Sobute New Materials Co., Ltd

Nanjing Bote New Materials Co., Ltd.

China University of Mining and Technology (CUMT)

Bote New Materials Taizhou Jiangyan Co., Ltd

Bote Building Materials (Tianjin) Co., Ltd

Xuzhou Coal Mine Safety Equipment Manufacture Co., Ltd.

Xin Shu

Qianping Ran

Yong Yang

Jiaping Liu

Jinzhi Liu

Han Yan

Hongxia Zhao

Gongbo Zhou

Chaoquan Tang

Dongliang Zhou

Shentong Li

Jiangang Zhang

Zhencai Zhu

Guohua Cao

Wei Li

Yuxing Peng

Jian Zhao

Ping Zhou

Yanwei Wang

Chusheng Liu

Benliang Hao

Xiumei Wang

Hua Zhu

Bi Ma

Shuying Zhai

Xin Chen

Zhen Huang

Eryi Hu

Cheng Yu

Lin Luo

The present invention discloses a polycarboxylic acid water-reducing agent with high adaptability to temperature and a method for preparing the same. The polycarboxylic acid water-reducing agent is prepared by introducing an unsaturated macromonomer D with a temperature-sensitive side chain which could be bonded to the backbone of the polycarboxylic acid through free radical polymerization. The polycarboxylic acid water-reducing agent prepared by the invention has an adsorption group density that can be automatically adjusted with the change of ambient temperature, and thereby shows similar dispersing capability and dispersion retention capability at different ambient temperatures, demonstrating high adaptability to different ambient temperatures. It can be used in a larger temperature range with a constant dosage, which is beneficial to further popularization and application of the polycarboxylic acid water-reducing agent in regions of different climates.

Polycarboxylic acid water-reducing agent with high adaptability to temperature and method for preparing the same

Disclosed are a highly adaptable viscosity-reducing polycarboxylate water reducer and its preparation method and application. The highly adaptable viscosity-reducing polycarboxylate water reducer is composed of a polymer and water, and the polymer accounts for 30-50 wt %; since the main chain of the polymer contains a hydrophobic benzene ring and hydrophilic amine, the polymer has strong rigidity and good solubility in an aqueous solution, and is rich in two adsorption groups of carboxyl group/phosphono group. The highly adaptable viscosity-reducing polycarboxylate water reducer of the present invention has excellent water-reducing and slump retention properties and is suitable for general construction projects and commercial concrete projects. Compared with the conventional polycarboxylate water reducer, the highly adaptable viscosity-reducing polycarboxylate water reducer of the present invention has strong adaptability to concrete materials and can effectively reduce the viscosity of high-strength concrete (C50-C100), thus having bright application prospects in the high-end water reducer market.

High-adaptability viscosity-reducing polycarboxylic acid water reducer, preparation method therefor and use thereof

Disclosed is an amphiphilic multifunctional hybrid nanoparticle. The nanoparticle of the present invention has a detachable hydrophilic organic polymer with both a water-soluble long chain and a hydrophobic long hydrocarbon functional group attached to the surface, wherein the body of the nanoparticle is a silica or an organofunctional group substituted silica or an organofunctional group substituted silicon-oxygen bond network, and the nanoparticle contains a free organosiloxane with hydrophobic long hydrocarbon functional groups and a fatty acid or fatty acid ester or aluminum complex of fatty acid with hydrophobic long hydrocarbon functional groups. The nanoparticle can reduce the water permeability of the cement-based material; the cement-based material has the internal hydration products and interfaces are hydrophobized, further reducing the possibility that the harmful particles erode the cement-based material through moisture penetration; furthermore, Si—Al oxides participate is beneficial to the improvement of its mechanical properties.

Amphipathic multifunctional hybrid nanoparticle, and preparation method therefor and application thereof

The present invention discloses a multitype-adsorptive-group polycarboxylic acid water-reducing agent, consisting of 30-60 wt % of a macromolecule with multitype-adsorptive groups and water, the macromolecule with multitype-adsorptive groups has a polyethylene glycol side chain, and adsorption groups of the polymer backbone include a carboxylic acid group, a sulfonic acid group and a phosphoric acid group, the phosphoric acid group being linked to the backbone of the macromolecule with multitype-adsorptive groups by nucleophilic addition. The water-reducing agent of the present invention has significantly improved adaptability to different cements and aggregates while maintaining a high water reduction efficiency, compared with the conventional polycarboxylic acid water-reducing agent agent. It has a good water reducing efficiency in many different grades of cement, as well as a better resistance to aggregates containing more impurities such as machine-made sand.

Multitype-adsorptive-group polycarboxylic acid water-reducing agent, method for preparing the same and use thereof

Disclosed is a preparation method of a polycarboxylate water reducer having a regular sequence structure. The preparation method of the present invention comprises: performing Michael addition on polyethylene glycol ether acrylate macromonomer A and amino-containing carboxylic acid B for 5-12 hours, then cooling to 0&#xb0; C., dropwise adding acryloyl chloride slowly and evenly, and further reacting for 12 hours at room temperature to obtain carboxyl-containing polyether macromonomer C; mixing the carboxyl-containing polyether macromonomer C, a small molecular RAFT reagent, an initiator, and water adequately; and holding the polymerization mass concentration at 30%-60% and heating to 60-80&#xb0; C. in the atmosphere of N2 to react for 2-5 hours to obtain the polycarboxylate water reducer having a regular sequence structure.

Preparation method for polycarboxylate water reducer having regular sequence structure

The invention relates to a serpentine inspection robot mechanism for lifting cage guide driven by magnetic wheels, comprising a magnetic wheel drive part and a pitching yawing part, wherein the magnetic wheel drive part comprises a worm and gear transmission mechanism (I) and a magnetic wheel driving mechanism (II), and the pitching yawing part comprises a pitching yawing mechanism (III). Magnetic wheels are driven by the worm and gear transmission mechanism (I) and the magnetic wheel driving mechanism (II), while the pitching and yawing control of the robot are realized by the pitching yawing mechanism (III). The serpentine robot driven by the magnetic wheels () resolves the problems that the efficiency of ordinary serpentine robot is low, and it is difficult for the simple-wheel-type robot to span the large gap and to reach some concealed corners, with the cage guide of the lifting machine sucked by the magnetic wheels ().

Serpentine inspection robot mechanism for lifting cage guide driven by magnetic wheels

A multiple-state health monitoring apparatus for critical components in a hoisting system includes a frame. The frame is a square structure formed by welding a plurality of rectangular steels. A steel wire rope is arranged around a periphery of the square structure. A power system, a friction-and-wear apparatus, a brake-and-wear apparatus, and a tensioning apparatus are sequentially mounted from left to right on a bottom layer of the square structure. A bearing signal collection system, a tension sensor, an excitation apparatus, and a steel-wire-rope image collection system are sequentially mounted from left to right on a top layer of the square structure. The steel wire rope sequentially passes through all the apparatuses or systems and is driven by the power system to perform circling. All the apparatuses or systems are used to monitor an operation status of the steel wire rope.

Multiple-state health monitoring apparatus and monitoring method for critical components in hoisting system

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Nanjing, China

Xin Shu