thermal conductivity characteristic of the POSS-based photopolymerizable monomer is utilized, so that image storage quality is ensured, continuous industrial production of the image recording material is achieved, the process cost is reduced and the production efficiency is improved.

Directly printable image recording material and preparation method thereof

The disclosure belongs to the technical field of photopolymer materials, and more particularly relates to a dual image storage material as well as a preparation method and application thereof. The dual image storage material is obtained by selective photoreaction of 1 to 50 parts by weight of an organic fluorescent material, 7 to 50 parts by weight of liquid crystal, 0.2 to 10 parts by weight of a photoinitiator and 33 to 67 parts by weight of photopolymerizable monomers. The obtained dual image storage material can present a high-brightness holographic pattern under sunlight and a fluorescent pattern under ultraviolet light in the same spatial position. The presented holographic and fluorescent patterns may be the same or different. The obtained dual image storage material can be used in the field of optical anti-counterfeiting, optical information storage, displays or the like.

Dual image storage material as well as preparation method and application thereof

A POSS-based non-isocyanate polyurethane modified poly(propylene carbonate) and a method of making are described. The POSS-based non-isocyanate polyurethane modified poly(propylene carbonate) includes a poly(propylene carbonate) and 1 to 20 wt % of a POSS-based non-isocyanate polyurethane. The method includes subjecting a POSS-based epoxy compound to a cycloaddition reaction with COto obtain a POSS-based cyclic carbonate under an action of a catalyst, and subjecting the POSS-based cyclic carbonate to a ring-opening reaction with a monoamino compound to obtain the POSS-based non-isocyanate polyurethane. Polyurethane bonds and hydroxyl in the POSS-based non-isocyanate polyurethane serve as proton donors and forms a high-density of hydrogen bonds with carbonate units of the poly(propylene carbonate), enhancing the compatibility of the POSS-based non-isocyanate polyurethane with the poly(propylene carbonate).

POSS-based polyurethane modified poly(propylene carbonate) and preparation method thereof

The present invention provides a visible light photoinitiating system for preparing a holographic photopolymer material with high-diffraction efficiency. The photoinitiating system comprises a photosensitizer and a co-initiator, and its mechanism is that the photosensitizer transforms from ground state to excited state after absorbing photons, and then interacts with the co-initiator through transfer of electrons and protons, which produces an alkyl (or aryl) free radical R and a ketyl radical K; wherein the free radical R initiates the addition polymerization of monomers that are capable of free radical polymerization, whereas the radical K inhibits the chain propagation of the macromolecular free radicals to a certain degree due to the steric hindrance effect, and thus delays the gelation time of the photopolymerization, which helps to increase the phase separation between the polymer and the functional components. A holographic photopolymer material with high-diffraction efficiency can be obtained by employing this visible light photoinitiating system.

Visible light photoinitiating system for preparing high diffraction efficiency hologram optical polymer material

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Hubei, China

Xingping Zhou